디이소부틸아민

디이소부틸아민
디이소부틸아민 구조식 이미지
카스 번호:
110-96-3
한글명:
디이소부틸아민
동의어(한글):
다이-아이소-뷰틸아민;다이아이소뷰틸아민;디이소부틸아민;다이-아이소부틸아민;2-메틸-N-(2-메틸프로필)-1-프로판아민;비스(2-메틸프로필)아민
상품명:
Diisobutylamine
동의어(영문):
DIBA;(i-C4H9)2NH;Diisobutylamin;AURORA KA-7633;DIISOBUTYLAMINE;amine,diisobutyl;Di-n-isobutylaMine;Diisobutylamine,99%;diisobutylamine diba;LABOTEST-BB LTBB000475
CBNumber:
CB4279808
분자식:
C8H19N
포뮬러 무게:
129.24
MOL 파일:
110-96-3.mol
MSDS 파일:
SDS

디이소부틸아민 속성

녹는점
-77 °C (lit.)
끓는 점
137-139 °C (lit.)
밀도
0.74 g/mL at 25 °C (lit.)
굴절률
n20/D 1.4081(lit.)
인화점
85 °F
저장 조건
Flammables area
용해도
insoluble to slightly soluble in water; soluble in ethanol, methanol, ethyl ether, ethyl acetate, acetone, benzene, aromatic and aliphatic hydrocarbons, fixed oils, mineral oil, oleic and stearic acids
산도 계수 (pKa)
11.07±0.28(Predicted)
물리적 상태
액체
색상
투명한
냄새
아민 냄새
수용성
5g/L(20℃)
감도
Air Sensitive
BRN
1209251
Dielectric constant
2.7(22℃)
LogP
2.383 (est)
CAS 데이터베이스
110-96-3(CAS DataBase Reference)
NIST
1-Propanamine, 2-methyl-N-(2-methylpropyl)-(110-96-3)
EPA
Diisobutylamine (110-96-3)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 C
위험 카페고리 넘버 10-22-34-52/53
안전지침서 26-36/37/39-45-25-16-61
유엔번호(UN No.) UN 2361 3/PG 3
WGK 독일 1
RTECS 번호 TX1750000
F 고인화성물질 34
TSCA Yes
위험 등급 3
포장분류 III
HS 번호 29211990
유해 물질 데이터 110-96-3(Hazardous Substances Data)
기존화학 물질 KE-05-0500
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H226 인화성 액체 및 증기 인화성 액체 구분 3 경고
H301 삼키면 유독함 급성 독성 물질 - 경구 구분 3 위험 GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H412 장기적 영향에 의해 수생생물에 유해함 수생 환경유해성 물질 - 만성 구분 3 P273, P501
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
3
3 0

디이소부틸아민 MSDS


Diisobutylamine

디이소부틸아민 C화학적 특성, 용도, 생산

화학적 성질

The chemical reactivity of diisobutylamine is similar to other aliphatic amines and is governed by the unshared electron pair on the nitrogen atom. It is a strong base tending to form salts with acids. As with other secondary amines, diisobutylamine can be nitrosated, especially under acidic conditions, by nitrite ion or by nitrogen oxides from the air to form the carcinogenic and mutagenic N-nitrosodiisobutylamine (Olah et al 1975).

용도

Diisobutylamine was used to study the effect of achiral amine on hydrogenation of ethyl pyruvate over cinchonidine-Pt/Al2O3 catalyst system. Diisobutylamine is the principal starting material for the herbicide Butylate (Zeneca).

생산 방법

Diisobutylamine can be produced by the reaction of ammonia and butanol over a dehydration catalyst at high temperature and pressure (Hawley 1977). Alternatively, ammonia, butanol, and hydrogen can be passed over a dehydrogenation catalyst. In 1976, 18,000 tons of diisobutylamine were produced (Schweizer et al 1978). Diisobutylamine is also naturally present in foods and soil.
As with other secondary amines, diisobutylamine can be nitrosated to form the highly toxic (Olah 1975) N-nitrosodiisobutylamine (Guttenplan 1987; Vlasenko et al 1981; Spiegeholder et al 1978). Thus, nitrosation of commercial preparations of diisobutylamine occurs on standing, presumably by reaction with nitrogen oxides in the air (Spiegelhalder et al 1978) and N-nitrosodiisobutylamine has been found in various fishery products (Kawabata et al 1974) and other foods (Osborne 1972; Telling 1972).

일반 설명

Diisobutylamine appears as a clear colorless liquid with an ammonia-like odor. Insoluble in water and less dense than water. Hence floats on water. Vapors heavier than air. Toxic oxides of nitrogen produced during combustion.

공기와 물의 반응

Highly flammable. Sensitive to heat and air. Insoluble in water.

반응 프로필

Diisobutylamine can react vigorously with oxidizing materials . Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

건강위험

Diisobutylamine is a relatively strong base and is therefore irritating to the eyes, respiratory tract, and skin. Inhalation of vapors can result in pulmonary edema following prolonged exposure. Ingestion of liquid can cause severe burning of the esophagus.

공업 용도

Diisobutylamine is used as a chemical intermediate in the manufacture of several agricultural and pharmaceutical products.

Safety Profile

Poison by ingestion. A dangerous fire hazard when exposed to heator flame; can react vigorously with oxidizing materials. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits toxic fumes of Nox

신진 대사

There is little information available on the metabolism of diisobutylamine.

디이소부틸아민 준비 용품 및 원자재

원자재

준비 용품


디이소부틸아민 공급 업체

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