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ChemicalBook >> CAS DataBase List >>CROTONALDEHYDE

CROTONALDEHYDE suppliers

CROTONALDEHYDE

CAS:
4170-30-3
MF:
C4H6O
MW:
70.09

Company Type

Properties

Melting point:
−76 °C(lit.)
Boiling point:
104 °C(lit.)
Density 
0.853 g/mL at 20 °C(lit.)
vapor density 
2.41 (vs air)
vapor pressure 
32 mm Hg ( 20 °C)
refractive index 
n20/D 1.437
Flash point:
48 °F
storage temp. 
2-8°C
solubility 
Miscible with alcohol, benzene, gasoline, kerosene, solvent naphtha, and toluene (Hawley, 1981)
form 
Colorless liquid
color 
Colourless
Odor Threshold
0.023ppm
Water Solubility 
Soluble in water. (150g/L) at 20°C.
Sensitive 
Air Sensitive
Merck 
13,2624
BRN 
1209254
Henry's Law Constant
1.92 x 10-5 atm?m3/mol (Buttery et al., 1971)
Exposure limits
NIOSH REL: TWA 2 ppm (6 mg/m3), IDLH 50 ppm; OSHA PEL: TWA 2 ppm; ACGIH TLV: ceiling 0.3 ppm (adopted).
Stability:
Air sensitive. Highly flammable. Readily forms explosive mixtures with air. May polymerize in the presence of acids, alkalies or amines. Uncontrolled polymerisation may lead to a rapid temperature rise. Incompatible with acids, bases, amines, strong oxidizing agents, butadiene, ketones, oxygen. May contain a stabilizer.
LogP
0.6 at 25℃

Safety Information

Symbol(GHS) 
GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS06,GHS08,GHS09
Signal word 
Danger
Hazard statements 
H225-H301+H311-H315-H318-H330-H335-H341-H373-H400
Precautionary statements 
P201-P210-P280-P301+P310+P330-P304+P340+P310-P305+P351+P338+P310
Hazard Codes 
F,T+,N
Risk Statements 
11-24/25-26-37/38-41-48/22-50-68
Safety Statements 
26-28-36/37/39-45-61-16
RIDADR 
UN 1143 6.1/PG 1
WGK Germany 
3
RTECS 
GP9625000
9-13-23
TSCA 
Yes
HazardClass 
6.1(a)
PackingGroup 
I
Toxicity
LD50 orally in rats: 0.3 g/kg (Smyth, Carpenter)
IDLA
50 ppm

Use

CROTONALDEHYDE can react violently with strong oxidizing reagents, e.g., reaction with conc. nitric acid leads to instantaneous ignition [Andrussow, L., Chim. Ind. (Paris), 1961, 86, p. 542]. In contact with strong acids or bases CROTONALDEHYDE will undergo an exothermic condensation reaction. Reaction with 1,3-butadiene is particularly violent [Greenlee, K. W., Chem. Eng. News, 1948, 26, p. 1985]. Crotonaldehyde may rapidly polymerize with ethyl acetoacetate (Soriano, D.S. et al. 1988. Journal of Chemical Education 65:637.).

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