ChemicalBook >>Dimethyl malonate>>Methyl malonate(108-59-8)

Methyl malonate(108-59-8)

Methyl malonate(108-59-8)
Product IdentificationBack to Contents
【Product Name】

Methyl malonate
【Synonyms】

Dimethyl 1,3-propanedioate
Dimethyl propanedioate
Malonic acid, dimethyl ester
Methyl malonate
Propanedioic acid, dimethyl ester
【CAS】

108-59-8
【Formula】

C5H8O4
【Molecular Weight】

132.12
【EINECS】

203-597-8
【RTECS】

OO0950000
【RTECS Class】

Primary Irritant
【Merck】

12,6169
【Beilstein/Gmelin】

774261
【Beilstein Reference】

4-02-00-01880
Physical and Chemical PropertiesBack to Contents
【Appearance】

Clear, colorless liquid.
【Solubility in water】

Very soluble
【Melting Point】

-62
【Boiling Point】

181
【Vapor Pressure】

45 (101 C)
【Density】

1.1722 g/cm3 (0 C)
【pKa/pKb】

11.79 (pKa)
【Heat Of Vaporization】

61.88 kJ/mol
【Heat Of Combustion】

-2313 kJ/mol
【Usage】

A common reagent for organic synthesis.
【Refractive Index】

1.4149 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Remove from exposure to fresh air immediately.
【Skin】

Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.
Handling and StorageBack to Contents
【Storage】

Store in a cool, dry place. Keep container closed when not in use.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear safety glasses and chemical goggles if splashing is possible. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】

Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.
【Exposure Effects】

The toxicological properties of this material have not been investigated.
【Poison Class】

4
Fire Fighting MeasuresBack to Contents
【Flash Point】

90
【Autoignition】

440
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire.
【Upper exp. limit】

17.4
【Lower exp. limit】

1.3
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment.
Stability and ReactivityBack to Contents
【Disposal Code】

1
【Incompatibilities】

Acids - bases - oxidizing agents - reducing agents.
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Transport InformationBack to Contents
【HS Code】

2917 19 10
Hazards IdentificationBack to Contents
【EC Safety Phrase】

S 23 24/25
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