(7-hydroxy-5,6,7,8-tetrahydro-3H-pyrrolizin-1-yl)methyl 2-hydroxy-2-(1 -hydroxyethyl)-3-methyl-butanoate

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(7-hydroxy-5,6,7,8-tetrahydro-3H-pyrrolizin-1-yl)methyl 2-hydroxy-2-(1 -hydroxyethyl)-3-methyl-butanoate Basic information
Product Name:(7-hydroxy-5,6,7,8-tetrahydro-3H-pyrrolizin-1-yl)methyl 2-hydroxy-2-(1 -hydroxyethyl)-3-methyl-butanoate
Synonyms:(7-hydroxy-5,6,7,8-tetrahydro-3H-pyrrolizin-1-yl)methyl 2-hydroxy-2-(1 -hydroxyethyl)-3-methyl-butanoate;(2S,3R)-2,3-Dihydroxy-2-(1-methylethyl)butanoic acid [(1S)-2,3,5,7aβ-tetrahydro-1-hydroxy-1H-pyrrolizin-7-yl]methyl ester;Rinderine;Butanoic acid, 2,3-dihydroxy-2-(1-methylethyl)-, [(1S,7aR)-2,3,5,7a-tetrahydro-1-hydroxy-1H-pyrrolizin-7-yl]methyl ester, (2S,3R)-
CAS:6029-84-1
MF:C15H25NO5
MW:299.36
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Mol File:6029-84-1.mol
(7-hydroxy-5,6,7,8-tetrahydro-3H-pyrrolizin-1-yl)methyl 2-hydroxy-2-(1 -hydroxyethyl)-3-methyl-butanoate Structure
(7-hydroxy-5,6,7,8-tetrahydro-3H-pyrrolizin-1-yl)methyl 2-hydroxy-2-(1 -hydroxyethyl)-3-methyl-butanoate Chemical Properties
Melting point 100-1°C
Boiling point 463.3±45.0 °C(Predicted)
density 1.26±0.1 g/cm3(Predicted)
pka12.59±0.29(Predicted)
Safety Information
Hazardous Substances Data6029-84-1(Hazardous Substances Data)
MSDS Information
(7-hydroxy-5,6,7,8-tetrahydro-3H-pyrrolizin-1-yl)methyl 2-hydroxy-2-(1 -hydroxyethyl)-3-methyl-butanoate Usage And Synthesis
DescriptionAn alkaloid, also belonging to the pyrrolizidine group, this base has been found in Rindera baldshuanica Kusn. It forms colourless crystals from Me2CO and has [α]20D + 24.62° (EtOH). Three non-phenolic hydroxyl groups are present and the alkaloid forms well crystalline salts with mineral acids, e.g. the hydrochloride, m.p. 152-3°C; hydrobromide, m.p. 123-4°C and the hydriodide, m.p. 118- 9°e. The structure may be deduced from the hydrolysis products which are heliotridine and (+ )-trachelanthic acid.
UsesRinderine is a pyrrolizidine alkaloid which are a class of compounds used as defense mechanisms in several plant families. Rinderine may be used by other insects, sequestered from food in use for their own defense and may also be found in some medicinal herb preparations.
DefinitionChEBI: Rinderine is a member of pyrrolizines.
ReferencesAkramov, Kiyamitdinova, Yunusov., Uzbek. Khirn. Zh., No.6, 36 (1961)
(7-hydroxy-5,6,7,8-tetrahydro-3H-pyrrolizin-1-yl)methyl 2-hydroxy-2-(1 -hydroxyethyl)-3-methyl-butanoate Preparation Products And Raw materials
Tag:(7-hydroxy-5,6,7,8-tetrahydro-3H-pyrrolizin-1-yl)methyl 2-hydroxy-2-(1 -hydroxyethyl)-3-methyl-butanoate(6029-84-1) Related Product Information
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