폴리이소프렌

폴리이소프렌
폴리이소프렌 구조식 이미지
카스 번호:
9003-31-0
한글명:
폴리이소프렌
동의어(한글):
이소프렌고무;폴리아이소프렌;폴리이소프렌
상품명:
POLYISOPRENE
동의어(영문):
IR;Natural rubber;NATSYN 2210;cis-1,4-Polyisoprene rubber;Isoprene rubber;POLYISOPRENE, CIS;Trans-polyisoprene;1,3-Butadiene, 2-methyl-, homopolymer;isoprened;Kraton[R]
CBNumber:
CB1382840
분자식:
C5H8
포뮬러 무게:
68.12
MOL 파일:
9003-31-0.mol
MSDS 파일:
SDS

폴리이소프렌 속성

녹는점
64 °C
끓는 점
122-142 °C(lit.)
밀도
0.92 g/mL at 25 °C
굴절률
n20/D 1.521
인화점
>230 °F
저장 조건
2-8°C
물리적 상태
슬래브/청크
CAS 데이터베이스
9003-31-0
EPA
1,3-Butadiene, 2-methyl-, homopolymer (9003-31-0)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T
위험 카페고리 넘버 60-61-10-20/21-38
안전지침서 24/25-7/9-45-36/37-16-53
유엔번호(UN No.) UN 1307 3/PG 3
WGK 독일 3
RTECS 번호 VL8020000
유해 물질 데이터 9003-31-0(Hazardous Substances Data)
기존화학 물질 KE-23528
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H226 인화성 액체 및 증기 인화성 액체 구분 3 경고
H304 삼켜서 기도로 유입되면 치명적일 수 있음 흡인 유해성물질 구분 1 위험 GHS hazard pictograms
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
H412 장기적 영향에 의해 수생생물에 유해함 수생 환경유해성 물질 - 만성 구분 3 P273, P501
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P310 삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P331 토하게 하지 마시오.

폴리이소프렌 C화학적 특성, 용도, 생산

개요

Polyisoprene is the polymer known as natural rubber, although it can also be manufactured. The natural rubber latex is harvested from the rubber tree, Hevea brasiliensis. This substance has a variety of natural additives, such as proteins and sugars. The polymer from the natural latex is resistant to many solvents and also is easily processed. The synthetic form of this rubber is produced from a pure isoprene solution with a stereospecific isomer to produce the more commonly used cis-l,4 isomer. These rubbers are resistant to abrasion and most solvents and are commercially used in automobile tires, adhesives, and a variety of products that come in close contact with the general public. Their use in baby bottle nipples is a good indication of the extremely low toxicity associated with these elastomers.
Polyisoprene structure

화학적 성질

There are two main solvents for rubber: turpentine and naptha (petroleum). Because rubber does not dissolve easily, the material is finely divided by shredding prior to immersion. Natural rubber has been partially replaced by synthetics, particularly styrene–butadiene, as a generalpurpose rubber. High resilience, low heat buildup, and easy processing are particular advantages of natural rubber when it is often used in blends with synthetic polyisoprene and other elastomers. Natural rubber, alone and in combination with neoprene, has been rated highly for resistance to water, dimethyl sulfoxide, and some alcohols in a comparative test of glove materials; resistance to other solvents varied from good to poor. Polyisoprene supports combustion.

용도

Natural rubber is a vital, strategic, and irreplaceable raw material used in enormous quantities by the commercial, medical, transportation, and defense industries. At least 40,000 different products and over 400 medical devices contain natural rubber.

생산 방법

The latex of natural rubber is obtained from trees (Hevea brasiliensis); the actual monomer is isopentenyl pyrophosphate that has been formed by biosynthesis. Natural rubber contains low-molecular-weight impurities; small amounts of sugar, fatty acids, proteins, and trace metals all play an important part in processing.
Depending on the catalyst, rubber may undergo 1,2-; 3,4-; or 1,4- additional polymerization that leads to several isomeric structures.
Almost all commercial synthetic polyisoprenes are prepared from purified isoprene monomer by a solution process. A stereospecific catalyst, such as an Al–Ti Ziegler type, is required for direct polymerization to the cis-1,4 isomer.
The production of the finished polymer requires two separate manufacturing processes: (a) formation of the rawpolymer and (b) conversion of the polymer to the finished rubber product. The first step is similar to that of plastic production. Large-scale operations use bulk materials in an enclosed system.

정의

The major component of natural rubber, also made synthetically. Forms are stereospecific cis-1,4and trans-1,4-polyisoprene.Both can be produced synthetically by the effect of heat and pressure on isoprene in the presence of stereospecific catalysts. Nat

일반 설명

Available as part of Negative Photoresist kit 654892

공업 용도

Rubber is characterized as being a highly elastic or resilient material, and the natural product is obtained mainly as a latex from cuts in the trunks of the Hevea brasiliensis tree. The latex consists of small particles (averaging about 2500 ? units in diameter) of rubber suspended in an aqueous medium (at about 35% solids content). The system also contains about 6 to 8% nonrubber constituents, some of which are emulsifiers, naturally occurring antioxidants, and proteins.
Natural rubber is used for making many types of articles. Because of its abrasion-resistant quality and low hysteresis in reinforced compounds, it is used in truck-tire tread stocks and in conveyor belts that which are employed in conveying abrasive material such as coal, crushed rock, ore, and cinders. In large tires, it has found application in carcass compounds because of the tack and building qualities of the raw polymer. It has also been used in carcass compounds because of the low heat buildup (low hysteresis) of the carcass compound vulcanizate during severe service conditions in tire usage.

폴리이소프렌 준비 용품 및 원자재

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