ペンタエチレンヘキサミン 化学特性,用途語,生産方法
外観
無色～黄色～黄赤色透明液体
用途
繊維処理剤,キレート剤,界面活性剤
化学的特性
dark yellow-green liquid
使用
5.Pentaethylenehexamine has been used in the preparation of:
- polyisobutylene succinimide (PIBSI) dispersants, used as engine oil-additives
- poly(glycidyl methacrylate) (P(GMA)) homopolymers
- poly(amidoamine)s
一般的な説明
Yellowish liquid with an odor of ammonia.
空気と水の反応
Water soluble.
反応プロフィール
PENTAETHYLENEHEXAMINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
健康ハザード
Contact with eyes can cause slight to moderate irritation and possible burns. May cause transient fogging of the eyes as a result of corneal edema, which is reversible. May cause moderate skin irritation or allergic skin reaction with symptoms of redness, itching, swelling, or rash. Vapors may irritate the eyes, nose, throat, and respiratory tract. May cause coughing, headache, nausea and vomiting. If swallowed, may cause nausea, vomiting and abdominal pain. May cause burns of the mouth, throat, esophagus, and stomach.
安全性プロファイル
Moderately toxic by ingestion. Mutation data reported. Whenheated to decomposition it emits toxic fumes of NOx.
純化方法
Fractionally distil it twice at 10-20mm, the fraction boiling at 220-250o being collected. It can be further purified via the hydrochloride. Its solution in MeOH (40mL of base in 250mL) is cooled in an ice-bath and conc HCl (~50mL) is added dropwise with stirring. The precipitated hydrochloride is filtered off, washed with Me2CO, and Et2O, then dried in a vacuum desiccator. The free base is then obtained by basification, extraction into Et2O, drying (NaOH), filtering, evaporating and distilling the residue as before. It forms a Cu complex [Cu(C10H28N6)]2+. [Jonassen et al. J Am Chem Soc 79 4279 1957, Beilstein 4 IV 1245.]
ペンタエチレンヘキサミン 上流と下流の製品情報
原材料
準備製品