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METHYL (TRIMETHYLSILYL)ACETATE

CAS No.
2916-76-9
Chemical Name:
METHYL (TRIMETHYLSILYL)ACETATE
Synonyms
Methyl 2-(triMethylsilyl)acetate;METHYLTRIMETHYLSILICATE;METHYL (TRIMETHYLSILYL)ACETATE;Methyl (trimethylsilyl)acetate,98%;Trimethylsilylacetic acid methyl ester;2-(Trimethylsilyl)acetic acid methyl ester;Acetic acid, 2-(trimethylsilyl)-, methyl ester;2-[Dimethyl(methyl)silyl]acetic acid methyl ester
CBNumber:
CB7704732
Molecular Formula:
C6H14O2Si
Molecular Weight:
146.26
MDL Number:
MFCD00008450
MOL File:
2916-76-9.mol
Last updated:2022-11-11 11:01:00

METHYL (TRIMETHYLSILYL)ACETATE Properties

Boiling point 38-39 °C13 mm Hg(lit.)
Density 0.891 g/mL at 25 °C(lit.)
refractive index n20/D 1.414(lit.)
Flash point 91 °F
storage temp. Flammables area
Specific Gravity 0.890
Hydrolytic Sensitivity 2: reacts with aqueous acid
BRN 1098961

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Warning
Hazard statements  H226-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Hazard Codes  F,Xi
Risk Statements  11-36/37/38
Safety Statements  16-26-36
RIDADR  UN 3272 3/PG 3
WGK Germany  3
10-21
TSCA  No
HazardClass  3.1
PackingGroup  II
HS Code  29319090
NFPA 704
3
1 1

METHYL (TRIMETHYLSILYL)ACETATE price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 234966 Methyl trimethylsilylacetate 97% 2916-76-9 5g $79.6 2023-01-07 Buy
TRC M322525 Methyl2-(Trimethylsilyl)acetate 2916-76-9 1g $45 2021-12-16 Buy
Frontier Specialty Chemicals JK283775 Methyl trimethylsilylacetate 98% 2916-76-9 5g $67 2021-12-16 Buy
AK Scientific 8796AJ Methyl trimethylsilylacetate 2916-76-9 5g $117 2021-12-16 Buy
Frontier Specialty Chemicals JK283775 Methyl trimethylsilylacetate 98% 2916-76-9 25g $192 2021-12-16 Buy
Product number Packaging Price Buy
234966 5g $79.6 Buy
M322525 1g $45 Buy
JK283775 5g $67 Buy
8796AJ 5g $117 Buy
JK283775 25g $192 Buy

METHYL (TRIMETHYLSILYL)ACETATE Chemical Properties,Uses,Production

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

Methyl 2-(Trimethylsilyl)acetate is a useful compound in the organic synthesis.

General Description

Methyl trimethylsilylacetate on reaction with lithium diisopropylamide in THF at -78°C yields methyl lithiotrimethylsilylacetate. It also undergoes Peterson olefination to yield mainly Z-isomers of steroid 17β-side chain methyl acrylates.

Purification Methods

Methyl trimethylsilylacetate [2916-76-9] M 146.3, b 65-68o/50mm, d 4 0.89. Dissolve it in Et2O, shaken with 1M HCl, wash with H2O, aqueous saturated NaHCO3, H2O again, and dry it (a precipitate may be formed in the NaHCO3 solution and should be drawn off and discarded). The solvent is distilled off, and the residue is fractionated through a good column. IR (CHCl3) max 1728cm1 . [Fessenden & Fessenden J Org Chem 32 3535 1967, Matsuda et al. J Org Chem 45 237 1980, Beilstein 4 III 1855, 4 IV 3974 for Et ester.]

METHYL (TRIMETHYLSILYL)ACETATE Preparation Products And Raw materials

Global( 70)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15932 58
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9347 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32480 60
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58
career henan chemical co
+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
Hubei Co-Formula Material Tech Co., Ltd.
+86-27-84459282 sales@cfmats.com CHINA 882 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671 sales@tnjchem.com China 34572 58
WinWin Chemical CO., Limited
+86-0577-64498589 +8615325081899 sales@win-winchemical.com China 13854 58
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739 info@dycnchem.com CHINA 52867 58
CD Chemical Group Limited
+8615986615575 info@codchem.com China 20356 58

View Lastest Price from METHYL (TRIMETHYLSILYL)ACETATE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
	Methyl (trimethylsilyl)acetate pictures 2019-12-29 Methyl (trimethylsilyl)acetate
2916-76-9
US $1.00 / g 1g Min98% HPLC g/kg/ton Career Henan Chemical Co
METHYLTRIMETHYLSILICATE METHYL (TRIMETHYLSILYL)ACETATE 2-(Trimethylsilyl)acetic acid methyl ester 2-[Dimethyl(methyl)silyl]acetic acid methyl ester Trimethylsilylacetic acid methyl ester Methyl (trimethylsilyl)acetate,98% Acetic acid, 2-(trimethylsilyl)-, methyl ester Methyl 2-(triMethylsilyl)acetate 2916-76-9 2961-76-9 CH33SiCH2CO2CH3 Esters Organic Building Blocks Building Blocks C6 to C7 Carbonyl Compounds C6 to C7 Carbonyl Compounds Esters