Beta-Damascone

Beta-Damascone Suppliers list
Company Name: CD Chemical Group Limited
Tel: +8615986615575
Email: info@codchem.com
Products Intro: CAS:35044-68-9
Purity:0.99 Package:1000KG;100KG;5KG;1KG
Company Name: HJ AROCHEM  
Tel: +91-8690768060 +91-9724420086
Email: mail@hjarochem.com
Products Intro: Product Name:BETA DAMASCONE
CAS:35044-68-9
Purity:99% Package:1 kg,5 kg, 10 kg,25kg and 1 MT
Company Name: Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.  
Tel: 025-66099280 17798518460
Email: cfzhang@aikonchem.com
Products Intro: Product Name:1-(2,6,6-Trimethylcyclohex-1-en-1-yl)but-2-en-1-one
CAS:35044-68-9
Purity:95% Package:1g;5g;10g
Company Name: Sigma-Aldrich  
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Email: orderCN@merckgroup.com
Products Intro: Product Name:Beta-Damascone
CAS:35044-68-9
Purity:United States Pharmacopeia (USP) Reference Standard Package:3X0.5ML Remarks:1162648-3X0.5ML
Company Name: Shanghai Witofly Chemical Co. ,Ltd.  
Tel: 021-021-50630626 18964684208
Email: sales@witofly.com
Products Intro: Product Name:Beta-Damascone
CAS:35044-68-9
Purity:98% HPLC Package:25kg
Beta-Damascone Basic information
Product Name:Beta-Damascone
Synonyms:1-(2,6,6-Trimethyl-1-cyclohexenyl)-2-butene-1-one;1-(2-Butenoyl)-2,6,6-trimethyl-1-cyclohexene;BETA-DAMASCONE;2-Buten-1-one, 1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-;B-Damascone;3,4-Dihydro-3,4,7-megastigmatrien-7-one;α-DAMASCONE
CAS:35044-68-9
MF:C13H20O
MW:192.3
EINECS:
Product Categories:
Mol File:35044-68-9.mol
Beta-Damascone Structure
Beta-Damascone Chemical Properties
Boiling point 271.2±10.0 °C(Predicted)
density 0.907±0.06 g/cm3(Predicted)
FEMA 3243 | 1-(2,6,6-TRIMETHYL-1-CYCLOHEXEN-1-YL)-2-BUTEN-1-ONE
storage temp. 2-8°C
Odorat 1.00 % in dipropylene glycol. fruity floral black currant plum rose honey tobacco
Odor Typefruity
JECFA Number384
LogP4.40
EPA Substance Registry System2-Buten-1-one, 1-(2,6,6-trimethyl-1-cyclohexen-1-yl)- (35044-68-9)
Safety Information
MSDS Information
Beta-Damascone Usage And Synthesis
Chemical PropertiesBeta-Damascone is a colorless to pale yellow liquid with a very powerful floral, complex fruity note, reminiscent of plum, rose, and blackcurrant. ??-Damascone is found as a volatile constituent of many natural materials, for example, in rose oils and extracts.
One synthetic route to the damascones starts with an appropriate cyclogeranic acid derivative (halide, ester, etc.). This is reacted with an allyl magnesium halide to give 2,6,6-trimethylcyclohexenyl diallyl carbinol, which on pyrolysis yields the desired l-(2,6,6-trimethylcyclohexenyl)-3-buten-l-one. Damascone is obtained by rearrangement of the double bond in the side chain.
The ??- and ??-damascones are used in perfume compositions, especially rose perfumes, and in flavor compositions, to which they impart naturalness and body.
OccurrenceIn Burley tobacco oil; in volatile fractions from leaves of Carphephorus corymbosus and C. paniculatus. Reported found in bilberry, butter, milk, caviar, chicken fat, cooked beef and mutton, cured pork, pork and beef fat, roasted filberts and peanuts, pecans, potato chips, soybean, coriander leaf and seed and kiwifruit.
PreparationVarious methods: recently from ionone izoxazoles, also from 7,8-dehydro-β-ionole.
Aroma threshold valuesDetection: 8.6 to 41 ppb
Taste threshold valuesTaste characteristics at 30 ppm: green, woody, minty with a herbal floral nuance.
Tag:Beta-Damascone(35044-68-9) Related Product Information
DAMASCONE