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(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE structure

CAS No.: 1517-82-4

Chemical Name:: (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE

Synonyms: (S)-p-toL;(1R,2S,5R)-(-)-MenthyL;menthyl p-toluenesulfinate;(S)-(-)-MENTHYL P-TOLUENESULFINATE;Menthyl (S)-4-methylbenzenesulfinate;(?-(1R)-Menthyl (S)-p-toluenesulfinate;(-)-Menthyl (S)-4-methylbenzenesulfinate;(-)-(1R)-MENTHYL (S)-TOLUENE-4-SULFINATE;(-)-(1R)-Menthyl (S)-toluene-4-sulfinate;(1R,2S,5R)-MENTHYL (S)-P-TOLUENESULFINATE

CBNumber:: CB6129035

Molecular Formula:: C17H26O2S

Molecular Weight:: 294.45

MDL Number:: MFCD32173978

MOL File:: 1517-82-4.mol

MSDS File:: SDS

Last updated:2023-04-23 13:52:06

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(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Properties

Melting point	99-104 °C
Boiling point	402.3±38.0 °C(Predicted)
Density	1.08
refractive index	-199 ° (C=1.5, Acetone)
storage temp.	-20°C
solubility	Acetone (Slightly), Chloroform (Slightly)
form	Solution
color	Yellow to brown or gray
optical activity	[α]20/D 195°, c = 2 in acetone
BRN	3207468

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H302-H315-H319-H335
Precautionary statements	P261-P305+P351+P338
Safety Statements	22-24/25
WGK Germany	3
HS Code	29309090

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE price More Price(27)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	278750	(1R,2S,5R)-(?)-Menthyl (S)-p-toluenesulfinate 98%	1517-82-4	10g	$182	2023-06-20	Buy
TCI Chemical	M1044	(1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate >98.0%(HPLC)	1517-82-4	5g	$115	2024-03-01	Buy
TCI Chemical	M1044	(1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate >98.0%(HPLC)	1517-82-4	25g	$390	2024-03-01	Buy
TRC	M220400	(1R,2S,5R)-(?)-Menthyl (S)-p-toluenesulfinate	1517-82-4	2.5g	$70	2021-12-16	Buy
ChemScene	CS-M1307	(S)-((1R,2S,5R)-2-isopropyl-5-methylcyclohexyl)4-methylbenzenesulfinate	1517-82-4	5g	$75	2021-12-16	Buy

Product number	Packaging	Price	Buy
278750	10g	$182	Buy
M1044	5g	$115	Buy
M1044	25g	$390	Buy
M220400	2.5g	$70	Buy
CS-M1307	5g	$75	Buy

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Chemical Properties,Uses,Production

Chemical Properties

White crystalline powder

Uses

(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate can react with:

metal ketimines to form enantiopure sulfinimines
p-(methylthio)benzaldehyde to form (S)-(-)-N-(4-methylthiobenzylidene)-p-toluenesulfinimine

Uses

(1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate is a reactant used in the synthesis of sulfoxide pincer complexes of Mg, Rh and Ir.

General Description

(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate is mainly used for the introduction of p-toluenesulfinyl group in asymmetric synthesis.

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE synthesis

Synthesis of (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE from P-TOLUENESULFINIC ACID and L-Menthol

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Preparation Products And Raw materials

Raw materials

Methyl (R)-2-Amino-2-benzyl-3,3,3-trifluoropropanoate Benzene, 1-methyl-4-[[(4-methylphenyl)sulfinyl]sulfonyl]- P-TOLUENESULFINYL CHLORIDE (S)-4-Methylbezenesulfinamide P-TOLUENESULFINIC ACID

Tosyl chloride L-Menthol

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Preparation Products

Benzenesulfinic acid, 4-methyl-, 5-methyl-2-(1-methylethyl)cyclohexyl ester p-Toluenethiosulfonic acid S-p-tolyl ester (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Suppliers

Global( 138)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	15928	58
Shanghai Arbor Chemical Co., Ltd.	021-60451682	act@arborchemical.com	CHINA	906	58
Shenzhen Nexconn Pharmatechs Ltd	+86-755-89396905 +86-15013857715	admin@nexconn.com	China	10248	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63711	58
career henan chemical co	+86-0371-86658258 15093356674;	factory@coreychem.com	China	29826	58
Fuxin Pharmaceutical	+86-021-021-50872116 +8613122107989	contact@fuxinpharm.com	China	10297	58
Hefei TNJ Chemical Industry Co.,Ltd.	0551-65418671	sales@tnjchem.com	China	34572	58
Alfa Chemistry		info@alfa-chemistry.com	United States	2344	58
Aston Chemical	13000000000	sales@astonchem.com	United States	1634	58
Dayang Chem (Hangzhou) Co.,Ltd.	571-88938639 +8617705817739	info@dycnchem.com	CHINA	52867	58

Supplier	Advantage
Shanghai Daken Advanced Materials Co.,Ltd	58
Shanghai Arbor Chemical Co., Ltd.	58
Shenzhen Nexconn Pharmatechs Ltd	58
Alchem Pharmtech,Inc.	58
career henan chemical co	58
Fuxin Pharmaceutical	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Alfa Chemistry	58
Aston Chemical	58
Dayang Chem (Hangzhou) Co.,Ltd.	58

View Lastest Price from (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2020-01-09	(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE 1517-82-4	US $2.00 / KG	1g	98%min	ask	Career Henan Chemical Co
	2019-12-23	(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE	US $1.00 / g	100g	99%	G/KG/T	Career Henan Chemical Co

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
1517-82-4
US $2.00 / KG
98%min
Career Henan Chemical Co

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
US $1.00 / g
99%
Career Henan Chemical Co

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Spectrum

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE(1517-82-4)MS (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE(1517-82-4)¹HNMR (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE(1517-82-4)IR1 (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE(1517-82-4)Raman

1517-82-4((1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE)Related Search:

p-Toluenesulfonic acid P-TOLUENESULFINIC ACID (1S,2R,5S)-MENTHYL (R)-P-TOLUENESULFINATE,(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE,(+)-(1S)-Menthyl (R)-p-toluenesulfinate DL-Menthol 2,5-DIMETHYLCYCLOHEXANOL

3,7-DIMETHYL-1-OCTANOL METHYL P-TOLUENESULFINATE (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE 2-Methylcyclohexanol (+)-MENTHOL

DL-Menthol 2-ETHYLCYCLOHEXANOL

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(S)-(-)-Menthyl p-toluenesulfinate, (-)-(1R)-Menthyl (S)-p-toluenesulfinate 4-Methylbenzenesulfinic acid (1R)-2α-isopropyl-5β-methylcyclohexane-1β-yl ester 4-Methylbenzenesulfinic acid (1R,3R,4S)-p-menthane-3-yl ester p-Toluenesulfinic acid (1R,1β)-2α-isopropyl-5β-methylcyclohexyl ester p-Toluenesulfinic acid (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl ester p-Toluenesulfinic acid (1R,3R,4S)-menthyl ester p-Toluenesulfinic acid (1R,3R,4S)-p-menthane-3-yl ester (1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate,98% [S(S)]-4-Methylbenzenesulfinic acid (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester Menthyl (S)-4-methylbenzenesulfinate (S)-((1R,2S,5R)-2-isopropyl-5-Methylcyclohexyl) 4-Methylbenzenesulfinate (-)-Menthyl (S)-4-methylbenzenesulfinate (1S)-2-Isopropyl-5-methylcyclohexyl 4-methylbenzenesulfinate (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFITE (-)-(1R)-MENTHYL (S)-TOLUENE-4-SULFINATE (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE (1R,2S,5R)-MENTHYL (S)-P-TOLUENESULFINATE (S)-(-)-MENTHYL P-TOLUENESULFINATE (S)-(-)-P-TOLUENESULFINIC ACID L-MENTHYL ESTER (?-(1R)-Menthyl (S)-p-toluenesulfinate menthyl p-toluenesulfinate Benzenesulfinic acid, 4-methyl-, (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester, [S(S)]- (S)-p-toL (1R,2S,5R)-(-)-MenthyL (1R,2S,5R)-(-)-Menthyl(S)-p-Toluenesulfinate> 4-Methylbenzenesulfinic acid (1R,3R,4S)-p-menthane-3- (-)-(1R)-Menthyl (S)-toluene-4-sulfinate 1517-82-4 Organic Building Blocks Sulfonates/Sulfinates Chiral Building Blocks Terpenes Monocyclic Monoterpenes Asymmetric Synthesis Chiral Building Blocks Organic Building Blocks Sulfonates/Sulfinates chiral Asymmetric Synthesis Biochemistry Monocyclic Monoterpenes Synthetic Organic Chemistry Terpenes