1,6-Didehydro-3α-methoxy-15,16-[methylenebis(oxy)]-11a-homoerythrinan

1,6-Didehydro-3α-methoxy-15,16-[methylenebis(oxy)]-11a-homoerythrinan Basic information
Product Name:1,6-Didehydro-3α-methoxy-15,16-[methylenebis(oxy)]-11a-homoerythrinan
Synonyms:Schelhammericine;1,6-Didehydro-3α-methoxy-15,16-[methylenebis(oxy)]-11a-homoerythrinan;2H,4H-[1,3]Dioxolo[4,5-h]indolo[7a,1-a][2]benzazepine, 1,5,6,12,13,14-hexahydro-13-methoxy-, (11bS,13R)-
CAS:21030-78-4
MF:C19H23NO3
MW:313.39
EINECS:
Product Categories:
Mol File:21030-78-4.mol
1,6-Didehydro-3α-methoxy-15,16-[methylenebis(oxy)]-11a-homoerythrinan Structure
1,6-Didehydro-3α-methoxy-15,16-[methylenebis(oxy)]-11a-homoerythrinan Chemical Properties
Melting point 76-7°C
Safety Information
MSDS Information
1,6-Didehydro-3α-methoxy-15,16-[methylenebis(oxy)]-11a-homoerythrinan Usage And Synthesis
DescriptionThis alkaloid, isolated from Schelhammera pedunculata F. Muell, has the homoerythrina structure given above which is based upon chemical and spectroscopic evidence and comparison with the two following bases. It is dextrorotatory with [α]D + 122° (CHCI3). A methoxyl and a methylenedioxy group are present as su bstituents.
ReferencesJohns et al., Chem. Commun., 1102 (1968)
1,6-Didehydro-3α-methoxy-15,16-[methylenebis(oxy)]-11a-homoerythrinan Preparation Products And Raw materials
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