salutaridine

salutaridine 구조식 이미지
카스 번호:
1936-18-1
상품명:
salutaridine
동의어(영문):
salutaridine;5,6,8,14-Tetradehydro-4-hydroxy-3,6-dimethoxy-17-methylmorphinan-7-one;Morphinan-7-one, 5,6,8,14-tetradehydro-4-hydroxy-3,6-dimethoxy-17-methyl-
CBNumber:
CB81384792
분자식:
C19H21NO4
포뮬러 무게:
327.37
MOL 파일:
1936-18-1.mol

salutaridine 속성

녹는점
197-198°
알파
D12 +114° (c = 0.5 in methanol)
끓는 점
532.5±50.0 °C(Predicted)
밀도
1.33±0.1 g/cm3(Predicted)
용해도
클로로포름(약간 용해됨), 메탄올(약간 용해됨)
물리적 상태
고체
물리적 상태
단단한 모양
산도 계수 (pKa)
9.28±0.40(Predicted)
색상
옅은 갈색에서 밝은 갈색까지

안전

유해 물질 데이터 1936-18-1(Hazardous Substances Data)

salutaridine C화학적 특성, 용도, 생산

개요

An alkaloid obtained from Croton salutaris, this base has been postulated as an intermediate compound in the biosynthesis of the morphine alkaloids. It yields colourless rods when crystallized from AcOEt and has [α]D + 111 ° (c 1.69, EtOH). The ultraviolet spectrum in EtOH has two absorption maxima at 240 and 277 mJl. Two methoxyl groups, a phenolic hydroxyl group and a methylimino group are present, the base furnishing an O-acetate, m.p. 171°C; [α]D + 120° (c 1.25, EtOH). More recently, it has been discovered in Croton balsamifera Jacq. and Papaver orientale.

용도

Salutaridine is one of the biosynthetic precursors of morphine (M652290), a principle alkaloid of opium.

참고 문헌

Barton et al., J. Chem. Soc., 2423 (1965)
Battersby, Brown., Chem. Commun., 170 (1966)
Chambers, Haynes, Stuart., ibid, 449 (1966)
Mass spectra:
Wheeler, Kinstle, Rinehart.,J. Amer. Chem. Soc., 89,4494 (1967)

salutaridine 준비 용품 및 원자재

원자재

준비 용품


salutaridine 공급 업체

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