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ChemicalBook >제품 카탈로그 >제약 중간체>헤테로 사이 클릭 화합물>피리딘 화합물>피리딘 유도체>2,2′:6′,2′′-터피리딘

2,2′:6′,2′′-터피리딘

2,2′:6′,2′′-터피리딘
2,2′:6′,2′′-터피리딘 구조식 이미지
카스 번호:
1148-79-4
한글명:
2,2′:6′,2′′-터피리딘
동의어(한글):
2,2':6',2-터피리딘;2,2′:6′,2′′-터피리딘;2,2':6',2"-터피리딘
상품명:
2,2':6',2''-TERPYRIDINE
동의어(영문):
Terpyridine;TERPY;´SKL085;Ba 2799;Nsc3905;TRIPYRIDYL;Terpyridyl;Trypyridyl;TRIPYRIDINE
CBNumber:
CB1407532
분자식:
C15H11N3
포뮬러 무게:
233.27
MOL 파일:
1148-79-4.mol
MSDS 파일:
SDS

2,2′:6′,2′′-터피리딘 속성

녹는점
90-93 °C
끓는 점
370 °C
밀도
1.1901 (rough estimate)
굴절률
1.5610 (estimate)
저장 조건
Sealed in dry,Room Temperature
용해도
디옥산: 0.1 g/mL, 투명
산도 계수 (pKa)
4.60±0.10(Predicted)
물리적 상태
결정성 분말
색상
크림색에서 노란색, 갈색까지
수용성
1.472g/L(24.99ºC)
BRN
11199
InChIKey
DRGAZIDRYFYHIJ-UHFFFAOYSA-N
CAS 데이터베이스
1148-79-4(CAS DataBase Reference)
EPA
2,2':6',2''-Terpyridine (1148-79-4)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T+,T
위험 카페고리 넘버 27/28-37/38-41
안전지침서 26-28-36/37/39-45
유엔번호(UN No.) UN 2811 6.1/PG 1
WGK 독일 3
TSCA Yes
위험 등급 6.1
포장분류 I
HS 번호 29333990
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H318 눈에 심한 손상을 일으킴 심한 눈 손상 또는 자극성 물질 구분 1 위험 GHS hazard pictograms P280, P305+P351+P338, P310
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고 GHS hazard pictograms
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P262 눈, 피부, 의복에 묻지 않도록 하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P310 삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
1
4 0

2,2′:6′,2′′-터피리딘 C화학적 특성, 용도, 생산

개요

A case of occupational dermatitis was reported in a chemical technician, with no cross reactivity to pyridine derivatives.

화학적 성질

Off-white crystal

용도

2,2';6',2"-terpyridine is widely utilized in the field of supramolecular chemistry, which is used to manufacture the racks, ladders and grids, helicates, catenanes and dendrimers. It plays an important role as a ligand in coordination chemistry. Its complexes are employed in the oxidation of alcohols, the carbonylation of aromatic compounds and as oxygen-binding molecules. Functionalized terpyridine ligands were used in semiconductors and solar panels. It forms chealate complexes with europium(III) and terbium(III), which is used in protein labelling.

정의

ChEBI: A tridentate heterocyclic ligand that binds metals at three meridional sites giving two adjacent 5-membered MN2C2 chelate rings.

일반 설명

2,2′:6′,2′′;-Terpyridine is a tridentate ligand that can be prepared in two steps starting from 2-acetylpyridine.

색상 색인 번호

This molecule is a terpyridine with a 4-methyl substitution. A case of occupational dermatitis was reported in a chemical technician with no cross-reactivity to pyridine derivatives.

Purification Methods

Crystallise it from diethyl ether, toluene or from pet ether, then aqueous MeOH, followed by sublimation in a vacuum at 90o. It is used for estimating Ag and Ru. [Kamra et al. Anal Chim Acta 81 177 1976, Beilstein 26 III/IV 258.]

2,2′:6′,2′′-터피리딘 준비 용품 및 원자재

원자재

3,3-bis(methylsulfanyl)-1-pyridin-2-ylprop-2-en-1-one TRIMETHYL(2-PYRIDYL)TIN 2,6-Diiodopyridine 4'-(METHYLTHIO)-2,2':6',2''-TERPYRIDINE 4-Bromo-2,2''-bipyridine 4'-CHLORO-2,2':6',2''-TERPYRIDINE 5-BROMO-2,2'-BIPYRIDINE 6-BROMO-2,2'-BIPYRIDINE 2-아세틸피리딘 2,6-Dibromopyridine 4-피리딘붕소산

준비 용품

2,2′:6′,2′′-터피리딘 공급 업체

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2,2′:6′,2′′-터피리딘 관련 검색:

2,2′:6′,2′′-터피리딘 4'-CHLORO-2,2':6',2''-TERPYRIDINE,4'-CHLORO-2,2'6'2''-TERPYRIDINE [2,2':6',2''-TERPYRIDINE]-3',4'-DICARBOXYLIC ACID 4,4',4''-TRI-TERT-BUTYL-2,2':6',2''-TERPYRIDINE 1,6-DIHYDRO-[3,2':4',3'']-TERPYRIDINE 6''-CHLORO-[3,2':5',3'']-TERPYRIDINE 4',4''''-(1,4-PHENYLENE)BIS(2,2':6',2''-TERPYRIDINE) 6,6''-DIBROMO-2,2':6',2''-TERPYRIDINE,6,6-DIBROMO-2,2:6,2-TERPYRIDINE 6,6''-DIMETHYL-[2,2':6',2''-TERPYRIDINE]-4'-CARBOXYLIC ACID ETHYL ESTER 5,5''-DIMETHYL-[2,2':6',2''-TERPYRIDINE]-4'-CARBOXYLIC ACID 2,2':6',2''-TERPYRIDINE-4'-CARBOXYLIC ACID [2,2':6',2''-TERPYRIDINE]-4'-CARBOXYLIC ACID BUTYL ESTER 4'-(4-NITROPHENYL)-2,2':6',2''-TERPYRIDINE 4'-PHENYL-2,2':6',2''-TERPYRIDINE 5,5''-DIMETHYL-[2,2':6',2''-TERPYRIDINE]-4'-CARBOXYLIC ACID ETHYL ESTER ETHYL 2,2':6',2''-TERPYRIDINE-4'-CARBOXYLATE DICHLORO(2 2':6' 2''-TERPYRIDINE)- 5-METHYL-4'-NITRO-2,2':6',2''-TERPYRIDINE
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