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Decabromodiphenyl oxide

CAS No.
1163-19-5
Chemical Name:
Decabromodiphenyl oxide
Synonyms
BDE-209;DECABROMODIPHENYL ETHER;DECA;DecaBDE;dbdpo;DBDE;PBDE209;PENTABROMOPHENYL ETHER;BIS(PENTABROMOPHENYL) ETHER;br55n
CBNumber:
CB9705445
Molecular Formula:
C12Br10O
Molecular Weight:
959.17
MDL Number:
MFCD00000059
MOL File:
1163-19-5.mol
MSDS File:
SDS
Last updated:2024-03-14 15:18:32

Decabromodiphenyl oxide Properties

Melting point >300 °C(lit.)
Boiling point 425°C
Density 3 g/cm3
vapor pressure 0Pa at 21℃
refractive index 1.5000 (estimate)
Flash point -12 °C
storage temp. 2-8°C
solubility <0.0001mg/l
form Solid
color White to Light Brown
Water Solubility <0.1 g/100 mL at 20 ºC
BRN 2188438
Stability Stable. Incompatible with strong oxidizing agents.
InChIKey WHHGLZMJPXIBIX-UHFFFAOYSA-N
LogP 6.625 at 25℃
CAS DataBase Reference 1163-19-5(CAS DataBase Reference)
FDA UNII N80BQ29A0H
IARC 3 (Vol. 48, 71) 1999
EPA Substance Registry System Decabromodiphenyl oxide (1163-19-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07,GHS08,GHS09,GHS05
Signal word  Danger
Hazard statements  H302-H312-H318-H351-H413-H320-H341-H225-H304-H315-H336-H361d-H373-H410
Precautionary statements  P305+P351+P338-P310a-P501a-P201-P210-P273-P301+P310-P331-P370+P378-P202-P260-P264-P280-P305+P351+P338+P337+P313-P308+P313-P405-P501
Hazard Codes  Xn,Xi,N,F
Risk Statements  20/21/22-67-65-63-50/53-48/20-38-11
Safety Statements  36/37-62-61-60-16
RIDADR  3152
WGK Germany  1
RTECS  KN3525000
Hazard Note  Irritant
TSCA  Yes
HazardClass  9
PackingGroup  II
HS Code  29093031
Toxicity Review IARC: Group 3 IMEMDT 48,73,90; Animal Limited Evidence IMEMDT 48,73,90. NTP Carcinogenesis Studies (feed); Some Evidence: rat NTPTR* NTP-TR-309,86; (feed); Equivocal Evidence: mouse NTPTR* NTP-TR-309,86. Polybrominated biphenyl compounds ar

Decabromodiphenyl oxide price More Price(20)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich NIST2258 BDE 209 in 2,2,4-Trimethylpentane NIST?SRM? 1163-19-5 6G $1020 2024-03-01 Buy
Sigma-Aldrich 89407 BDE No 209 solution ~50?μg/mL (Isooctane:Toluene 50:50), analytical standard 1163-19-5 1ML $203 2024-03-01 Buy
TCI Chemical D1388 Decabromodiphenyl Ether >95.0%(GC) 1163-19-5 25g $14 2021-12-16 Buy
TRC D212850 Decabromodiphenyl Ether 1163-19-5 100mg $1210 2021-12-16 Buy
Medical Isotopes, Inc. 50540 DecabromodiphenylOxide 1163-19-5 100mg $2000 2021-12-16 Buy
Product number Packaging Price Buy
NIST2258 6G $1020 Buy
89407 1ML $203 Buy
D1388 25g $14 Buy
D212850 100mg $1210 Buy
50540 100mg $2000 Buy

Decabromodiphenyl oxide Chemical Properties,Uses,Production

Description

DBDPO is a white to off-white powder.Molecular weight = 959.9. Hazard Identification (based onNFPA-704 M Rating System): Health 2, Flammability 0,Reactivity 0. Slightly soluble in water.

Chemical Properties

Decabromodiphenyl Oxide (DBDPO) is a white to off-white or light yellow powder. Almost insoluble in all solvents. Good thermal stability. Heated to 354 ℃, weight loss 5%. It is a non-toxic and non-polluting flame retardant.

Uses

Decabromodiphenyl ether is a brominated flame retardant that is used in conjunction with antimony trioxide in high impact polystyrene. DecaBDE is used as an additive flame retardant, and has a variety of applications including in plastics/polymers/composites, textiles, adhesives, sealants, coatings and inks. DecaBDE containing plastics are used in housings of computers and TVs, wires and cables, pipes and carpets. Adverse effects are reported for soil organisms, birds, fish, frog, rat, mice and humans. One of the new POPs under the Stockholm Convention

Definition

ChEBI: Decabromodiphenyl ether is a polybromodiphenyl ether that is diphenyl ether in which all of the hydrogens have been replaced by bromines. It has a role as a neurotoxin.

Application

Decabromodiphenyl oxide is an unreactive, additive flame retardant widely used for its thermal stability and its low cost in thermoplastic resins, thermoset resins, textiles and adhesives. The major applications are in high impact polystyrene, glass reinforced thermoplastic polyester and moulding resins, low density polyethylene extrusion coatings, polypropylene (homo- and copolymers), acrylonitrile butadiene styrene rubber, nylon and polyvinyl chloride.

Preparation

Decabromodiphenyl ether can be synthesized by reacting diphenyl ether with bromine in the presence of halogenated catalyst (iron powder, etc.).
The diphenyl ether is dissolved in the solvent, the catalyst is added, and then bromine is added to carry out the reaction. After the reaction, filter, wash and dry to obtain decabromodiphenyl ether. Commonly used solvents are dibromoethane, dichloroethane, dibromomethane, carbon tetrachloride, tetrachloroethane and the like.

General Description

White to off-white powder with a chemical odor.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Decabromodiphenyl oxide is incompatible with strong oxidizers .

Fire Hazard

Flash point data for Decabromodiphenyl oxide are not available; however, Decabromodiphenyl oxide is probably combustible.

Safety Profile

Questionable carcinogen with experimental neoplastigenic data. Experimental reproductive effects. Used as a flame retardant for thermoplastics. When heated to decomposition it emits toxic fumes of Br-. See also ETHERS and BROMIDES

Potential Exposure

It is used as a fire retardant for thermoplastics and man-made fibers.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.

storage

Color Code—Green: General storage may be used.Prior to working with DPDPO you should be trained on itsproper handling and storage. Store in tightly closed containers in a cool, well-ventilated area away from strong oxidizers.Where possible, automatically transfer this chemical fromdrums or other storage containers to process containers. Useonly nonsparking tools and equipment, especially when opening and closing containers of this chemical. Sources of ignition, such as smoking and open flames, are prohibited wherethis chemical is used, handled, or stored in a manner thatcould create a potential fire or explosion hazard. Whereverthis chemical is used, handled, manufactured, or stored, useexplosion-proof electrical equipment and fittings.

Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required. UN3152 Polyhalogenated biphenyls, solid or Polyhalogenated ter- phenyls, solid, Hazard class: 9; Labels: 9-Miscellaneous hazardous material.

Incompatibilities

Incompatible with strong oxidizers (chlo- rates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. Ethers have a tendency to form unstable and explosive peroxides.

Global( 404)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Daken Advanced Materials Co.,Ltd
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View Lastest Price from Decabromodiphenyl oxide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Decabromodiphenyl oxide pictures 2024-04-26 Decabromodiphenyl oxide
1163-19-5
US $0.00 / kg 1kg ≥83% 2000mt/year Jinan Finer Chemical Co., Ltd
Decabromodiphenyl oxide pictures 2023-09-06 Decabromodiphenyl oxide
1163-19-5
US $0.00-0.00 / KG 1KG 99% 500000kg Hebei Guanlang Biotechnology Co., Ltd.
Decabromodiphenyl oxide pictures 2023-08-24 Decabromodiphenyl oxide
1163-19-5
US $0.00 / Kg 1Kg 99% 20ton Hebei Mojin Biotechnology Co., Ltd
1,1’-oxybis(2,3,4,5,6-pentabromo-benzen 1,1’-oxybis[2,3,4,5,6-pentabromo-benzen Decabromodiphenyl ether solution, Decabromodiphenyl oxide Benzene, 1,1-oxybis2,3,4,5,6-pentabromo- bde no 209solution decabromodiphenyl ether solution 1,1'-Oxybis (2,3,4,5,6-pentabromobenzol) Decabromodiphenyl ester berkflamb10e br55n bromkal82-0de bromkal82-ode DECABROMODIPHYNLY OXIDE Decabromodiphenylether~Pentabromophenylether DI-PENTABROMOBENZENEETHER DECABROMINATEDDIPHENYLETHER DECABDPE Pentabromophenyl ether,98% 1,2,3,4,5-pentabromo-6-(2,3,4,5,6-pentabromophenoxy)benzene Decabromodiphenyl ether ,99% PBDE 209 (Decabromodiphenylether) Decabromodiphenyl oxide 10g [1163-19-5] Decabromodiphenyl ox DECABDE (BDE-209) Bromkal 81 1,1'-Oxybis(2,3,4,5,6-pentabromobenzene) DecabroModipheny DECABROMODIPHENYL OXIDE BDE NO 209 PERBROMODIPHENYL ETHER SAYTEX 102E SAYTEX(R) 102E FLAME RETARDANT 6,6'-Oxybis(1,2,3,4,5-pentabroMobenzene) DecabroModiphenyl ether 98% PBDE 209 (Deca Pentabromophenyl ether 1,1'-oxybis(2,3,4,5,6-pentabromo)-Benzene 1,1'-oxybis(2,3,4,5,6-pentabromobenzene) 1,1'-oxybis[2,3,4,5,6-pentabromo-benzen berkflam b 10e bis(pentabromophenyl) ether bromkal83-10de de83r decabrom decabromobiphenylether decabromobiphenyloxide decabromodiphenylether(dbdpe) decabromophenylether ether,bis(pentabromophenyl) ether,decabromodiphenyl FR-10 fr300 fr300ba frp53 nci-c55287 saytex102 tardex100 DODPO FR-RDO 1 DecabromodiphenylEtherSolution,1000mg/L,1mL Decabromodiphenyl Ether@50 μg/mL in Isooctane:Toluene (50:50) Decabromodiphenyl Ether > DecabromodiphenylEtherSolution,10mg/L,5mL