9,9-Bis(3,4-dicarboxyphenyl)fluorene Dianhydride

9,9-Bis(3,4-dicarboxyphenyl)fluorene Dianhydride 구조식 이미지
카스 번호:
135876-30-1
상품명:
9,9-Bis(3,4-dicarboxyphenyl)fluorene Dianhydride
동의어(영문):
9,9-Bis;1,3-Isobenzofurandione, 5,5;9,9-Bis(3,4-dicarboxyphenyl)fluorene Dianhydride;9,9-Bis(3,4-dicarboxyphenyl) fluorine Dianhydride;(BPAF)9,9-Bis(3,4-dicarboxyphenyl)fluorene Dianhydride;5,5'-(9H-Fluorene-9,9-diyl)bis(2-benzofuran-1,3-dione);9,9-Bis(3,4-dicarboxyphenyl)fluorene Dianhydride (BPAF);1,3-Isobenzofurandione, 5,5'-(9H-fluoren-9-ylidene)bis-;5,5'-(9H-fluorene-9,9-diyl)bis(isobenzofuran-1,3-dione);5,5'-(9H-Fluorene-9,9-diyl)bis(isobenzofuran-1,3-dione)
CBNumber:
CB13191782
분자식:
C29H14O6
포뮬러 무게:
458.42
MOL 파일:
135876-30-1.mol

9,9-Bis(3,4-dicarboxyphenyl)fluorene Dianhydride 속성

녹는점
269 °C
끓는 점
687.9±55.0 °C(Predicted)
밀도
1.521±0.06 g/cm3(Predicted)
물리적 상태
powder to crystal
색상
흰색에서 거의 흰색
InChI
InChI=1S/C29H14O6/c30-25-19-11-9-15(13-21(19)27(32)34-25)29(16-10-12-20-22(14-16)28(33)35-26(20)31)23-7-3-1-5-17(23)18-6-2-4-8-24(18)29/h1-14H
InChIKey
FMACFWAQBPYRFO-UHFFFAOYSA-N
SMILES
C1(C2C=CC3C(=O)OC(=O)C=3C=2)(C2C=CC3C(=O)OC(=O)C=3C=2)C2=C(C=CC=C2)C2=C1C=CC=C2
CAS 데이터베이스
135876-30-1

안전

HS 번호 2932990090

9,9-Bis(3,4-dicarboxyphenyl)fluorene Dianhydride C화학적 특성, 용도, 생산

개요

9,9-Bis(3,4-dicarboxyphenyl)fluorene Dianhydride is a dianhydride that is used in the production of polymers. It has a melting point of about 240°C and can be used as a catalyst for the thermal oxidation of aromatic hydrocarbons. 9,9-Bis(3,4-dicarboxyphenyl)fluorene Dianhydride is also a crystallization agent for organic compounds and can be used as an oxidizing agent in the process of dehydrating crystals. The reaction product of 9,9-Bis(3,4-dicarboxyphenyl)fluorene Dianhydride is epoxy resin.

화학적 성질

white to almost white powder to crystal

용도

Used in Polyimide Monomer

주요 응용

9,9-Bis(3,4-dicarboxyphenyl)fluorene Dianhydride (BPAF) can be used in the preparation of new imine oligomers and thermosets. The BPAF-derived imide oligomers exhibited improved organic solvents solubility and higher melt viscosity compared to those based on 2,3,3′,4′-biphenyltetracarboxylic dianhydride (3,4′-BPDA), due to their bulky, twisted, and sterically hindered cardo architectures. The imide oligomers under pressure were converted into thermosets by the thermal crosslinking of phenylethynyl at 370 °C for 2 h. The BPAF-derived thermosets exhibited much higher glass transition temperature (Tg) (> 404 °C), 5% weight-loss temperature (T5%) (> 549 °C) in an air environment, and more excellent high-frequency dielectric properties from 30 to 45 GHz (dielectric constant as low as 2.85 and dielectric loss factor as low as 0.0037) while possessing comparable or even better mechanical properties relative to the 3,4′-BPDA-derived polymers. Therefore, these polymers based on BPAF may have potential applications as matrix resins for heat-resistant, structural and functional composites[1].

9,9-Bis(3,4-dicarboxyphenyl)fluorene Dianhydride 준비 용품 및 원자재

원자재

준비 용품


9,9-Bis(3,4-dicarboxyphenyl)fluorene Dianhydride 공급 업체

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