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ChemicalBook >> CAS DataBase List >> Methylmagnesium Bromide

Methylmagnesium Bromide

Methylmagnesium Bromide price.
  • $12 - $4334.49
  • Product name: Methylmagnesium Bromide
  • CAS: 75-16-1
  • MF: CH3BrMg
  • MW: 119.24
  • EINECS:200-844-1
  • MDL Number:MFCD00000041
  • Synonyms:METHYLMAGNESIUM BROMIDE;Methyl magnesium bromide(in ethyl ether);BROMOMETHYLMAGNESIUM;bromomethyl-magnesiu ;methyl-magnesiubromide(ethylethersolution)[qr] ;methylmagnesium bromide sol.;METHYLMAGNESIUM BROMIDE, 1.0M SOLUTION I N BUTYL ETHER;METHYLMAGNESIUM BROMIDE SOL., ~3 M IN DI ETHYL ETHER
31 prices
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Brand
  • Alfa Aesar
  • American Custom Chemicals Corporation
  • Apolloscientific
  • Oakwood
  • Sigma-Aldrich
  • Strem Chemicals
  • TCI Chemical
Package
  • 10ml
  • 0.25mole
  • 25ml
  • 50ml
  • 1mole
  • 4x25ml
  • 100ml
  • 200ml
  • 250G
  • 4x100ml
  • 500ml
  • 800ml
  • 2.4L
  • 8l
  • 18L
  • ManufacturerAlfa Aesar
  • Product number041252
  • Product descriptionMethylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal? bottles
  • Packaging100ml
  • Price$50.6
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number087324
  • Product descriptionMethylmagnesium bromide, 3M in ether
  • Packaging500ml
  • Price$129.65
  • Updated2024-03-01
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  • ManufacturerAlfa Aesar
  • Product number041252
  • Product descriptionMethylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal? bottles
  • Packaging500ml
  • Price$172
  • Updated2024-03-01
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0004503
  • Product descriptionMETHYLMAGNESIUM BROMIDE 95.00%
  • Packaging250G
  • Price$4334.49
  • Updated2021-12-16
  • Buy
  • ManufacturerApolloscientific
  • Product numberOR320077
  • Product descriptionMethylmagnesiumbromide3.2Msolutionin2-MeTHF
  • Packaging100ml
  • Price$116
  • Updated2021-12-16
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  • ManufacturerOakwood
  • Product number102010
  • Product descriptionMethylmagnesium bromide solution 3.0 M in diethyl ether
  • Packaging10ml
  • Price$12
  • Updated2021-12-16
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  • ManufacturerOakwood
  • Product number102010
  • Product descriptionMethylmagnesium bromide solution 3.0 M in diethyl ether
  • Packaging25ml
  • Price$15
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product number102010
  • Product descriptionMethylmagnesium bromide solution 3.0 M in diethyl ether
  • Packaging100ml
  • Price$30
  • Updated2021-12-16
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  • ManufacturerOakwood
  • Product number102010
  • Product descriptionMethylmagnesium bromide solution 3.0 M in diethyl ether
  • Packaging800ml
  • Price$140
  • Updated2021-12-16
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  • ManufacturerOakwood
  • Product number102010
  • Product descriptionMethylmagnesium bromide solution 3.0 M in diethyl ether
  • Packaging2.4L
  • Price$540
  • Updated2021-12-16
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  • ManufacturerSigma-Aldrich
  • Product number189898
  • Product descriptionMethylmagnesium bromide solution 3.0M in diethyl ether
  • Packaging4x25ml
  • Price$51.4
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number189898
  • Product descriptionMethylmagnesium bromide solution 3.0M in diethyl ether
  • Packaging50ml
  • Price$53.8
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number282235
  • Product descriptionMethylmagnesium bromide solution 1.4 M in THF: toluene (1:3)
  • Packaging100ml
  • Price$74.3
  • Updated2024-03-01
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  • ManufacturerSigma-Aldrich
  • Product number703583
  • Product descriptionMethylmagnesium bromide solution ~3.4?M in 2-methyltetrahydrofuran
  • Packaging100ML
  • Price$99.1
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number189898
  • Product descriptionMethylmagnesium bromide solution 3.0M in diethyl ether
  • Packaging100ml
  • Price$102
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number282235
  • Product descriptionMethylmagnesium bromide solution 1.4?M in THF: toluene (1:3)
  • Packaging4X25ML
  • Price$107
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar 041252 Methylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal? bottles 100ml $50.6 2024-03-01 Buy
Alfa Aesar 087324 Methylmagnesium bromide, 3M in ether 500ml $129.65 2024-03-01 Buy
Alfa Aesar 041252 Methylmagnesium bromide, 3M in ether, packaged under Argon in resealable ChemSeal? bottles 500ml $172 2024-03-01 Buy
American Custom Chemicals Corporation ING0004503 METHYLMAGNESIUM BROMIDE 95.00% 250G $4334.49 2021-12-16 Buy
Apolloscientific OR320077 Methylmagnesiumbromide3.2Msolutionin2-MeTHF 100ml $116 2021-12-16 Buy
Oakwood 102010 Methylmagnesium bromide solution 3.0 M in diethyl ether 10ml $12 2021-12-16 Buy
Oakwood 102010 Methylmagnesium bromide solution 3.0 M in diethyl ether 25ml $15 2021-12-16 Buy
Oakwood 102010 Methylmagnesium bromide solution 3.0 M in diethyl ether 100ml $30 2021-12-16 Buy
Oakwood 102010 Methylmagnesium bromide solution 3.0 M in diethyl ether 800ml $140 2021-12-16 Buy
Oakwood 102010 Methylmagnesium bromide solution 3.0 M in diethyl ether 2.4L $540 2021-12-16 Buy
Sigma-Aldrich 189898 Methylmagnesium bromide solution 3.0M in diethyl ether 4x25ml $51.4 2024-03-01 Buy
Sigma-Aldrich 189898 Methylmagnesium bromide solution 3.0M in diethyl ether 50ml $53.8 2024-03-01 Buy
Sigma-Aldrich 282235 Methylmagnesium bromide solution 1.4 M in THF: toluene (1:3) 100ml $74.3 2024-03-01 Buy
Sigma-Aldrich 703583 Methylmagnesium bromide solution ~3.4?M in 2-methyltetrahydrofuran 100ML $99.1 2024-03-01 Buy
Sigma-Aldrich 189898 Methylmagnesium bromide solution 3.0M in diethyl ether 100ml $102 2024-03-01 Buy
Sigma-Aldrich 282235 Methylmagnesium bromide solution 1.4?M in THF: toluene (1:3) 4X25ML $107 2024-03-01 Buy

Properties

Boiling point :78-80℃
Density :1.035 g/mL at 25 °C
Flash point :77 °F
storage temp. :water-free area
form :Solution, may develop some turbidity precipitate
color :Pale brown
Water Solubility :Reacts with water.
Sensitive :Air & Moisture Sensitive
BRN :3535220
Exposure limits :ACGIH: TWA 400 ppm; STEL 500 ppm
OSHA: TWA 400 ppm(1200 mg/m3)
NIOSH: IDLH 1900 ppm InChIKey :AVFUHBJCUUTGCD-UHFFFAOYSA-M
CAS DataBase Reference :75-16-1(CAS DataBase Reference)
EPA Substance Registry System :Magnesium, bromomethyl- (75-16-1)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger GHS hazard pictograms P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H261 In contact with water releases flammable gas Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 2
Category 3
Danger
Warning
GHS hazard pictograms P231+P232, P280, P370+P378,P402+P404, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger GHS hazard pictograms
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger GHS hazard pictograms P280, P305+P351+P338, P310
H320 Causes eye irritation Serious eye damage/eye irritation Category 2B Warning P264, P305+P351+P338,P337+P313
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H371 May cause damage to organs Specific target organ toxicity, single exposure Category 2 Warning P260, P264, P270, P309+P311, P405,P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger GHS hazard pictograms P260, P264, P270, P314, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P231+P232 Handle under inert gas. Protect from moisture.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P309 IF exposed or if you feel unwell:
P310 Immediately call a POISON CENTER or doctor/physician.
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P370+P378 In case of fire: Use … for extinction.
P402+P404 Store in a dry place. Store in a closed container.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P422 Store contents under …
P501 Dispose of contents/container to..…

Description

Methylmagnesium bromide is widely used in organic synthesis.

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