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(E,E)-2,4-Hexadienal

CAS No.
142-83-6
Chemical Name:
(E,E)-2,4-Hexadienal
Synonyms
2,4-HEXADIENAL;(2E,4E)-Hexa-2,4-dienal;SORBALDEHYDE;SORBIC ALDEHYDE;FEMA 3429;JACS-142-83-6;Hexa-2,4-dienal;n-Hex-2,4-dienal;T2 T4 HEXADIENAL;2,4-HEXADIEN-1-AL
CBNumber:
CB9143146
Molecular Formula:
C6H8O
Molecular Weight:
96.13
MDL Number:
MFCD00007004
MOL File:
142-83-6.mol
MSDS File:
SDS
Last updated:2024-05-06 18:26:58

(E,E)-2,4-Hexadienal Properties

Melting point -16.5°C
Boiling point 69 °C/20 mmHg (lit.)
Density 0.895 g/mL at 20 °C 0.871 g/mL at 25 °C (lit.)
vapor density >1 (vs air)
refractive index n20/D 1.541(lit.)
FEMA 3429 | TRANS,TRANS-2,4-HEXADIENAL
Flash point 154 °F
storage temp. 2-8°C
Specific Gravity 0.871
Odor at 10.00 % in dipropylene glycol. sweet green spicy floral citrus
Odor Type green
Water Solubility It is Insoluble in water, but soluble in ethanol.
Sensitive Air Sensitive
JECFA Number 1175
BRN 1698401
Stability Stable. Combustible. Incompatible with strong reducing agents, strong bases, strong oxidizing agents.
LogP 1.06
CAS DataBase Reference 142-83-6(CAS DataBase Reference)
Substances Added to Food (formerly EAFUS) TRANS, TRANS-2,4-HEXADIENAL
EWG's Food Scores 2
FDA UNII 878K4I6N7T
Proposition 65 List 2,4-Hexadienal (89% trans, trans isomer; 11% cis, trans isomer)
IARC 2B (Vol. 101) 2013
NIST Chemistry Reference 2,4-Hexadienal, (E,E)-(142-83-6)
EPA Substance Registry System 2,4-Hexadienal, (2E,4E)- (142-83-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS05,GHS06
Signal word  Danger
Hazard statements  H301+H311-H314-H317
Precautionary statements  P261-P270-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  T,Xi,Xn
Risk Statements  22-24-34-43-36/37/38-20/21/22
Safety Statements  26-36/37/39-45-36
RIDADR  UN 2922 8/PG 3
WGK Germany  3
RTECS  WG1925000
1-10
Hazard Note  Irritant
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29121900
NFPA 704
2
2 0

(E,E)-2,4-Hexadienal price More Price(14)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 180343 trans,trans-2,4-Hexadienal 95% 142-83-6 25ml $92.6 2024-03-01 Buy
Sigma-Aldrich 180343 trans,trans-2,4-Hexadienal 95% 142-83-6 100ml $198 2024-03-01 Buy
TCI Chemical H0581 2,4-Hexadienal >95.0%(GC) 142-83-6 25mL $46 2021-12-16 Buy
Alfa Aesar A13200 2,4-Hexadienal, predominantly trans,trans, 95% 142-83-6 5g $22.65 2024-03-01 Buy
Alfa Aesar A13200 2,4-Hexadienal, predominantly trans,trans, 95% 142-83-6 25g $55.65 2024-03-01 Buy
Product number Packaging Price Buy
180343 25ml $92.6 Buy
180343 100ml $198 Buy
H0581 25mL $46 Buy
A13200 5g $22.65 Buy
A13200 25g $55.65 Buy

(E,E)-2,4-Hexadienal Chemical Properties,Uses,Production

Description

trans, frans-2,4-Hexadienal has a fresh, green, floral citrus odor. May be synthesized by slowly heating croton-aldehyde with acetaldehyde in the presence of pyridine at 85 - 90°C.

Chemical Properties

liquid

Chemical Properties

trans, trans-2,4-Hexadienal has a sweet, green aroma; in dilution, a pleasant citrusy green.

Occurrence

Reported found in olive, roasted peanuts, tomato, caviar, fish, auto-oxidized salmon oil, tea, apricot, strawberry, wheaten bread, Russian cheeses, cooked chicken and beef, boiled mutton, hop oil, raw and roasted peanuts, soybean, olive, rice, buckwheat, malt, kiwifruit and scallops.

Uses

trans,trans-2,4-Hexadienal (sorbic aldehyde) was used in the synthesis of chiral cycloadducts.

Uses

2,4-Hexadienal, is used in the synthesis of chiral cycloadducts. 2,4-Hexadienal is used as a flavouring agent, as a chemical intermediate in various organic synthetic reactions and as a raw material in the manufacture of sorbic acid. It is also used as in the manufacture of polymethine dyes, as a pharmaceutical intermediate in the manufacture of mitomycins and antihypercholesteraemics, as an inhibitor of corrosion for steel used in oil field operations, as a monomer in reactions with silane comonomers for the manufacture of polyalkenyloxysilane polymer and as a fumigant against larvae of the Caribbean fruit fly.

Definition

ChEBI: (E,E)-2,4-hexadienal is a hexadienal that is hexanal with trans double bonds at positions 2 and 4. It is found in tomatoes, kiwi fruit, mangoes, potato chips, herbs and spices. It has a role as a flavouring agent and a plant metabolite. It is a polyunsaturated fatty aldehyde, a hexadienal and a volatile organic compound.

Preparation

Can be obtained by slowly heating crotonaldehyde with acetaldehyde in the presence of pyridine at 85 to 90°C.

Aroma threshold values

Detection: 60 to 476 ppb

Taste threshold values

Taste characteristics at 25 ppm: sweet, green, waxy, aldehydic, with fresh melon nuances.

General Description

trans,trans-2,4-Hexadienal is a volatile is a flavor compound that is reported to occur in different types of tea.

75-07-0
142-83-6
123-73-9
Synthesis of (E,E)-2,4-Hexadienal from Acetaldehyde
Global( 181)Suppliers
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Hebei Mojin Biotechnology Co., Ltd
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View Lastest Price from (E,E)-2,4-Hexadienal manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(E,E)-2,4-Hexadienal pictures 2024-05-06 (E,E)-2,4-Hexadienal
142-83-6
US $20.00 / kg 1kg 99.9% 200000kg Ouhuang Engineering Materials (Hubei) Co., Ltd
(E,E)-2,4-Hexadienal pictures 2023-06-30 (E,E)-2,4-Hexadienal
142-83-6
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
2,4-Hexadienal pictures 2023-02-13 2,4-Hexadienal
142-83-6
US $10.00 / KG 1KG 99% 50MT Hebei baicao biology science and technology co., ltd
  • 2,4-Hexadienal pictures
  • 2,4-Hexadienal
    142-83-6
  • US $10.00 / KG
  • 99%
  • Hebei baicao biology science and technology co., ltd
(2E,4E)-2,4-Hexadienal (2E,4E)-Hexadienal (E)-2,(E)-4-hexadienal (E,E)-2,4-hexadienal (e,e)-4-hexadienal TRANS-2,4-HEXADIENAL Sorbaldehyde, Sorbic aldehyde trans-2,trans-4-Hexadienal,95%,sum of isomers (2E,4E)-2,4-Hexadienal(sorbaldehyde) trans,trans-Hexa-2,4-dienal, Sorbaldehyde, Sorbic aldehyde trans,trans-2,4-Hexadienal 95% FEMA 3429 2,4-HEXADIEN-1-AL (E,E)-hexa-2,4-dienal 1,3-Pentadiene-1-carboxaldehyde 2,4-(E-E)-Hexadienal 3-Propyleneacrolein 4-Hexadienal,(E,E)-2 Hexa-2,4-dienal n-Hex-2,4-dienal sorbaldehyde(2,4-hexadienal) trans,trans-hexa-2,4-dienal T2 T4 HEXADIENAL TRANS 2, TRANS 4-HEXADIENAL TRANS,TRANS-2,4-HEXADIENAL TIMTEC-BB SBB006613 2 4-HEXADIENAL 95+% trans-2,trans-4-Hexadienal, sum of isomers, 95% 2,4-Hexadienal, (2E,4E)- 2,4-hexadienal, predominantly trans,trans Sorbaldehyde (6CI,7CI,8CI) 2,4-Hexadienalpredominantly trans JACS-142-83-6 2,4-Hexadienal> (E,E)-2,4-Hexadienal USP/EP/BP (2E,4E)-Hexa-2,4-dienal 2,4-HEXADIENAL SORBALDEHYDE SORBIC ALDEHYDE 2,4-Hexadienal, ≥ 80.0% 142-83-6 CH3CHCHCHCHCHO Building Blocks Aldehydes Carbonyl Compounds C1 to C6 Organic Building Blocks aldehyde Flavor