ChemicalBook Chinese  Japanese  Germany

ChemicalBook >> CAS DataBase List >> Vinyl acetate

Vinyl acetate

CAS No. 108-05-4
Chemical Name: Vinyl acetate
Synonyms: VAM;VyAc;Vinile;Vinyle;zesett;Zeset T;octanwinylu;Vinylacetat;CH3CO2CH=CH2;Everflex 81L
CBNumber: CB7852732
Molecular Formula: C4H6O2
Formula Weight: 86.09
MOL File: 108-05-4.mol
Vinyl acetate Property
Melting point : -93 °C
Boiling point : 72-73 °C(lit.)
density : 0.934 g/mL at 25 °C(lit.)
vapor density : 3 (vs air)
vapor pressure : 88 mm Hg ( 20 °C)
refractive index : n20/D 1.395(lit.)
Fp : 20 °F
storage temp. : 0-6°C
solubility : 20g/l
form : Liquid
color : Clear colorless to almost colorless
PH: 7 (20g/l, H2O, 20℃)
explosive limit: 2.6-13.4%(V)
Water Solubility : 23 g/L (20 ºC)
Sensitive : Light Sensitive
Merck : 14,9992
BRN : 1209327
Stability:: Stable. Highly flammable. Incompatible with acids, bases, oxidizing agents, peroxides, chlorosulfonic acid, ethylene imine, hydrochloric acid, oleum, nitric acid, sulfuric acid, 2-aminoethanol, light. Susceptible to polymerization; commercial product may be stabilized by the addition of hydroquinone.
CAS DataBase Reference: 108-05-4(CAS DataBase Reference)
NIST Chemistry Reference: Acetic acid ethenyl ester(108-05-4)
EPA Substance Registry System: Acetic acid ethenyl ester(108-05-4)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes : F,T,Xn
Risk Statements : 11-39/23/24/25-23/24/25-36-20/21/22-40-37-20
Safety Statements : 16-23-29-33-45-36/37-7-9
RIDADR : UN 1301 3/PG 2
WGK Germany : 2
RTECS : AK0875000
TSCA : Yes
HazardClass : 3
PackingGroup : II
HS Code : 29153200
HS Code : 29333999
Hazardous Substances Data: 108-05-4(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning P261, P271, P304+P340, P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H341 Suspected of causing genetic defects Germ cell mutagenicity Category 2 Warning P201,P202, P281, P308+P313, P405,P501
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H401 Toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 2 P273, P501
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 3 P273, P501
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P370+P378 In case of fire: Use … for extinction.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.

Vinyl acetate Chemical Properties,Usage,Production

Chemical Properties
colourless mobile liquid with a sweet, irritating odour
General Description
A clear colorless liquid. Flash point 18°F. Density 7.8 lb / gal. Slightly soluble in water. Vapors are heavier than air. Vapors irritate the eyes and respiratory system. May polymerize if heated or contaminated. If polymerization occurs inside a container, the container may violently rupture. Used to make adhesives, paints, and plastics.
Air & Water Reactions
Highly flammable. Slightly soluble in water.
Reactivity Profile
Vinyl acetate may undergo spontaneous exothermic polymerization on exposure to light. Reacts with air or water to produces peroxides that initiate explosively violent polymerization. Reacts with hydrogen peroxide to form explosive peracetic acid. Reacts with oxygen to form explosive peroxides. Forms explosive Vinyl acetate ozonide on contact with ozone. Undergoes violent or explosive reactions with 2-aminoethanol, chlorosulfonic acid, ethylenediamine, mineral acids (hydrochloric acid, hydrofluoric acid, nitric acid, sulfuric acid, oleum), and peroxides [Lewis, 3rd ed., 1993, p. 1311]. Polymerization initiated by dibenzoyl peroxide in ethyl acetate accelerated out of control, ignited and exploded [Vervalin, 1973, p. 81]. Polymerization in toluene solution has caused several large industrial explosions [MCA Case History No. 2087].
Health Hazard
Vinyl acetate has been related to reproductive abnormalities. It is a skin and upper respiratory tract irritantand a central nervous system depressant. Exposure caused gradual deterioration of heart muscles.
Fire Hazard
When heated to decomposition, Vinyl acetate burns and emits acrid fumes. Highly dangerous when exposed to heat, flames or oxidizers; explosion hazard with strong acids and strong oxidizers. Incompatible with alumina, oxidizing materials, 2-aminoethanol, chlorosulfonic acid; ethyleneimine; 36% hydrochloric acid; 48.7% hydrofluoric acid; 70% nitric acid; oleum; 96% sulfuric acid; ethylene diamine; peroxides and silica gel. Avoid light or any polymerizing initiator. Hazardous polymerization can be initiated by organic and inorganic peroxides; azo compounds; redox systems (including organometallic components); light; and high energy radiation.
Vinyl acetate Preparation Products And Raw materials
Raw materials
Platinum Palladium chloride Acetylene Acetic acid glacial
Preparation Products
Adhesive for nonwoven fabric Ethylene-vinyl acetate copolymer ((1R,4S)-2-Azabicyclo[2.2.1]hept-5-en-3-one METHYL 5-FORMYL-2-METHYL-3-FUROATE Starch, hydrogen phosphate acetate emulsion used for paper series PC Vinyl acetate-acrylate copolymer,emulsion maleic acid-vinyl acetate copolymer VINYL STEARATE Pressure sensitive adhesive STARCH ACETATE stiffening agent for synthetic fibre 855 LT-01 emulsion 2-TRIFLUOROMETHYLQUINOLINE-7-CARBOXYLIC ACID POLY(VINYL ACETATE) PR-I retanning agent 1,1-Dimethoxy-2-(2-methoxyethoxy)ethane Bromoacetaldehyde diethyl acetal coating adhensive SSS-85 POLY(ETHYLENE-CO-METHACRYLIC ACID) PALMITIC ACID VINYL ESTER Poly(vinyl alcohol) Tazobactam acid 2-Acetylbutyrolactone Acetylated Dishtarch Phosphate irradiation initiated starch-g-vinyl acetate water absorbent agent 5-NORBORNEN-2-YL ACETATE
Vinyl acetate Suppliers      Global( 170)Suppliers     
Supplier Tel Fax Email Country ProdList Advantage
Shanghai Aladdin Bio-Chem Technology Co.,LTD 021-20337333/400-620-6333
021-50323701 sale@aladdin-e.com China 25125 65
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96831 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40403 62
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30314 84
TCI (Shanghai) Development Co., Ltd. 800-988-0390
021-67121385 sales@tcishanghai.com.cn China 22833 81
Beijing dtftchem Technology Co., Ltd. 13651141086; 86(10)60275028、60275820
86 (10) 60270825 dtftchem@sina.com China 3437 62
Energy Chemical 021-58432009 / 400-005-6266
021-58436166-800 info@energy-chemical.com China 44197 61
Beijing Ouhe Technology Co., Ltd +86-10-4006331231;+86-10-51280831;+86-10-82967028
+86-10-82967029 sales@ouhechem.com China 10816 60
JinYan Chemicals(ShangHai) Co.,Ltd. 13817811078,021-50426030
86-021-50426522,50426273 sales@jingyan-chemical.com China 10094 60
Secco work (Beijing) chemical technology co., LTD 010-69755668;
010-69755668 1139670422@qq.com China 3549 54
 
108-05-4(Vinyl acetate)Related Search:
ETHYLENE Acrylic acid Megestrol acetate VINYL PROPIONATE Methyl acetate Diethylenetriaminepentaacetic acid POLYVINYL ACEATE Butyl acetate Vinyl chloroacetate Ethylene-vinyl acetate copolymer POLY(VINYL ACETATE) USP Tocopheryl acetate Triacetin Vinyl acetate Benzyl acetate Potassium Acetate PHENYL ACETATE ACETATE
1-Acetoxyethylene Acetate de vinyle acetatedevinyle acetatedevinyle(french) Acetic acid, ethylene ether Aceticacid,ethenylester aceticacid,ethyleneester aceticacid,ethyleneether aceticacidethenylester acetoxyethene CH3CO2CH=CH2 Ethanoic acid, ethenyl ester ethanoicacid,ethenylester Ethenyl acetate ethenylacetate Everflex 81L Octan winylu octanwinylu octanwinylu(polish) Plyamul 40305-00 Unocal 76 Res 6206 Unocal 76 Res S-55 Vinile Vinile(acetato di) vinile(acetatodi) Vinnapas A 50 Vinyl A monomer Vinyl acetate h.q. Vinyl ester of acetic acid Vinyl ethanoate Vinylacetaat Vinylacetat vinylacetateh.q. vinylacetatehq vinylacetatemonomer15 Vinylaceticester vinylamonomer Vinyle Vinyle(acetate de) vinyle(acetatede) vinyle(acetatede)(french) Vinylester kyseliny octove vinylesterkyselinyoctove vinylethanoate VyAc Zeset T zesett Organic Building Blocks Esters VINYL ACETATE MONOMER VINYL ACETATE VAM Ethenyl ethanoate Building Blocks Carbonyl Compounds C2 to C5 108-05-4 ACETIC ACID VINYL ESTER
Copyright 2017 © ChemicalBook. All rights reserved