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Tris(4-fluorophenyl)phosphine

Tris(4-fluorophenyl)phosphine Structure
Tris(4-fluorophenyl)phosphine structure
CAS No.
18437-78-0
Chemical Name:
Tris(4-fluorophenyl)phosphine
Synonyms
Tris(4-fL;Tris(4-fluorophe;Tris(4-fluorophenyl);TRI(4-FLUOROPHENYL)PHOSPHINE;Tris(4-Flurophenyl)Phosphine;Tri-(p-fluorophenyl)phosphine;TRIS(P-FLUOROPHENYL)PHOSPHINE;TRIS(4-FLUOROPHENYL)PHOSPHINE;tris(4-fluorophenyl)phosphane;Phosphine, tris(p-fluorophenyl)-
CBNumber:
CB6286703
Molecular Formula:
C18H12F3P
Molecular Weight:
316.26
MDL Number:
MFCD00013553
MOL File:
18437-78-0.mol
MSDS File:
SDS
Last updated:2023-11-17 13:52:59
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Tris(4-fluorophenyl)phosphine Properties

Melting point 79-83 °C(lit.)
Boiling point 160°C/0.1mmHg(lit.)
storage temp. Inert atmosphere,Room Temperature
form Crystalline Powder
color White to very slightly yellow
Water Solubility Insoluble in water.
Sensitive Air Sensitive
BRN 919838
InChI InChI=1S/C18H12F3P/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H
InChIKey GEPJPYNDFSOARB-UHFFFAOYSA-N
SMILES P(C1=CC=C(F)C=C1)(C1=CC=C(F)C=C1)C1=CC=C(F)C=C1
CAS DataBase Reference 18437-78-0(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
HazardClass  IRRITANT
HS Code  29319090
NFPA 704
1
2 0

Tris(4-fluorophenyl)phosphine price More Price(27)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 395099 Tris(4-fluorophenyl)phosphine 98% 18437-78-0 5g $153 2024-03-01 Buy
TCI Chemical T2900 Tris(4-fluorophenyl)phosphine >98.0%(GC) 18437-78-0 5g $143 2024-03-01 Buy
Alfa Aesar A14813 Tris(4-fluorophenyl)phosphine 98% 18437-78-0 1g $27.65 2024-03-01 Buy
Alfa Aesar A14813 Tris(4-fluorophenyl)phosphine 98% 18437-78-0 5g $108.65 2024-03-01 Buy
Strem Chemicals 15-7890 Tris(p-fluorophenyl)phosphine, 99% 18437-78-0 1g $58 2024-03-01 Buy
Product number Packaging Price Buy
395099 5g $153 Buy
T2900 5g $143 Buy
A14813 1g $27.65 Buy
A14813 5g $108.65 Buy
15-7890 1g $58 Buy

Tris(4-fluorophenyl)phosphine Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powde

Uses

Ligand for rhodium-catalyzed oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.

Rhodium-Catalyzed Oxygenative Addition to Terminal Alkynes for the Synthesis of Esters, Amides, and Carboxylic Acids

Uses

Tris(4-fluorophenyl)phosphine, is an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff.

Uses

Tris(4-fluorophenyl)phosphine (TFPP) and tris(2,2,2- trifluoroethyl) phosphite (TTFP) were used as flame-retarding additives in Li-ion battery clectrolytes.
Ligand for rhodium-catalyzed oxygenative addition to terminal alkynes for a greener synthesis esters, amides, and carboxylic acids.

Preparation

with 4-bromofluorobenzene, magnesium, and phosphorous (III) trichloride.3 Alternatively, reduction of tris(4-fluorophenyl)phosphine oxide with an iron catalyst.

General Description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Synthesis

Tris (4-fluorophenyl)phosphine oxide could be used as a starting material to synthesize Tris(4-fluorophenyl)phosphine. Into the reactor were added 0.2 mmol of tris(4-fluorophenyl)phosphine oxide, 0.36 mmol of trifluoroacetic anhydride, and 1 ml of dioxane as a solvent. Stir at room temperature under a nitrogen atmosphere for 30 min; after the reaction, continue adding 0.2 mmol of sodium bicarbonate, 0.24 mmol of 15-Crown-5, and 1.2 mmol of sodium hydride under a nitrogen environment. Under 150 ℃, stir for 24 hours, stop the reaction, cool to room temperature, and distilled under reduced pressure to remove the solvent. The crude product is separated by column chromatography to obtain Tris(4-fluorophenyl)phosphine with a yield of 74%.
Tris(4-fluorophenyl)phosphine

Tris(4-fluorophenyl)phosphine Preparation Products And Raw materials

Raw materials

Preparation Products

Tris(4-fluorophenyl)phosphine Suppliers

Global( 203)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd. 		571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 15932 58
Hangzhou FandaChem Co.,Ltd. 		008657128800458; +8615858145714 fandachem@gmail.com China 9348 55
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd. 		18871490254 linda@hubeijusheng.com CHINA 28180 58
Accela ChemBio Inc. 		(+1)-858-699-3322 info@accelachem.com United States 19965 58
Wuhan Pengo Technology.,Ltd. 		+86-27-81330736 +86-13628634921 sunny.w@boronicgroup.com CHINA 171 58
Chongqing Chemdad Co., Ltd 		+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
Wuhan Chemwish Technology Co., Ltd 		027-67849912 sales@chemwish.com CHINA 10828 58
CONIER CHEM AND PHARMA LIMITED 		+8618523575427 sales@conier.com China 49390 58
Supplier Advantage
Capot Chemical Co.,Ltd. 		60
Shanghai Daken Advanced Materials Co.,Ltd 		58
Hangzhou FandaChem Co.,Ltd. 		55
career henan chemical co 		58
Hubei Jusheng Technology Co.,Ltd. 		58
Accela ChemBio Inc. 		58
Wuhan Pengo Technology.,Ltd. 		58
Chongqing Chemdad Co., Ltd 		58
Wuhan Chemwish Technology Co., Ltd 		58
CONIER CHEM AND PHARMA LIMITED 		58

View Lastest Price from Tris(4-fluorophenyl)phosphine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Tris(4-fluorophenyl)phosphine pictures 2023-02-04 Tris(4-fluorophenyl)phosphine
18437-78-0
 US $0.00 / G 100G 98%min 30kg/month WUHAN FORTUNA CHEMICAL CO., LTD
Tris(4-fluorophenyl)phosphine pictures 2020-03-16 Tris(4-fluorophenyl)phosphine
18437-78-0
 US $1.00-0.00 / KG 1KG 99% 20 tons Shaanxi Dideu Medichem Co. Ltd
TRIS(4-FLUOROPHENYL)PHOSPHINE pictures 2019-07-06 TRIS(4-FLUOROPHENYL)PHOSPHINE
18437-78-0
 US $1.00 / KG 1G 99% 1MT Career Henan Chemical Co

Tris(4-fluorophenyl)phosphine Spectrum

Tris(4-fluorophenyl)phosphine(18437-78-0)1HNMRTris(4-fluorophenyl)phosphine(18437-78-0)IRTris(4-fluorophenyl)phosphine(18437-78-0)Raman

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