N-Phenylbenzylamine
- CAS No.
- 103-32-2
- Chemical Name:
- N-Phenylbenzylamine
- Synonyms
- N-BENZYLANILINE;BENZYLANILINE;aminobenzophenone;BENZYL-PHENYL-AMINE;Benzenemethanamine, N-phenyl-;AURORA 4803;Phenhenzamine;AKOS BBS-00003909;A-TOLUYL CHLORIDE;Phenylbenzylamine
- CBNumber:
- CB9762952
- Molecular Formula:
- C13H13N
- Molecular Weight:
- 183.25
- MDL Number:
- MFCD00003018
- MOL File:
- 103-32-2.mol
- MSDS File:
- SDS
| Melting point | 35-38 °C (lit.) |
|---|---|
| Boiling point | 306-307 °C (lit.) |
| Density | 1.061 g/mL at 25 °C (lit.) |
| refractive index |
n |
| Flash point | 217 °F |
| storage temp. | Store below +30°C. |
| solubility | alcohol: soluble |
| form | Crystalline Powder or Low Melting Mass |
| pka | 3.89±0.10(Predicted) |
| Specific Gravity | 1.061 |
| color | Colorless to yellow-beige |
| Water Solubility | INSOLUBLE |
| Merck | 14,1126 |
| CAS DataBase Reference | 103-32-2(CAS DataBase Reference) |
| FDA UNII | R1FVH9A316 |
| NIST Chemistry Reference | Benzenemethanamine, N-phenyl-(103-32-2) |
| EPA Substance Registry System | Benzenemethanamine, N-phenyl- (103-32-2) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P280-P302+P352-P362+P364 | |||||||||
| Hazard Codes | C,Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-37/39 | |||||||||
| RIDADR | UN 2577 8/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 21 | |||||||||
| HS Code | 29214980 | |||||||||
| NFPA 704 |
|
N-Phenylbenzylamine price More Price(21)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 185493 | N-Benzylaniline ≥99% | 103-32-2 | 25g | $75.6 | 2024-03-01 | Buy |
| Sigma-Aldrich | 185493 | N-Benzylaniline ≥99% | 103-32-2 | 100g | $117.6 | 2024-03-01 | Buy |
| Sigma-Aldrich | 8.20982 | N-Phenylbenzylamine for synthesis | 103-32-2 | 250g | $113 | 2023-01-07 | Buy |
| TCI Chemical | P0159 | N-Phenylbenzylamine >98.0%(GC) | 103-32-2 | 25g | $41 | 2024-03-01 | Buy |
| TCI Chemical | P0159 | N-Phenylbenzylamine >98.0%(GC) | 103-32-2 | 100g | $82 | 2024-03-01 | Buy |
N-Phenylbenzylamine Chemical Properties,Uses,Production
Synthesis
N-Phenylbenzylamine can be obtained by condensation of benzyl chloride and aniline. Mix and stir sodium bicarbonate, water and aniline, heat to 90-95°C, and slowly add benzyl chloride. React at 90-95°C for 3h. Cool and filter. The filtrate was separated, and the organic layer was washed with saturated brine and dried over anhydrous sodium sulfate. Then, under reduced pressure distillation, the 81°C (1.6kPa) fraction was collected to recover aniline, and the 170-190°C (1.6kPa) fraction was cooled and solidified to give N-Phenylbenzylamine.
Chemical Properties
colorless to yellow-beige crystalline powder
Uses
N-Benzylaniline is a major metabolite of the antihistaminic Antazoline and other N-substituted benzylanilines.
Uses
N-Benzylaniline was used in the separation of tervalent gallium, indium and thallium by solvent extraction method.
Synthesis Reference(s)
Chemistry Letters, 8, p. 45, 1979
Organic Syntheses, Coll. Vol. 1, p. 102, 1941
Tetrahedron Letters, 19, p. 4987, 1978 DOI: 10.1016/S0040-4039(01)85789-0
General Description
The electropolymerisation of N-benzylaniline at transparent Indium Tin Oxide glass electrodes has been investigated by UV-visible spectroelectrochemistry. N-Benzylaniline on electrochemical oxidation in aqueous sulfuric acid solution produces an adherent conducting polymer film at the platinum electrode.
Purification Methods
Crystallise the amine from pet ether (b 60-80o) (ca 0.5mL/g). The picrate has m 113o (from Et2O). [Beilstein 12 H 1023, 12 I 449, 12 II 548, 12 III 2215, 12 IV 2172.]
N-Phenylbenzylamine Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| airuikechemical co., ltd. | +undefined86-15315557071 | sales02@airuikechemical.com | China | 994 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9348 | 55 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 | sales@sdzschem.com | China | 2931 | 58 |
| Shandong chuangyingchemical Co., Ltd. | 18853181302 | sale@chuangyingchem.com | CHINA | 5909 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63711 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49390 | 58 |
| Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 | sale04@alfachem.cn | China | 12468 | 58 |
View Lastest Price from N-Phenylbenzylamine manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-09 | n-benzylaniline
103-32-2
|
US $0.00-0.00 / Kg | 1Kg | 99.9% | 200tons | airuikechemical co., ltd. | |
 |
2019-07-06 | N-Phenylbenzylamine
103-32-2
|
US $7.00 / KG | 1KG | 99% | 100KG | Career Henan Chemical Co |
-
- n-benzylaniline
103-32-2
- US $0.00-0.00 / Kg
- 99.9%
- airuikechemical co., ltd.
-
- N-Phenylbenzylamine
103-32-2
- US $7.00 / KG
- 99%
- Career Henan Chemical Co
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