6-methyl-2-oxoperhydropyrimidin-4-ylurea

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Company Name: Hubei Xinyang Medical Technology Co., Ltd  
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Products Intro: Product Name:(6-Methyl-2-oxo-hexahydro-pyrimidin-4-yl)-urea
CAS:1129-42-6
Purity:99% HPLC Package:10mg;25mg;50mg;100mg
Company Name: Shaanxi DIDU pharmaceutical and Chemical Co., Ltd  
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Products Intro: Product Name:6-methyl-2-oxoperhydropyrimidin-4-ylurea
CAS:1129-42-6
Purity:99% Package:25KG
Company Name: HONEST JOY HOLDINGS LIMITED  
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6-methyl-2-oxoperhydropyrimidin-4-ylurea Basic information
Product Name:6-methyl-2-oxoperhydropyrimidin-4-ylurea
Synonyms:6-methyl-2-oxoperhydropyrimidin-4-ylurea;Crotonylidene diurea;Urea, (hexahydro-6-methyl-2-oxo-4-pyrimidinyl)-;(hexahydro-6-methyl-2-oxo-4-pyrimidinyl)-Urea;1-(6-Methyl-2-oxohexahydropyriMidin-4-yl)urea;(6-Methyl-2-oxo-hexahydro-pyrimidin-4-yl)-urea
CAS:1129-42-6
MF:C6H12N4O2
MW:172.19
EINECS:214-447-6
Product Categories:
Mol File:1129-42-6.mol
6-methyl-2-oxoperhydropyrimidin-4-ylurea Structure
6-methyl-2-oxoperhydropyrimidin-4-ylurea Chemical Properties
Melting point 250 °C (decomp)
Boiling point 454.3±45.0 °C(Predicted)
density 1.30±0.1 g/cm3(Predicted)
pka13.19±0.40(Predicted)
Water Solubility 5.065g/L at 20℃
LogP-1.34 at 20℃
EPA Substance Registry System(Hexahydro-6-methyl-2-oxo-4-pyrimidinyl)urea (1129-42-6)
Safety Information
MSDS Information
6-methyl-2-oxoperhydropyrimidin-4-ylurea Usage And Synthesis
Usessignificantly increases the activity of urease and dehydrogenase soil enzymes as well as yield and quality of banana on inceptisol.
Production Methods6-methyl-2-oxoperhydropyrimidin-4-ylurea, is obtained either by condensation of urea with crotonaldehyde in the presence of acid or by the more straightforward route involving condensation of urea with acetaldehyde in the molar ratio 1 : 1 in the presence of acid, which is used in industry. 2,7-Dioxo-4,5-dimethyldecahydropyrimido[4,5-d]pyrimidine is formed as a byproduct in the second route.
2-Oxo-4-ureido-6-methylhexahydropyrimidine is produced industrially by a continuous process employing a stirred tank cascade. A 70% urea solution is treated with acetaldehyde at a molar ratio of 1 : 1 in the presence of a catalytic amount of 75% sulfuric acid. The exothermic reaction is kept between 38 and 60 ℃ by controlled cooling. The pH is initially kept above 3 and in the final reactors below 2 by addition of sulfuric acid. Average residence time in the cascade is 40 min. In the last stirred tank, the reaction mixture is neutralized with aqueous potassium hydroxide solution. Drying is carried out in a spray tower.
Flammability and ExplosibilityNon flammable
Agricultural UsesCrotonylidene diurea (CDU) or crotonylidene urea is a fertilizer containing 28% nitrogen which is released slowly. CDU is made by reacting crotonaldehyde with urea in a 1:2 ratio.
6-methyl-2-oxoperhydropyrimidin-4-ylurea Preparation Products And Raw materials
Raw materialsUrea-->Crotonaldehyde
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