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Phenyl sulfoxide

CAS No.
945-51-7
Chemical Name:
Phenyl sulfoxide
Synonyms
PhS(O)Ph;thionylbenzene;PHENYL SULFOXIDE;Diphenyl sulfoxid;PHENYL SULPHOXIDE;sulfinyldibenzene;1,1'-sulfinylbis-;sulfoxide,diphenyl;DIPHENYL SULFOXIDE;Two phenylsulfoxide
CBNumber:
CB5187724
Molecular Formula:
C12H10OS
Molecular Weight:
202.27
MDL Number:
MFCD00002085
MOL File:
945-51-7.mol
MSDS File:
SDS
Last updated:2024-04-23 16:18:34

Phenyl sulfoxide Properties

Melting point 69-71 °C (lit.)
Boiling point 206-208 °C/13 mmHg (lit.)
Density 1.1833 (rough estimate)
refractive index 1.6090 (estimate)
Flash point 206-208°C/13mm
storage temp. Sealed in dry,Room Temperature
solubility Chloroform (Slightly), DMSO (Slightly)
form Crystalline Powder
color White to off-white
Water Solubility Soluble in water. Soluble in most organic solvents.
BRN 1908444
InChIKey JJHHIJFTHRNPIK-UHFFFAOYSA-N
CAS DataBase Reference 945-51-7(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 4V290005U9
NIST Chemistry Reference Diphenyl sulfoxide(945-51-7)
EPA Substance Registry System Benzene, 1,1'-sulfinylbis- (945-51-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS02
Signal word  Danger
Hazard statements  H225
Precautionary statements  P210-P403+P235
Hazard Codes  Xi
Safety Statements  22-24/25
WGK Germany  3
RTECS  DA9185000
Hazard Note  Irritant
TSCA  Yes
HS Code  29309070
NFPA 704
0
1 0

Phenyl sulfoxide price More Price(39)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich P35405 Diphenyl sulfoxide 96% 945-51-7 25g $62.4 2024-03-01 Buy
Sigma-Aldrich P35405 Diphenyl sulfoxide 96% 945-51-7 100g $108 2024-03-01 Buy
TCI Chemical D1002 Diphenyl Sulfoxide >99.0%(GC) 945-51-7 5g $18 2024-03-01 Buy
TCI Chemical D1002 Diphenyl Sulfoxide >99.0%(GC) 945-51-7 25g $36 2024-03-01 Buy
Alfa Aesar B22135 Diphenyl sulfoxide, 98+% 945-51-7 25g $48.65 2024-03-01 Buy
Product number Packaging Price Buy
P35405 25g $62.4 Buy
P35405 100g $108 Buy
D1002 5g $18 Buy
D1002 25g $36 Buy
B22135 25g $48.65 Buy

Phenyl sulfoxide Chemical Properties,Uses,Production

Chemical Properties

white to off-white crystalline powder

Uses

Diphenyl sulfoxide is a reagent used as an oxidant and hydroxyl activator in combination with a variety of electrophilic reagents. Efficient glycosidation of a phenyl thiosialoside donor with diphenyl sulfoxide and triflic anhydride in dichloromethane was reported. Direct glycosylations with 1-hydroxy glycosyl donors is made using trifluoromethanesulfonic anhydride and diphenyl sulfoxide. The preparation of triarylsulfonium halides was by the action of aryl Grignard reagents on diphenyl sulfoxide.

Definition

ChEBI: Diphenyl sulfoxide is a sulfoxide.

Synthesis Reference(s)

Journal of the American Chemical Society, 114, p. 6269, 1992 DOI: 10.1021/ja00041a069
Tetrahedron Letters, 31, p. 4533, 1990 DOI: 10.1016/S0040-4039(00)97667-6

139-66-2
945-51-7
127-63-9
Synthesis of Phenyl sulfoxide from Diphenyl sulfide
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View Lastest Price from Phenyl sulfoxide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Phenyl sulfoxide pictures 2024-04-23 Phenyl sulfoxide
945-51-7
US $50.00 / kg 1kg 99.10% 50000kg Ouhuang Engineering Materials (Hubei) Co., Ltd
Phenyl sulfoxide pictures 2023-07-28 Phenyl sulfoxide
945-51-7
US $10.00 / KG 1KG 99% 5000000kg Hebei Mojin Biotechnology Co., Ltd
Phenyl Sulfoxide pictures 2023-05-10 Phenyl Sulfoxide
945-51-7
US $5.00-2.00 / KG 1KG 99% 10000kg Hebei Guanlang Biotechnology Co,.LTD
  • Phenyl sulfoxide pictures
  • Phenyl sulfoxide
    945-51-7
  • US $50.00 / kg
  • 99.10%
  • Ouhuang Engineering Materials (Hubei) Co., Ltd
  • Phenyl Sulfoxide pictures
  • Phenyl Sulfoxide
    945-51-7
  • US $5.00-2.00 / KG
  • 99%
  • Hebei Guanlang Biotechnology Co,.LTD
1,1’-sulfinylbis-benzen 1,1’-sulfinylbis-Benzene Diphenyl sulfoxide,Phenyl sulfoxide Phenyl sulfoxide, 97% 100GR Phenyl sulfoxide, 97% 25GR Diphenyl sulfoxid (benzenesulfinyl)benzene bis-(phenyl)-sulfoxide Two phenylsulfoxide Benzene, 1,1'-sulfinylbis- Phenylsulfinylbenzene Sulfoxide, diphenyl sulfoxide,diphenyl DIPHENYL SULFOXIDE DIPHENYL SULPHOXIDE PHENYL SULPHOXIDE PHENYL SULFOXIDE DIPHENYL SULFOXIDE PESTANAL DiphenylSulphoxide98% Diphenyl sulfoxide, 97+% Diphenyl Sulphoxide 98% Diphenylsulphoxide,97% thionylbenzene Diphenyl sulfoxide, 98+% sulfinyldibenzene Phenyl sulfoxide, 97% 25g PhS(O)Ph Phenyl sulfoxide,97% 1,1'-sulfinylbis- Diphenyl Sulfoxide > 945-51-7 C12H10O1S1 C6H52SO C12H10OS Sulfoxides Sulfur Compounds Organic Building Blocks Building Blocks Reagents for Oligosaccharide Synthesis Building Blocks Chemical Synthesis Organic Building Blocks Sulfoxides Sulfur Compounds fine chemicals Biochemistry Reagents for Oligosaccharide Synthesis bc0001