ベンゾトリフルオリド 化学特性,用途語,生産方法
外観
無色～ほとんど無色, 澄明の液体
溶解性
水に不溶 (140mg/L), エタノール, アセトン, 各種有機溶剤に易溶。エタノール及びアセトンに極めて溶けやすく、水にほとんど溶けない。
用途
染料、高重合体の原料。
化学的特性
Benzotrifluoride is a colorless to light yellow liquid, low viscosity liquid. Its polarity is intermediate between those of dichloromethane and ethyl acetate, and it is miscible with common organic solvents and able to dissolve many organic compounds. Benzotrifluoride is used in a wide variety of reactions including radical reactions, oxidations and reductions, phase-transfer reactions, transition metal catalyzed processes andLewis acid reactions.
使用
Benzotrifluoride is a useful alternative solvent for organic reactions currently conducted in dichloromethane and related solvents.
定義
ChEBI: (trifluoromethyl)benzene is a fluorohydrocarbon that is fluoroform in which the hydrogen is substituted by a phenyl group. It has a role as a solvent and an environmental contaminant. It is a fluorohydrocarbon and a member of (trifluoromethyl)benzenes. It derives from a fluoroform.
一般的な説明
A clear colorless liquid with an aromatic odor. Flash point of 54°F. Vapors are heavier than air. Insoluble in water and slightly denser than water. May be toxic by inhalation.
空気と水の反応
Highly flammable. Insoluble in water.
反応プロフィール
Benzotrifluoride may react with oxidizing materials, strong bases and reducing agents.
危険性
Highly toxic by inhalation. Flammable, dangerous fire risk.
健康ハザード
Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control may cause pollution.
火災危険
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
安全性プロファイル
Poison by intraperitoneal route.Moderately toxic by subcutaneous route. Dangerous fire hazard. To fight fire, usewater, foam, CO2, spray mist, dry chemical. When heatedto decomposition it emits toxic fumes of F??. Incompatiblewith oxidizing materials
純化方法
Purify benzotrifluoride by repeated treatment with boiling aqueous Na2CO3 (until no test for chloride ion is obtained), dry it with K2CO3, then with P2O5, and fractionally distil it. [Beilstein 5 IV 802.]
ベンゾトリフルオリド 上流と下流の製品情報
原材料
準備製品