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| | 6,7-Didehydro-16-methoxy-22α-methylobscurinervan-21-one Basic information |
| Product Name: | 6,7-Didehydro-16-methoxy-22α-methylobscurinervan-21-one | | Synonyms: | 6,7-Didehydro-16-methoxy-22α-methylobscurinervan-21-one;Neblinine;1H,6aH,17aH-Furo[2,3-b]indolizino[8,1-cd][1,4]oxazino[2,3,4-jk]carbazol-5(4H)-one, 7,7a,9,10,15,16-hexahydro-12-methoxy-9-methyl-, (3aS,6aS,7aR,9R,14bR,17aS)- | | CAS: | 6872-64-6 | | MF: | C23H26N2O4 | | MW: | 394.46 | | EINECS: | | | Product Categories: | | | Mol File: | 6872-64-6.mol |  |
| | 6,7-Didehydro-16-methoxy-22α-methylobscurinervan-21-one Chemical Properties |
| Melting point | 256-8°C (dec.). |
| | 6,7-Didehydro-16-methoxy-22α-methylobscurinervan-21-one Usage And Synthesis |
| Description | Aspidosperma neblinine Monachino yields this alkaloid which forms transparent
crystals from hexane. It is laevorotatory with [α]27D
- 14° (c 1.19, CHC13).
Catalytic reduction furnishes the dihydro derivative, m.p. 230-3°C (dec.). The
structure is that of 15-demethoxyobscurinervidine. | | References | Brown, Djerassi., J. Amer. Chern. Soc., 86,2451 (1964) |
| | 6,7-Didehydro-16-methoxy-22α-methylobscurinervan-21-one Preparation Products And Raw materials |
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