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Aniline hydrochloride(142-04-1)

Aniline hydrochloride(142-04-1)
Product IdentificationBack to Contents
【Product Name】

Aniline hydrochloride
【Synonyms】

Anilinium chloride
Benzeamine hydrochloride
【CAS】

142-04-1
【Formula】

C6H8ClN
【Molecular Weight】

129.59
【EINECS】

205-519-8
【RTECS】

CY0875000
【RTECS Class】

Tumorigen; Mutagen; Reproductive Effector; Primary Irritant
【Merck】

13,616
【Beilstein/Gmelin】

3593823
【Beilstein Reference】

4-12-00-00223
【EC Index Number】

612-009-00-2
【EC Class】

carcinogenic, toxic, dangerous for the environment
Physical and Chemical PropertiesBack to Contents
【Appearance】

A white to greenish colored crystalline solid.
【Solubility in water】

Soluble
【Melting Point】

198
【Boiling Point】

245
【Density】

1.2215 g/cm3 (20 C)
【Usage】

Used to make dyes and printing ink.
【Vapor Density】

1.222
First Aid MeasuresBack to Contents
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Skin】

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Store in a cool, dry place. Do not store in direct sunlight. Store in a tightly closed container.
【Handling】

Wash thoroughly after handling. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Use only in a chemical fume hood.
Hazards IdentificationBack to Contents
【Inhalation】

Harmful if inhaled. Causes respiratory tract irritation. May cause anoxia, characterized by weakness, headache, dizziness, confusion, cyanosis, weak and irregular heart beat, collapse, unconsciousness, convulsions, coma and death.
【Skin】

Causes skin irritation. Harmful if absorbed through the skin. Causes symptoms similar to those of inhalation.
【Eyes】

Causes eye irritation.
【Ingestion】

Harmful if swallowed. May cause irritation of the digestive tract. May cause effects similar to those for inhalation exposure.
【Hazards】

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. May polymerize explosively when heated or involved in a fire. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.
【EC Risk Phrase】

R 20/21/22 40 48/23/24/25 50
【EC Safety Phrase】

S 28 36/37 45
【UN (DOT)】

1548
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

May cause methemoglobinemia, which is characterized by chocolate-brown colored blood, headache, weakness, dizziness, breath shortness, cyanosis, rapid heart rate, unconsciousness and possible death. May cause cancer according to animal studies.
【Exposure limit(s)】

2 ppm TWA ACGIH
【Poison Class】

1*
Fire Fighting MeasuresBack to Contents
【Flash Point】

193
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
【Fire Potential】

May burn but does not ignite readily.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Wash area with soap and water. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation.
Stability and ReactivityBack to Contents
【Disposal Code】

9
【Stability】

Stable under normal temperatures and pressures.
【Incompatibilities】

Strong oxidizing agents.
【Decomposition】

Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1548
【Hazard Class】

6.1
【Packing Group】

III
【HS Code】

2921 41 00
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