유사저빈

유사저빈
유사저빈 구조식 이미지
카스 번호:
36069-05-3
한글명:
유사저빈
동의어(한글):
유사저빈
상품명:
PSEUDOJERVINE
동의어(영문):
PSEUDOJERVINE;Spiro[9H-benzo[a]fluorene-9,2'(3'H)-furo[3,2-b]pyridin]-11(1H)-one, 3-(β-D-glucopyranosyloxy)-2,3,3'a,4,4',5',6,6',6a,6b,7,7',7'a,8,11a,11b-hexadecahydro-3',6',10,11b-tetramethyl-, (2'R,3S,3'R,3'aS,6'S,6aS,6bS,7'aR,11aS,11bR)-
CBNumber:
CB61424850
분자식:
C33H49NO8
포뮬러 무게:
587.749
MOL 파일:
36069-05-3.mol

유사저빈 속성

녹는점
300-301° (dec)
알파
D25 -133° (c = 0.48 in 1:3 ethanol-chloroform)
끓는 점
643.44°C (rough estimate)
밀도
1.1485 (rough estimate)
굴절률
1.5960 (estimate)
산도 계수 (pKa)
12.91±0.70(Predicted)

안전

유사저빈 C화학적 특성, 용도, 생산

개요

This alkaloid has been found in both Veratrum album and V. viride Ait. It crystallizes from EtOH in hexagonal tablets and has [α]20D - 139° (CHC13). The hydrochloride dihydrate has m.p. 254-6°C (dry, dec.); the sulphate is also crystalline but the aurichloride is amorphous. Poethke has shown that the alkaloid is a secondary base, gives a nitro so derivative, m.p. 261°C, and contains five replaceable hydrogen atoms. On boiling with dilute HCl it is hydrolyzed to (+)- glucose and isojervine, an isomer of jervine. This latter base crystallizes with solvent, e.g. the CHC13 adduct softens at 135-1500 C; the crystallizate with EtOH has m.p. 114-6°C (dec.) and that with Me2CO has m.p. 110-4°C; [α]20D - 32° (EtOH).

참고 문헌

Wright, Luff., J. Chem. Soc., 35,405,421 (1879)
Salzberger., Arch. Pharm., 228,462 (1890)
Poethke., ibid, 275,357,571 (1937)
Poethke., ibid, 276, 170 (1938)
Jacobs, Craig.,J. Biol. Chem., 155,564 (1944)

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