(5α,25α)-8,14-Didehydrocevane-3β,15β-diol

(5α,25α)-8,14-Didehydrocevane-3β,15β-diol Basic information
Product Name:(5α,25α)-8,14-Didehydrocevane-3β,15β-diol
Synonyms:Korseveridine;Cevane-3,15-diol, 8,14-didehydro-, (3β,5α,15β,25α)- (9CI)
CAS:20072-14-4
MF:C27H43NO2
MW:413.64
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Mol File:20072-14-4.mol
(5α,25α)-8,14-Didehydrocevane-3β,15β-diol Structure
(5α,25α)-8,14-Didehydrocevane-3β,15β-diol Chemical Properties
Melting point 291- 2°C
Safety Information
MSDS Information
(5α,25α)-8,14-Didehydrocevane-3β,15β-diol Usage And Synthesis
DescriptionThis steroidal alkaloid is present in the bulbs of Korolkowia sewerzowii. It forms a series of crystalline salts, e.g. the hydrochloride, m.p. 326°C; hydrobromide, m.p. 315°C; hydriodide, m.p. 306°C and the methiodide, m.p. 312°C. The 0,0- diacetate has m.p. 200-l oC. When treated with aluminium in phenol and Me2 CO at 100°C for 4 hours, the alkaloid yields korseveridinone, m.p. 123-4°C. The positions of all the functional groups have been ascertained by NMR and mass spectroscopy.
ReferencesNuriddinov, Yunusov., Khim. Prir. Soedin., 3, 398 (1967)
Nuriddinov, Yunusov., ibid, 4, 101 (1968)
(5α,25α)-8,14-Didehydrocevane-3β,15β-diol Preparation Products And Raw materials
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