ARSENAZO III DISODIUM SALT
- CAS No.
- 62337-00-2
- Chemical Name:
- ARSENAZO III DISODIUM SALT
- Synonyms
- ARSENAZO III DISODIUM SALT;Arsenazo III disodium salt p.a.;ARSENAZO III DISODIUM SALT, REAG.;2,7-BIS(O-ARSONOPHENYLAZO) CHROMOTROPIC ACID;disodium 3,6-bis[(o-arsonophenyl)azo]-4,5-dihydroxynaphthalene-2,7-disulphonate;2,7-BIS(2-ARSENOPHENYLAZO)-1,8-DIHYDROXYNAPHTALENE-3,6-DISULFONIC ACID, DISODIUM SALT;3,6-Bis[(2-arsonophenyl)azo]-4,5-dihydroxy-2,7-naphthalenedisulfonic acid disodium salt;(3E,6E)-3,6-bis[(2-arsonophenyl)hydrazinylidene]-4,5-dioxonaphthalene-2,7-disulfonic acid;3,6-bis(2,2'-arsonophenylazo)-4,5-dihydroxy-2,7-naphthalenedisulfonic acid, disodium salt;3,6-Bis[2-(2-arsonophenyl)diazenyl]-4,5-dihydroxy-2,7-naphthalenedisulfonic Acid SodiuM Salt
- CBNumber:
- CB8251091
- Molecular Formula:
- C22H19As2N4NaO14S2
- Molecular Weight:
- 800.36
- MDL Number:
- MFCD00003936
- MOL File:
- 62337-00-2.mol
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS06,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H301-H331-H400-H410 | |||||||||
| Precautionary statements | P261-P301+P310a-P304+P340-P311a-P405-P501a | |||||||||
| Hazard Codes | T,N | |||||||||
| Risk Statements | 23/25-50/53 | |||||||||
| Safety Statements | 20/21-28-45-60-61 | |||||||||
| RIDADR | UN 3465 6.1/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | II | |||||||||
| NFPA 704 |
|
ARSENAZO III DISODIUM SALT price More Price(7)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Alfa Aesar | A11838 | Arsenazo III disodium salt | 62337-00-2 | 1g | $41.8 | 2021-12-16 | Buy |
| Alfa Aesar | A11838 | Arsenazo III disodium salt | 62337-00-2 | 5g | $139 | 2021-12-16 | Buy |
| Alfa Aesar | A11838 | Arsenazo III disodium salt | 62337-00-2 | 25g | $497 | 2021-12-16 | Buy |
| TRC | A774200 | Arsenazo III disodium salt | 62337-00-2 | 100mg | $155 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | OGM0001828 | ARSENAZO(III)DISODIUM SALT 98.00% | 62337-00-2 | 100MG | $739.2 | 2021-12-16 | Buy |
ARSENAZO III DISODIUM SALT Chemical Properties,Uses,Production
Chemical Properties
dark brown to brownish-black crystalline powder
Uses
Arsenazo-III is a diazo dye reagent used in the spectrophotometric determination of aluminum, gallium and indium. Toxic if swallowed. Toxic if inhaled. Very toxic to aquatic life.
Uses
Arsenazo III disodium salt is a diazo dye reagent used in the spectrophotometric determination of aluminum, gallium and indium. Further, it is used in the complexometric determination of lanthanides, thallium, scandium thorium, uranium and yttrium. In addition to this, it acts as a metal indicator and form specifically colored metal ion complexes in aqueous media.
Purification Methods
Contaminants include monoazo derivatives, starting materials for synthesis and by-products. It is partially purified by precipitation of the dye from aqueous alkali on addition of HCl. More thorough purification is achieved by taking a 2g sample in 15-25mL of 5% aqueous NH3 and filter. Add 10mL HCl (1:1) to the filtrate to precipitate the dye. Repeat the procedure and dissolve the solid dye (0.5g) in 7mL of a 1:1:1 mixture of n-propanol/conc NH3/water at 50o. After cooling, filter the solution and chromatograph the filtrate through a cellulose column using a 3:1:1 mixture of n-propanol/conc NH3/water as eluent. Collect the blue band and evaporate it to 10-15mL below 80o, then add 10mL of conc HCl to precipitate pure Arsenazo III. Wash it with EtOH and dry it in air [Borak et al. Talanta 17 215 1970]. The sodium salt is then obtained by dissolving it in the equivalent amount of dilute NaOH and freeze-drying. The purity of the dye can be checked by paper chromatography using M HCl as eluent. It is used for the estimation of Th, U, Zr, Cd and Zn [Michaylova & Yuroukova Anal Chim Acta 68 73 1974.]
ARSENAZO III DISODIUM SALT Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49390 | 58 |
| Alfa Chemistry | info@alfa-chemistry.com | United States | 2344 | 58 | |
| LEAPCHEM CO., LTD. | +86-852-30606658 | market18@leapchem.com | China | 43348 | 58 |
| J & K SCIENTIFIC LTD. | 010-82848833 400-666-7788 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Meryer (Shanghai) Chemical Technology Co., Ltd. | 4006608290; 18621169109 | market03@meryer.com | China | 40241 | 62 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30132 | 84 |
| Energy Chemical | 021-021-58432009 400-005-6266 | sales8178@energy-chemical.com | China | 44751 | 61 |
| Chemsky (shanghai) International Co.,Ltd | 021-50135380 | shchemsky@sina.com | China | 15421 | 60 |
| Sinopharm Chemical Reagent Co,Ltd. | 86-21-63210123 | sj_scrc@sinopharm.com | China | 9823 | 79 |
| Aikon International Limited | 025-58859352 18068836627 | sales01@aikonchem.com | China | 15085 | 58 |