2,4,6-Trimethyliodobenzene
- CAS No.
- 4028-63-1
- Chemical Name:
- 2,4,6-Trimethyliodobenzene
- Synonyms
- DF77;SKL669;Mesityliodine;MESITYL IODIDE;IODOMESITYLENE;2-Iodmesitylen;2-IODOMESITYLENE;MesitylIodide>2-Iodo-3-isopropyltoluene;2,4,6-TRIMETHYLIODOBENZENE
- CBNumber:
- CB3674064
- Molecular Formula:
- C9H11I
- Molecular Weight:
- 246.09
- MDL Number:
- MFCD00013707
- MOL File:
- 4028-63-1.mol
- MSDS File:
- SDS
Melting point | 28-32 °C |
---|---|
Boiling point | 250 °C |
Density | 1.5100 (rough estimate) |
refractive index | 1.5905 (estimate) |
storage temp. | 2-8°C(protect from light) |
form | powder to lump to clear liquid |
color | White or Colorless to Light yellow |
Sensitive | Light Sensitive |
BRN | 1860064 |
InChIKey | GTPNXFKONRIHRW-UHFFFAOYSA-N |
CAS DataBase Reference | 4028-63-1(CAS DataBase Reference) |
NIST Chemistry Reference | 2,4,6-Trimethyliodobenzene(4028-63-1) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H319 | |||||||||
Precautionary statements | P305+P351+P338 | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 24/25-36/37/39-24/28 | |||||||||
HazardClass | LIGHT SENSITIVE | |||||||||
HS Code | 29039990 | |||||||||
NFPA 704 |
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2,4,6-Trimethyliodobenzene price More Price(32)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | R258377 | 2-IODO-1,3,5-TRIMETHYL-BENZENE Aldrich | 4028-63-1 | 50mg | $29.8 | 2024-03-01 | Buy |
TCI Chemical | I0478 | Mesityl Iodide | 4028-63-1 | 5G | $18 | 2024-03-01 | Buy |
TCI Chemical | I0478 | Mesityl Iodide | 4028-63-1 | 25G | $62 | 2024-03-01 | Buy |
Alfa Aesar | A15360 | 2-Iodo-1,3,5-trimethylbenzene, 98% | 4028-63-1 | 5g | $51.65 | 2024-03-01 | Buy |
Alfa Aesar | A15360 | 2-Iodo-1,3,5-trimethylbenzene, 98% | 4028-63-1 | 25g | $196.65 | 2024-03-01 | Buy |
2,4,6-Trimethyliodobenzene Chemical Properties,Uses,Production
Chemical Properties
yellow crystalline low melting solid
Uses
Iodomesitylene can be used as a good catalyst for living radical polymerization due to its good molecular weight distribution.
Uses
suzuki reaction
Synthesis Reference(s)
Tetrahedron Letters, 10, p. 2427, 1969 DOI: 10.1017/S0009838800024678
Hazard
May cause eye, skin, and respiratory tract irritation. Light sensitive.
Health effects
Eye: May cause eye irritation.
Skin: May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion: May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
Inhalation: May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May be harmful if inhaled.
Synthesis
The synthesis of 2,4,6-Trimethyliodobenzene is as follows:
A 10 mL glass flask equipped with a magnetic stir bar wascharged with a methyl ketone (1 mmol) and dissolved in MeCN (2 mL). To thermostat solution NH4NO3 (10-25 mol%), I2 (50 mol%) and H2SO4 (aqueous 96% solution, 10-20 mol%) were added and the flask was furtherequipped with a balloon filled with air (1 L) and magnetically stirred at 60 C.The consumption of starting material was monitored by TLC. After completion of the reaction, the mixture was cooled to room temperature, diluted withEtOAc (10 mL), and insoluble material identified as ammonium sulfate filtered off. The filtrate neutralized with NaHCO3 (aqueous 10% solution, 2 mL)and Na2S2O3 (aqueous 10% solution, 2 mL) and phase was separated. The waterphase was washed with EtOAc additionally two times (2 5 mL). The combined organic phase was dried over anhydrous Na2SO4 and the solvent distilled under reduced pressure. The crude product obtained was analyzed by 1H NMR. Finally, the crude product was purified using column chromatography (SiO2, n-hexane/CH2Cl2 elution) and preparative thin layer chromatography to afford purematerial.
storage
Store in a cool, dry place. Store in a tightly closed container. Store protected from light.
2,4,6-Trimethyliodobenzene Preparation Products And Raw materials
Raw materials
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Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Nanjing Triumpharm Co.,Ltd | +86-02586182925 +86-15105172550 | info@triumpharm.com | China | 129 | 58 |
Shaanxi Dideu Medichem Co. Ltd | 18192627656 | 1012@dideu.com | China | 3002 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12446 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20293 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29798 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18628 | 58 |
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9329 | 55 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29888 | 58 |
Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 | alice@crovellbio.com | China | 8820 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39916 | 58 |
View Lastest Price from 2,4,6-Trimethyliodobenzene manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-07-26 | 2,4,6-Trimethyliodobenzene
4028-63-1
|
US $1.00-2.00 / KG | 1KG | 99% | 100000KG | Shaanxi Dideu Medichem Co. Ltd | ||
2024-04-28 | 2,4,6-Trimethyliodobenzene
4028-63-1
|
US $100.00-30.00 / kg | 1kg | 99.93% | 1000kg per week | Ouhuang Engineering Materials (Hubei) Co., Ltd | ||
2023-12-29 | 2,4,6-Trimethyliodobenzene
4028-63-1
|
US $101.00-1.00 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd |
- 2,4,6-Trimethyliodobenzene
4028-63-1
- US $1.00-2.00 / KG
- 99%
- Shaanxi Dideu Medichem Co. Ltd
- 2,4,6-Trimethyliodobenzene
4028-63-1
- US $100.00-30.00 / kg
- 99.93%
- Ouhuang Engineering Materials (Hubei) Co., Ltd
- 2,4,6-Trimethyliodobenzene
4028-63-1
- US $101.00-1.00 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
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