Indium chloride
- CAS No.
- 10025-82-8
- Chemical Name:
- Indium chloride
- Synonyms
- InCl3;Indium trichloride;Indium chloride (InCl3);Indiclor;Indium (III) chloride;Indium trichL;Indium Choride;INDIUM CHLORIDE;Trichloroindium;Indium(III) chL
- CBNumber:
- CB3750120
- Molecular Formula:
- Cl3In
- Molecular Weight:
- 221.18
- MDL Number:
- MFCD00011058
- MOL File:
- 10025-82-8.mol
- MSDS File:
- SDS
Melting point | 262 °C (dec.)(lit.) | ||||||||||||||
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Boiling point | 300°C | ||||||||||||||
Density | 3.46 g/mL at 25 °C(lit.) | ||||||||||||||
vapor pressure | 1Pa at 25℃ | ||||||||||||||
Flash point | 300°C subl. | ||||||||||||||
storage temp. | Inert atmosphere,Room Temperature | ||||||||||||||
solubility | Water (Slightly) | ||||||||||||||
form | powder | ||||||||||||||
Specific Gravity | 3.46 | ||||||||||||||
color | White to off-white | ||||||||||||||
Water Solubility | reacts | ||||||||||||||
Sensitive | Hygroscopic | ||||||||||||||
Crystal Structure | AlCl3 type | ||||||||||||||
crystal system | Monoclinic | ||||||||||||||
Merck | 14,4958 | ||||||||||||||
Space group | C2/m | ||||||||||||||
Lattice constant |
|
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Exposure limits |
ACGIH: TWA 0.1 mg/m3 NIOSH: TWA 0.1 mg/m3 |
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Stability | hygroscopic | ||||||||||||||
InChIKey | PSCMQHVBLHHWTO-UHFFFAOYSA-K | ||||||||||||||
LogP | 5.9 at 22℃ | ||||||||||||||
CAS DataBase Reference | 10025-82-8(CAS DataBase Reference) | ||||||||||||||
EWG's Food Scores | 1 | ||||||||||||||
FDA UNII | 31JB8MKF8Z | ||||||||||||||
NIST Chemistry Reference | Indium trichloride(10025-82-8) | ||||||||||||||
EPA Substance Registry System | Indium chloride (InCl3) (10025-82-8) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS05,GHS08 |
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Signal word | Danger | |||||||||
Hazard statements | H314-H372-H412 | |||||||||
Precautionary statements | P260-P273-P280-P303+P361+P353-P305+P351+P338-P314 | |||||||||
Hazard Codes | C | |||||||||
Risk Statements | 36/37/38-34-29-22 | |||||||||
Safety Statements | 26-36/37/39-45 | |||||||||
RIDADR | UN 3260 8/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | NL1400000 | |||||||||
F | 3-10 | |||||||||
TSCA | Yes | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | III | |||||||||
HS Code | 28273990 | |||||||||
Toxicity | MLD s.c. in rats: 10.2 mg/kg; MLD i.v. in rabbits: 0.64 mg/kg, McCord et al., J. Ind. Hyg. Toxicol. 24, 243 (1942) | |||||||||
NFPA 704 |
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Indium chloride price More Price(61)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 203440 | Indium(III) chloride 99.999% trace metals basis | 10025-82-8 | 1g | $45.1 | 2024-03-01 | Buy |
Sigma-Aldrich | 203440 | Indium(III) chloride 99.999% trace metals basis | 10025-82-8 | 10g | $197 | 2024-03-01 | Buy |
TCI Chemical | I0778 | Indium(III) Chloride Anhydrous >99.0%(T) | 10025-82-8 | 5g | $47 | 2024-03-01 | Buy |
TCI Chemical | I0778 | Indium(III) Chloride Anhydrous >99.0%(T) | 10025-82-8 | 25g | $140 | 2024-03-01 | Buy |
Alfa Aesar | 011856 | Indium(III) chloride, anhydrous, 99.999% (metals basis) | 10025-82-8 | 1g | $44.5 | 2023-06-20 | Buy |
Indium chloride Chemical Properties,Uses,Production
Description
Indium chloride is a useful catalyst for aqueous organic reactions including C-C bond formation, aldol reaction, Friedel-Crafts acylation, Diels-Alder reaction and reduction1-4. It is an efficient, mild, Lewis acid for organic synthesis. It is an efficient catalyst for thioacetalization and its chemoselectivity. It can also catalyze the enantioselective ring-opening of meso-aziridines with thiols. Moreover, it can act as a highly efficient catalyst in water for the preparation of furyl glycosides.
Chemical Properties
white crystalline powder
Hygroscopic. Decomposes in
water to InCl3 and In. M.p. 235°C; decomposes below the m.p.,
apparently to InCl3 and InCl; b.p. ~570°C; d 3.65. Rhombic
crystals.
Uses
Indium(III) chloride is used as catalyst for aqueous organic reactions including C-C bond formation, aldol reactions, and reductions and for organic synthesis.
Uses
In electroplating using a solution of the salt with dextrose and NaCN. This solution is stable, though it turns dark on standing and deposits a mud which, however, contains no indium.
Uses
Catalyzes the enantioselective ring-opening of meso-aziridines with thiols.1,2 A highly efficient catalyst in water for the preparation of furyl glycosides.3
Production Methods
According to Klemm, metallic In is oxidized in InCl3 in a stream of Cl2, which has been carefully dried with concentrated H2SO4 and P2O5. A thoroughly dried quartz apparatus whose components have been fused or connected by ground joints is used. Chlorination proceeds rather vigorously at first, with a pale glow, and it proceeds through the mono- and dichloride steps. These compounds are melts. The end product of the chlorination, InCl3, sublimes around 600°C as lustrous spangles which appear on the walls of the receiver. The Indium chloride (LnCl3) may be purified by subliming in a stream of N2 (or CO2) to which some Cl2 has been added. The sublimate can cool in a stream of inert, Cl2-free gas to remove excess chlorine.
General Description
Indium(III) chloride (InCl3) is an indium halide that is a Lewis acid in a variety of organic reactions.
Hazard
See indium.
Purification Methods
The anhydrous salt forms yellow deliquescent crystals which can be sublimed at 600o in the presence of Cl2/N2 (1:1) [does not melt]. It is resublimed in the presence of Cl2/N2 (1:10) and finally heated to 150o to expel excess Cl2. It is soluble in H2O and should be stored in a tightly closed container. [Baxter & Alter J Am Chem Soc 55 1943 1933.]
Indium chloride Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12446 | 58 |
Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5873 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29798 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18628 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21667 | 55 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32836 | 60 |
Zjartschem | +86-571 87238903 | jocelynpan@zjarts.com | CHINA | 993 | 58 |
Shanghai Zheyan Biotech Co., Ltd. | 18017610038 | zheyansh@163.com | CHINA | 3620 | 58 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29888 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
View Lastest Price from Indium chloride manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-08-15 | Indium chloride
10025-82-8
|
US $30.00-10.00 / kg | 1kg | 0.99 | 10 tons | Hebei Yanxi Chemical Co., Ltd. | ||
2023-10-10 | Indium chloride
10025-82-8
|
US $96.00 / KG | 25KG | 99.99% | 200ton | Hebei Mojin Biotechnology Co., Ltd | ||
2023-09-06 | Indium chloride
10025-82-8
|
US $0.00-0.00 / KG | 1KG | 99% | 500000kg | Hebei Guanlang Biotechnology Co., Ltd. |
- Indium chloride
10025-82-8
- US $30.00-10.00 / kg
- 0.99
- Hebei Yanxi Chemical Co., Ltd.
- Indium chloride
10025-82-8
- US $96.00 / KG
- 99.99%
- Hebei Mojin Biotechnology Co., Ltd
- Indium chloride
10025-82-8
- US $0.00-0.00 / KG
- 99%
- Hebei Guanlang Biotechnology Co., Ltd.
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