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ChemicalBook >> CAS DataBase List >> Trimethylsilyl trifluoromethanesulfonate

Trimethylsilyl trifluoromethanesulfonate

Trimethylsilyl trifluoromethanesulfonate price.
  • $10 - $2143.23
  • Product name: Trimethylsilyl trifluoromethanesulfonate
  • CAS: 27607-77-8
  • MF: C4H9F3O3SSi
  • MW: 222.26
  • EINECS:248-565-4
  • MDL Number:MFCD00000406
  • Synonyms:CT3795;Methanesulfonic acid, trifluoro-, trimethylsilyl ester;SILANE TMS-TRIFLATE;TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE;TRIMETHYLSILYL TRIFLUOROMETHYLSULPHONATE;TRIFLUOROMETHANSULFONIC ACID TRIMETHYLSILYL ESTER;TRIFLUOROMETHANESULFONIC ACID TRIMETHYLSILYL ESTER;Trimethylsilyl Trifluoromethanesulfonate [Trimethylsilylating Agent]
46 prices
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  • AK Scientific
  • Alfa Aesar
  • Apolloscientific
  • Chem-Impex
  • ChemSupplyAustralia
  • Crysdot
  • Medical Isotopes, Inc.
  • Oakwood
  • Sigma-Aldrich
  • Strem Chemicals
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  • TCI Chemical
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  • 8181290010
  • 250g-f
  • 8181290100
  • 250g
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  • 500g
  • 1KG
  • 2.5Kg
  • 5KG
  • ManufacturerAK Scientific
  • Product numberX7181
  • Product descriptionTrimethylsilyl trifluoromethanesulfonate
  • Packaging5g
  • Price$14
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ70009
  • Product descriptionTrimethylsilyl trifluoromethanesulfonate
  • Packaging30g
  • Price$26.4
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberX7181
  • Product descriptionTrimethylsilyl trifluoromethanesulfonate
  • Packaging100g
  • Price$79
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA12535
  • Product descriptionTrimethylsilyl trifluoromethanesulfonate 99%
  • Packaging10g
  • Price$45.4
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA12535
  • Product descriptionTrimethylsilyl trifluoromethanesulfonate 99%
  • Packaging50g
  • Price$146
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA12535
  • Product descriptionTrimethylsilyl trifluoromethanesulfonate 99%
  • Packaging250g
  • Price$546
  • Updated2024-03-01
  • Buy
  • ManufacturerApolloscientific
  • Product numberPC7867
  • Product descriptionTrimethylsilyltrifluoromethanesulphonate 98%
  • Packaging25g
  • Price$15
  • Updated2021-12-16
  • Buy
  • ManufacturerApolloscientific
  • Product numberPC7867
  • Product descriptionTrimethylsilyltrifluoromethanesulphonate 98%
  • Packaging100g
  • Price$44
  • Updated2021-12-16
  • Buy
  • ManufacturerApolloscientific
  • Product numberPC7867
  • Product descriptionTrimethylsilyltrifluoromethanesulphonate 98%
  • Packaging250g
  • Price$90
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number24444
  • Product descriptionTrimethylsilyltrifluoromethanesulfonate,99%(Titration) 99%(Titration)
  • Packaging25G
  • Price$15.12
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number24444
  • Product descriptionTrimethylsilyltrifluoromethanesulfonate,99%(Titration) 99%(Titration)
  • Packaging100G
  • Price$56
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number24444
  • Product descriptionTrimethylsilyltrifluoromethanesulfonate,99%(Titration) 99%(Titration)
  • Packaging250G
  • Price$123.2
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number24444
  • Product descriptionTrimethylsilyltrifluoromethanesulfonate,99%(Titration) 99%(Titration)
  • Packaging1KG
  • Price$464.8
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number24444
  • Product descriptionTrimethylsilyltrifluoromethanesulfonate,≥99%(Titration)Hazmat ≥99%(Titration)
  • Packaging5KG
  • Price$2143.23
  • Updated2021-12-16
  • Buy
  • ManufacturerChemSupplyAustralia
  • Product number300455
  • Product descriptionTrimethylsilyl trifluoromethanesulfonate, 99%
  • Packaging10g
  • Price$28.6
  • Updated2021-12-16
  • Buy
  • ManufacturerChemSupplyAustralia
  • Product number300455
  • Product descriptionTrimethylsilyl trifluoromethanesulfonate, 99%
  • Packaging50g
  • Price$99
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific X7181 Trimethylsilyl trifluoromethanesulfonate 5g $14 2021-12-16 Buy
AK Scientific J70009 Trimethylsilyl trifluoromethanesulfonate 30g $26.4 2021-12-16 Buy
AK Scientific X7181 Trimethylsilyl trifluoromethanesulfonate 100g $79 2021-12-16 Buy
Alfa Aesar A12535 Trimethylsilyl trifluoromethanesulfonate 99% 10g $45.4 2024-03-01 Buy
Alfa Aesar A12535 Trimethylsilyl trifluoromethanesulfonate 99% 50g $146 2024-03-01 Buy
Alfa Aesar A12535 Trimethylsilyl trifluoromethanesulfonate 99% 250g $546 2024-03-01 Buy
Apolloscientific PC7867 Trimethylsilyltrifluoromethanesulphonate 98% 25g $15 2021-12-16 Buy
Apolloscientific PC7867 Trimethylsilyltrifluoromethanesulphonate 98% 100g $44 2021-12-16 Buy
Apolloscientific PC7867 Trimethylsilyltrifluoromethanesulphonate 98% 250g $90 2021-12-16 Buy
Chem-Impex 24444 Trimethylsilyltrifluoromethanesulfonate,99%(Titration) 99%(Titration) 25G $15.12 2021-12-16 Buy
Chem-Impex 24444 Trimethylsilyltrifluoromethanesulfonate,99%(Titration) 99%(Titration) 100G $56 2021-12-16 Buy
Chem-Impex 24444 Trimethylsilyltrifluoromethanesulfonate,99%(Titration) 99%(Titration) 250G $123.2 2021-12-16 Buy
Chem-Impex 24444 Trimethylsilyltrifluoromethanesulfonate,99%(Titration) 99%(Titration) 1KG $464.8 2021-12-16 Buy
Chem-Impex 24444 Trimethylsilyltrifluoromethanesulfonate,≥99%(Titration)Hazmat ≥99%(Titration) 5KG $2143.23 2021-12-16 Buy
ChemSupplyAustralia 300455 Trimethylsilyl trifluoromethanesulfonate, 99% 10g $28.6 2021-12-16 Buy
ChemSupplyAustralia 300455 Trimethylsilyl trifluoromethanesulfonate, 99% 50g $99 2021-12-16 Buy

Properties

Melting point :25°C
Boiling point :77 °C/80 mmHg (lit.)
Density :1.228 g/mL at 25 °C (lit.)
vapor pressure :4.7 hPa (20 °C)
refractive index :n20/D 1.36(lit.)
Flash point :78 °F
storage temp. :Store below +30°C.
solubility :sol aliphatic and aromatic hydrocarbons, haloalkanes, ethers.
form :Fuming Liquid
color :Clear colorless to light brown
Specific Gravity :1.15
Water Solubility :REACTS
Sensitive :Moisture Sensitive
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
Merck :14,9719
BRN :1868911
InChIKey :FTVLMFQEYACZNP-UHFFFAOYSA-N
CAS DataBase Reference :27607-77-8(CAS DataBase Reference)
NIST Chemistry Reference :Trimethylsilyl trifluoromethanesulfonate(27607-77-8)
EPA Substance Registry System :Methanesulfonic acid, trifluoro-, trimethylsilyl ester (27607-77-8)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Trimethylsilyl trifluoromethanesulfonate is used to prepare powerful Lewis acid, difluoroboron triflate etherate in acetonitrile solvent. It is also used as a reagent in a Dieckmann-like cyclization of ester-imides and diesters. Further, it is used in the conversion of carbonyl compounds to their enol ethers. It is also employed for chemical glycosylation reactions. Its reactivity is similar to trimethylsilyl chloride and is also involved in organic synthesis.

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