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Vinylene carbonate

CAS No.
872-36-6
Chemical Name:
Vinylene carbonate
Synonyms
1,3-DIOXOL-2-ONE;vinyl carbonate;Vinylene carbote;The ethylene carbonate;Vinylene carbonate, 99%, water ≤50 ppm, stabilized with 90 ppm BHT;1,3-Dioxo-2-one;WITH HYDROQUINONE;Vinylene carbonat;VINYLENE CARBONATE;2H-1,3-dioxol-2-one
CBNumber:
CB9119200
Molecular Formula:
C3H2O3
Molecular Weight:
86.05
MDL Number:
MFCD00005380
MOL File:
872-36-6.mol
Last updated:2024-03-26 14:13:49

Vinylene carbonate Properties

Melting point 19-22 °C(lit.)
Boiling point 162 °C(lit.)
Density 1.360 g/mL at 20 °C
vapor pressure 3.35hPa at 25℃
refractive index n20/D 1.421(lit.)
Flash point 163 °F
storage temp. 2-8°C
solubility 11.5 g/100 mL
form Liquid
color Colorless to pale yellow
Specific Gravity 1.355
Water Solubility 11.5 g/100 mL
Sensitive Moisture Sensitive
BRN 105683
InChIKey VAYTZRYEBVHVLE-UHFFFAOYSA-N
LogP -0.36 at 20℃
CAS DataBase Reference 872-36-6(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 1X0ZZF9WFV
NIST Chemistry Reference 1,3-Dioxol-2-one(872-36-6)
EPA Substance Registry System 1,3-Dioxol-2-one (872-36-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS05,GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H302-H311-H315-H317-H318-H373-H411
Precautionary statements  P273-P280-P301+P312+P330-P302+P352+P312-P305+P351+P338+P310-P314
Hazard Codes  Xi,N,T
Risk Statements  43-36-51/53-48/22-41-38-24-22
Safety Statements  37/39-26-24-61-45-36/37/39
RIDADR  UN2810 - class 6.1 - PG 3 - EHS - Toxic, liquids, organic, n.o.s., HI: all
WGK Germany  3
RTECS  FG3325000
TSCA  Yes
HS Code  29209090
NFPA 704
2
3 1

Vinylene carbonate price More Price(26)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 809977 Vinylene carbonate 99.5%, acid <200 ppm, H2O <100 ppm 872-36-6 25g $476 2024-03-01 Buy
Sigma-Aldrich 757144 Vinylene carbonate contains 80 ppm BHT as stabilizer, 99% 872-36-6 25g $703 2023-01-07 Buy
TCI Chemical V0015 Vinylene Carbonate (stabilized with BHT) >98.0%(GC) 872-36-6 5g $84 2024-03-01 Buy
TCI Chemical V0015 Vinylene Carbonate (stabilized with BHT) >98.0%(GC) 872-36-6 25g $244 2024-03-01 Buy
Alfa Aesar 041400 Vinylene carbonate, 97+% stab. with BHT 872-36-6 0.5g $25.65 2024-03-01 Buy
Product number Packaging Price Buy
809977 25g $476 Buy
757144 25g $703 Buy
V0015 5g $84 Buy
V0015 25g $244 Buy
041400 0.5g $25.65 Buy

Vinylene carbonate Chemical Properties,Uses,Production

Chemical Properties

clear colorless to light yellow liquid

Uses

Vinylene carbonate is used as an additive to electrolyte solutions for anode side Lithiumion batteries. It also acts as a sealant to seal at least a portion of the silicon-polyvinyl acid interface. It is further used for great improvement of high temperature performance of the battery.

Application

Vinylene carbonate (VC) can be used as an electrolytic additive for ionic liquid electrolyte for the formation of lithium-ion batteries. It can also be used in the formation of hybrid solid electrolyte interphase (SEI) for the fabrication of lithium-based batteries.

Preparation

Vinylene carbonate is produced by the known method by eliminating hydrogen chloride from chloroethylene glycol carbonate by means of tertiary amines, in particular triethylamine. Chloroethylene glycol carbonate is obtained by free radical chlorination of ethylene glycol carbonate by means of chlorine or sulphuryl chloride. This synthesis was published for the first time in 1953 by Newman and Addor (JACS, 1953, page 1263; JACS 1955, page 3789).

General Description

This product has been enhanced for energy efficiency. Carbonate building block offered as a solution in ethyl acetate for more convenient handling. Vinylene carbonate may also be used as a dienophile in Diels-Alder reactions.

Flammability and Explosibility

Non flammable

Purification Methods

Purify it by zone melting, or distillation, and stabilize it with 0.5% of 2,6-di-tert-butyl-p-cresol. [Beilstein 19 III/IV 1597, 19/4 V 72.]

540-49-8
497-19-8
872-36-6
Synthesis of Vinylene carbonate from 1,2-DIBROMOETHYLENE and Sodium carbonate

Vinylene carbonate Preparation Products And Raw materials

Global( 445)Suppliers
Supplier Tel Email Country ProdList Advantage
EAST STAR BIOTECH (SUZHOU) CO., LTD.
+8617706846989 marketing@eaststarbio.com China 48 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
changzhou huayang technology co., ltd
+8615250961469 2571773637@qq.com China 9821 58
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12456 58
Dorne Chemical Technology co. LTD
+86-13583358881 +86-18560316533 Ethan@dornechem.com China 294 58
Zibo Hangyu Biotechnology Development Co., Ltd
+86-0533-2185556 +8617865335152 Mandy@hangyubiotech.com China 11013 58
Shandong Hanjiang Chemical Co., Ltd
+86-0533-2066820 +8618369939125 hanson@sdhanjiang.com China 1527 58
hebei hongtan Biotechnology Co., Ltd
+86-86-1913198-3935 +8617331935328 sales03@chemcn.cn China 951 58
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9348 55
Nanjing ChemLin Chemical Industry Co., Ltd.
025-83697070 product@chemlin.com.cn CHINA 3012 60

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View Lastest Price from Vinylene carbonate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Vinylene carbonate pictures 2024-04-26 Vinylene carbonate
872-36-6
US $1.00 / kg 1kg 99% 10000kg Dorne Chemical Technology co. LTD
Vinylene carbonate pictures 2024-04-26 Vinylene carbonate
872-36-6
US $30.00 / kg 1kg 98% 2000kg hebei hongtan Biotechnology Co., Ltd
Vinylene carbonate pictures 2024-04-12 Vinylene carbonate
872-36-6
US $0.00 / kg 1kg 0.99 10T Shandong Hanjiang Chemical Co., Ltd
Vinylene carbonate, 97+%, stab. with BHT Vinylene carbonate contains <=2% BHT as stabilizer, 97% Vinylene carbonate contains 80 ppm BHT as stabilizer, 99% WITH HYDROQUINONE Vinylene carbonate 99.5%, acid <200 ppm, H2O <100 ppm Vinylene carbonate, 97%, stabilized VINYLENE CARBONATE Carbonic acid, cyclic vinylene ester carbonicacid,cyclicvinyleneester Vinylene carbonate (stabilized with HQ) Vinylenecarbonate,97% VINYLENE CARBONATE, STAB. 1,3-Dioxo-2-one Vinylene carbonate, stabilized, 98% 1,3-DIOXAL-2-ONE (VINYLENE CARBONATE) VINYLENE CARBONATE (VC) Vinylenecarbonate,97+%,stab.withhydroquinone Vinylene carbonate, 98%, stabilized Vinylene Carbonate (stabilized with BHT) Vinylene carbonate,1,3-Dioxol-2-one Vinylene carbonate, stabilized, 98% 5GR Vinylene carbonat Vinylene carbonate solution Vinylene carbonate, 99%, for synthesis Vinylene Carbonate,98% Vinylene carbonate(872-36-6) 2H-1,3-dioxol-2-one 1-methyl-2,3-dihydro-1H-phosphole 1-oxide The ethylene carbonate Vinylene carbote 1,3-DIOXOL-2-ONE Vinylene carbonate, 99%, water ≤50 ppm, stabilized with 90 ppm BHT vinyl carbonate Vinylene carbonate contains 872-36-6 212-825-5 C3H2O3 Organic Building Blocks Building Blocks Carbonates Carbonyl Compounds Fine Chemical fine chemicals Other