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Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)

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Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Suppliers list
Company Name: Alfa Chemistry
Tel: +1-5166625404
Email: Info@alfa-chemistry.com
Products Intro: Product Name:(S)-[(RuCl(SEGPHOS))2(μ-cl)3][NH2Me2]
CAS:488809-34-3
Company Name: Shaoxin Catsyn Co., Ltd.
Tel: +undefined-0575-82040869 +86-0575-82040869;
Email: sales@catsyn.com
Products Intro: Product Name:Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II), [NH2Me2][{RuCl((S)-segphos)}2(μ-Cl)3]
CAS:488809-34-3
Purity:98% Min. Package:1G;1KG;100KG Remarks:SC10193
Company Name: Aladdin Scientific
Tel: +1-833-552-7181
Email: sales@aladdinsci.com
Products Intro: Product Name:(S)-[(RuCl(SEGPHOS;))(μ-Cl)][NHMe]
CAS:488809-34-3
Purity:95% Package:$15.9/50mg;$59.9/250mg;$184.9/1g;Bulk package Remarks:95%
Company Name: J & K SCIENTIFIC LTD.  
Tel: 010-82848833 400-666-7788
Email: jkinfo@jkchemical.com
Products Intro: Product Name:DiMethylaMMoniuM dichlorotri(μ-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((S)-segphos?)}2(μ-Cl)3]
CAS:488809-34-3
Package:1g,250Mg,5g
Company Name: TCI (Shanghai) Development Co., Ltd.  
Tel: 021-67121386
Email: Sales-CN@TCIchemicals.com
Products Intro: Product Name:[NH2Me2][(RuCl((S)-segphos(regR)))2(mu-Cl)3]
CAS:488809-34-3
Package:1G,200MG
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Basic information
Reaction
Product Name:Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)
Synonyms:[NH2Me2][(RuCl((S)-segphos(regR)))2(mu-Cl)3];[NH2ME2][(RUCL((S)-SEGPHOS))2(Μ-CL)3];DIMETHYLAMMONIUM DICHLOROTRI(Μ-CHLORO)BIS[(S)-(-)-5,5'-BIS(DIPHENYLPHOSPHINO)-4,4'-BI-1,3-BENZODIOXOLE]DIRUTHENATE(II),[NH2ME2][;Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II);(S)-[(RuCl(SEGPHOS(R)))2(μ-Cl)3][NH2Me2];Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(-)-5,5μ-bis(diphenylphosphino)-4,4μ-bi-1,3-benzodioxole]diruthenate(II);Dimethylammonium dichlorotri(chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((S)-segphos)}2(Cl)3];DiMethylaMMoniuM dichlorotri(Mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((S)-segphos)}2(μ-Cl)3]
CAS:488809-34-3
MF:C78H68Cl5NO8P4Ru2
MW:1650.69
EINECS:
Product Categories:Ru
Mol File:488809-34-3.mol
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Structure
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Chemical Properties
Melting point >100°C
storage temp. 2-8°C
Water Solubility Insoluble in water
form Powder
color light brown
Sensitive air sensitive
Safety Information
WGK Germany 3
HS Code 2843.90.0000
MSDS Information
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Usage And Synthesis
Reaction
  1. Highly enantioselective, highly active catalyst for hydrogenation of functionalized ketones. The chlororuthenate salts show catalytic activity at relatively low temperature. 
  2. Catalyst for enantioselective hydrogenation of enamines. 
Reactions of 488809-34-3
UsesTakasago Ligands and Complexes for Asymmetric Reactions
Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) Preparation Products And Raw materials
Tag:Dimethylammoniumdichlorotri(mu-chloro)bis[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II)(488809-34-3) Related Product Information
Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((S)-dtbm-segphos)]Cl　 Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl Chloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((S)-dm-segphos)]Cl Chloro{(R)-(-)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II)chloride[RuCl(p-cymene) ((R)-dtbm-segphos)]Cl　 Chloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole} (p-cymene)ruthenium(II)chloride[RuCl(p-cymene)((R)-dm-segphos)]Cl　 Chloro[(S)-(-)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II)chloride[RuCl (p-cymene)((S)-segphos)]Cl　 Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II)[NH2Me2][{RuCl((S)-dm-segphos)}2(μ-Cl)3] Dimethylammonium dichlorotri(chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos)}2(Cl)3] Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)