네오포닌

네오포닌
네오포닌 구조식 이미지
카스 번호:
33540-08-8
한글명:
네오포닌
동의어(한글):
네오포닌
상품명:
NEOEVONINE
동의어(영문):
Evorine;Neoevonin;NEOEVONINE;6-O-Deacetylevonine;8,11-Epoxy-9,12-ethano-11,15-methano-11H-[1,8]dioxacycloheptadecino[4,3-b]pyridine-5,17,22-trione, 13,14,21-tris(acetyloxy)-12-[(acetyloxy)methyl]-7,8,9,10,12,13,14,15,18,19-decahydro-10,20-dihydroxy-8,18,19,20-tetramethyl-, (8R,9R,10R,11S,12S,13R,14R,15S,18S,19S,20S,21S)- (9CI)
CBNumber:
CB81426151
분자식:
C34H41NO16
포뮬러 무게:
719.69
MOL 파일:
33540-08-8.mol

네오포닌 속성

녹는점
264-SoC
끓는 점
800.1±65.0 °C(Predicted)
밀도
1.44±0.1 g/cm3(Predicted)
산도 계수 (pKa)
11.97±0.70(Predicted)

안전

네오포닌 C화학적 특성, 용도, 생산

개요

A second macrocyclic alkaloid found in Euonymus sieboldiana Blume, this base also crystallizes as colourless crystals and is best purified by recrystallization from EtOH. It is dextrorotatory having [α]D + 24.9° (c 1.27, CHCI3). The ultraviolet spectrum is very similar to that of the preceding alkaloid with absorp_x0002_tion maxima at 224 and 26S mJi. The structure, as determined from the NMR and mass spectra is virtually identical with that of neoeuonymine, the only difference being the replacement of an acetoxy group with a ketone group in the reduced naphthalene moiety.

참고 문헌

Sugiura et al., Tetrahedron Lett., 2733 (1971)
Stereochemistry: Wada et al., Tetrahedron Lett., 3131 (1971)

네오포닌 준비 용품 및 원자재

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준비 용품


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