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ChemicalBook >> CAS DataBase List >> (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE

(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE

(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE price.
  • $67 - $547
  • Product name: (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE
  • CAS: 364732-88-7
  • MF: C40H34P2
  • MW: 576.65
  • EINECS:
  • MDL Number:MFCD03094575
  • Synonyms:(R)-Phanephos, 98%, ee 98%;(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane,99%e.e.;(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95%;(Rp)-(-)-4,12-Bis(diphenylphosphino)[2.2]paracyclophane;Phosphine, 1,1'-(tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diyl)bis[1,1-diphenyl-, stereoisomer;(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95%,99%ee
Price14 Properties Safety Information Description
14 prices
Selected condition：
Brand
  • Alfa Aesar
  • Ambeed
  • Arctom
  • BLDpharm
  • Sigma-Aldrich
  • Strem Chemicals
Package
  • 50mg
  • 100mg
  • 250mg
  • 500mg
  • ManufacturerAlfa Aesar
  • Product numberH25812
  • Product description(R)-Phanephos, 98%, ee 98%
  • Packaging250mg
  • Price$139.18
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA174075
  • Product description(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98%
  • Packaging50mg
  • Price$75
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA174075
  • Product description(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98%
  • Packaging100mg
  • Price$132
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA174075
  • Product description(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98%
  • Packaging250mg
  • Price$285
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS463635
  • Product description(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98%
  • Packaging50mg
  • Price$67
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS463635
  • Product description(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98%
  • Packaging100mg
  • Price$117
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS463635
  • Product description(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98%
  • Packaging250mg
  • Price$256
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD634145
  • Product description(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98%
  • Packaging50mg
  • Price$68
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD634145
  • Product description(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98%
  • Packaging100mg
  • Price$118
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD634145
  • Product description(R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98%
  • Packaging250mg
  • Price$259
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number682144
  • Product description(R)-(–)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane 96%
  • Packaging100mg
  • Price$120
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number682144
  • Product description(R)-(–)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane 96%
  • Packaging500mg
  • Price$547
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-0425
  • Product description(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95% (R)-PHANEPHOS
  • Packaging100mg
  • Price$102
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-0425
  • Product description(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95% (R)-PHANEPHOS
  • Packaging500mg
  • Price$412
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar H25812 (R)-Phanephos, 98%, ee 98% 250mg $139.18 2021-12-16 Buy
Ambeed A174075 (R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98% 50mg $75 2021-12-16 Buy
Ambeed A174075 (R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98% 100mg $132 2021-12-16 Buy
Ambeed A174075 (R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98% 250mg $285 2021-12-16 Buy
Arctom AS463635 (R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98% 50mg $67 2021-12-16 Buy
Arctom AS463635 (R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98% 100mg $117 2021-12-16 Buy
Arctom AS463635 (R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98% 250mg $256 2021-12-16 Buy
BLDpharm BD634145 (R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98% 50mg $68 2021-12-16 Buy
BLDpharm BD634145 (R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98% 100mg $118 2021-12-16 Buy
BLDpharm BD634145 (R)-4,12-Bis(diphenylphosphino)-[2.2]paracyclophane 98% 250mg $259 2021-12-16 Buy
Sigma-Aldrich 682144 (R)-(–)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane 96% 100mg $120 2024-03-01 Buy
Sigma-Aldrich 682144 (R)-(–)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane 96% 500mg $547 2024-03-01 Buy
Strem Chemicals 15-0425 (R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95% (R)-PHANEPHOS 100mg $102 2024-03-01 Buy
Strem Chemicals 15-0425 (R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane, min. 95% (R)-PHANEPHOS 500mg $412 2024-03-01 Buy

Properties

Melting point :222-225°C
alpha :-62.6° (c 3.11, CH2Cl2)
storage temp. :Inert atmosphere,Room Temperature
form :solid
color :white
optical activity :[α]/D -34±4°, c = 1 in chloroform
CAS DataBase Reference :364732-88-7

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321 Specific treatment (see … on this label).
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.
P362 Take off contaminated clothing and wash before reuse.

Description

(R)-(-)-4,12-Bis(diphenylphosphino)-[2.2]-paracyclophane may be used as a ligand in the following processes:Enantioselective reductive cyclization of 1,6-enynes via asymmetric hydrogenation in the presence of a rhodium catalyst to form alkylidene-substituted heterocycles.Asymmetric hydroboration of 3,3-disubstituted cyclopropenes to form 2,2-disubstituted cyclopropyl boronates.Asymmetric ring-opening reactions of azabenzonorbornadienes in the presence of zinc(II) triflate and palladium(II) acetate to form aminodihydronaphthalenes.

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Suppliers and manufacturers

career henan chemical co
(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE, 96%
$1.00 /1KG
(R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-(2.2)-PARACYCLOPHANE, 96% CAS:364732-88-7
Chongqing Chemdad Co., Ltd
changzhou huayang technology co., ltd
Hefei TNJ Chemical Industry Co.,Ltd.
Hangzhou MolCore BioPharmatech Co.,Ltd.
Shanghai Acmec Biochemical Technology Co., Ltd.
Aladdin Scientific J & K SCIENTIFIC LTD. Alfa Aesar Energy Chemical