3-METHYLOXINDOLE 96

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CAS:1504-06-9
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  • CAS:1504-06-9
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3-METHYLOXINDOLE 96 Basic information
Product Name:3-METHYLOXINDOLE 96
Synonyms:3-Methyl-2-oxindole,3-Methyloxindole;1,3-Dihydro-3-Methyl-2H-indol-2-one;3-Methyl-2-indolinone;2H-Indol-2-one, 1,3-dihydro-3-Methyl-;3-Methyl-2-oxindole 96%;(R,S)-3-Methyl-1,3-dihydro-indol-2-one;3-Methyl-1,3-dihydro-indol-2-one;3-METHYLOXINDOLE 96
CAS:1504-06-9
MF:C9H9NO
MW:147.17
EINECS:1533716-785-6
Product Categories:Aromatics, Indole Derivatives, Metabolites & Impurities;Aromatics;Indole Derivatives;Metabolites & Impurities;Building Blocks;C7 to C9;Chemical Synthesis;Heterocyclic Building Blocks;Indoles;Heterocyclic Compounds
Mol File:1504-06-9.mol
3-METHYLOXINDOLE  96 Structure
3-METHYLOXINDOLE 96 Chemical Properties
Melting point 117-121 °C(lit.)
Boiling point 279.3±29.0 °C(Predicted)
density 1.123±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
solubility Chloroform (Slightly), Ethanol (Slightly), Methanol (Slightly)
form Solid
pka14.81±0.40(Predicted)
color Light Beige to Beige
Water Solubility Insoluble in water.
CAS DataBase Reference1504-06-9
Safety Information
WGK Germany 3
HS Code 2933790090
MSDS Information
3-METHYLOXINDOLE 96 Usage And Synthesis
UsesA versatile reactant. As 3-Methylindole metabolite. Reactant for enantioselective α-amination reactions, Reactant for aldol reaction with glyoxal derivatives, Reactant for amine thiourea catalyzed conjugate addition to α,β-unsaturated aldehydes, Reactant for O-acetylation reactions, Reactant for preparation of a disubstituted oxoindole by using rhodium-catalyzed cyclopropanation/ring-opening reactions.
Uses• ;Reactant for enantioselective α-amination reactions1• ;Reactant for aldol reaction with glyoxal derivatives2• ;Reactant for amine thiourea catalyzed conjugate addition to α,β-unsaturated aldehydes3• ;Reactant for O-acetylation reactions4• ;Reactant for preparation of a disubstituted oxoindole by using rhodium-catalyzed cyclopropanation/ring-opening reactions5
DefinitionChEBI: 3-methyloxindole is a member of the class of oxindoles that is oxindole (1,3-dihydro-2H-indol-2-one) in which one of the hydrogens at position 3 has been replaced by a methyl group. It is a member of oxindoles and a methylindole.
General Description3-Methyl-2-oxindole (MOI) is a 3-substituted-2-oxindole. It is reported to be formed during the oxidation of indole-3-acetic acid in the presence of FeII under aerobic conditions. MOI undergoes asymmetric anti-Mannich-type reaction with N-tosyl aryl aldimines in the presence of alkaloid cinchona derivatives to form anti-3,3-disubsituted 2-oxindole derivatives. It also undergoes asymmetric hydroxyamination with nitrosoarenes to form N-nitroso aldol products.
3-METHYLOXINDOLE 96 Preparation Products And Raw materials
Tag:3-METHYLOXINDOLE 96(1504-06-9) Related Product Information
3-Methylthiopropanol 3-(Methylthio)butanal 3-(Methylthio)propionaldehyde 3-Picoline oxyphenisatine di(acetate) 3,3-BIS(P-HYDROXYPHENYL)OXINDOLE GELSEMINE Amedalin ETHYL 3-HYDROXY-4,6-DIMETHOXY-2-OXOINDOLINE-3-CARBOXYLATE 3-PHENYL-OXINDOLE 3-hydroxy-3-acetonyl-2-oxindole 1,3-Dihydro-3,3-dimethyl-2H-indol-2-one 1H-Indole-3-acetonitrile, 2,3-dihydro-2-oxo- 3-HYDROXY-3-PHENYLOXINDOLE 3-(2-AMINO-ETHYL)-1,3-DIHYDRO-INDOL-2-ONE 3-[3-CHLORO-5-(TRIFLUOROMETHYL)-2-PYRIDINYL]-1,3-DIHYDRO-2H-INDOL-2-ONE 3-METHOXY-1-(4-METHOXYPHENYL)-5-((4-METHYLPHENYL)CARBONYL)SPIRO[AZETIDINE-4,3'-INDOLINE]-2,6-DIONE BUTTPARK 58\40-88