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Ferrocene(102-54-5)

Ferrocene(102-54-5)
Product IdentificationBack to Contents
【Product Name】

Ferrocene
【Synonyms】

(RS)-3-Hydroxytetrahydrofuran
3-Hydroxyoxolane
3-Hydroxytetrahydrofuran
bis(Cyclopentadienyl)iron
Ferrocene
Iron dicyclopentadienyl
Oxolan-3-ol
【CAS】

102-54-5
【CAS】

453-20-3
【Formula】

C10H10Fe
【Formula】

C4H8O2
【Molecular Weight】

186.04
【Molecular Weight】

88.1
【EINECS】

203-039-3
【EINECS】

207-219-2
【RTECS】

LK0700000
【RTECS】

LU3450050
【RTECS Class】

Tumorigen; Organometallic; Mutagen
【RTECS Class】

Drug
【Merck】

13,4070
【Beilstein/Gmelin】

102545
【Beilstein/Gmelin】

3385 (G)
【Beilstein Reference】

5-17-03-00010
【EC Class】

harmful, dangerous for the environment
Physical and Chemical PropertiesBack to Contents
【Appearance】

Clear light yellow.
【Appearance】

Orange crystalline solid with a camphor-like odor.
【Solubility in water】

Very soluble
【Solubility in water】

Insoluble
【Boiling Point】

170 - 173
【Boiling Point】

181
【Vapor Pressure】

0.03 (25 C)
【Density】

1.107 g/cm3 (0 C)
【Density】

1.490 g/cm3 (20 C)
【Usage】

Antiknock additive for gasoline, catalyst.
【Refractive Index】

1.4465 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Store in a cool, dry place. Keep container closed when not in use.
【Storage】

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
【Handling】

Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Hazards IdentificationBack to Contents
【Inhalation】

The toxicological properties of this substance have not been fully investigated. Inhalation of dust may cause respiratory tract irritation.
【Skin】

No information regarding skin irritation and other potential effects was found.
【Eyes】

No information regarding eye irritation and other potential effects was found.
【Ingestion】

May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May cause blood abnormalities and hepatic cirrhosis.
【EC Risk Phrase】

R 22 51/53
【EC Safety Phrase】

S 22 36/37 61
【UN (DOT)】

3077
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Personal Protection】

Eyes: Wear chemical goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.
【Exposure Effects】

Blood pressure may be decreased following an iron overdose. Lethargy, restlessness or confusion may be seen early in the poisoning. Convulsions and coma may occur in later phases. Case reports of pregnant women who have received early aggressive treatment (decontamination and/or deferoxamine) have described good fetal outcomes.
【Exposure Effects】

The toxicological properties of this material have not been investigated.
【Exposure limit(s)】

NIOSH REL: TWA 10 mg/m3 (total) TWA 5 mg/m3 (resp) OSHA PEL: TWA 15 mg/m3 (total) TWA 5 mg/m3 (resp)
Fire Fighting MeasuresBack to Contents
【Flash Point】

81
【Autoignition】

> 150
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire.
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.
【Fire Potential】

This material is probably combustible.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Clean up spills immediately, using the appropriate protective equipment.
【Small spills/leaks】

Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.
Stability and ReactivityBack to Contents
【Disposal Code】

15
【Stability】

Stable under normal temperatures and pressures.
【Incompatibilities】

Strong oxidizing agents, ammonium perchlorate, tetranitromethane, mercury (III) nitrate
【Decomposition】

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
【Decomposition】

Irritating and toxic fumes and gases.
Transport InformationBack to Contents
【UN Number】

3077
【HS Code】

2931 00 95
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