ChemicalBook >>Acrylamide>>Ethylenecarboxamide(79-06-1)

Ethylenecarboxamide(79-06-1)

Ethylenecarboxamide(79-06-1)
Product IdentificationBack to Contents
【Product Name】

Ethylenecarboxamide
【Synonyms】

1-Diethylphosphorylethane
2-Propenamide
AAM
Acrylic acid amide
【CAS】

597-50-2
【CAS】

79-06-1
【Formula】

C3H5NO
【Formula】

C6H15OP
【Molecular Weight】

71.08
【Molecular Weight】

134.18
【EINECS】

201-173-7
【RTECS】

AS3325000
【RTECS】

SZ1640000
【RTECS Class】

Tumorigen; Mutagen; Reproductive Effector; Primary Irritant
【Merck】

13,131
【Beilstein/Gmelin】

1741571
【Beilstein/Gmelin】

605349
【Beilstein Reference】

4-02-00-01471
【Beilstein Reference】

4-04-00-03463
【EC Index Number】

616-003-00-0
【EC Class】

Carcinogenic Category 2; Mutagenic Category 2; Toxic for reproduction Category 3; Toxic; Harmful; Irritant; Sensitising
Physical and Chemical PropertiesBack to Contents
【Appearance】

Crystalline solid.
【Appearance】

White, odorless, crystalline solid.
【Solubility in water】

2150 g/L
【Solubility in water】

166 g/L (25 C)
【Melting Point】

48 - 52
【Melting Point】

84
【Boiling Point】

232
【Boiling Point】

243
【Vapor Pressure】

0.007 (25 C)
【Vapor Pressure】

0.05 (25 C)
【Density】

0.88 g/cm3 (20 C)
【Density】

1.122 g/cm3 (20 C)
【Partition Coefficient】

-.17
【Partition Coefficient】

-.67
【Heat Of Vaporization】

46.06 kJ/mol
【Heat Of Vaporization】

46.8 kJ/mol
【Usage】

Used for sewage and waste treatment, to make dyes, adhesives.
【Saturation Concentration】

Approximately 9 ppm at 25 C (calculated)
【Vapor Density】

2.45
First Aid MeasuresBack to Contents
【Ingestion】

If swallowed, wash out mouth with water provided person is conscious. Call a physician.
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Inhalation】

If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.
【Inhalation】

Material may be irritating to mucous membranes and upper respiratory tract. May be harmful if inhaled.
【Skin】

May cause skin irritation. May be harmful if absorbed through the skin.
【Skin】

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Skin】

In case of contact, immediately wash skin with soap and copious amounts of water. Remove contaminated clothing and shoes. Call a physician.
【Eyes】

May cause eye irritation.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
【Eyes】

In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. Call a physician.
Handling and StorageBack to Contents
【Storage】

Keep away from heat, sparks, and flame. Do not store in direct sunlight. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from acids. Do not store near alkaline substances. Keep away from polymerization catalysts.
【Storage】

Keep container tightly closed. Store under inert gas.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid contact with heat, sparks and flame. Do not ingest or inhale. Use with adequate ventilation.
Hazards IdentificationBack to Contents
【Ingestion】

May be harmful if swallowed.
【Inhalation】

May cause drowsiness, tingling sensations, fatigue, weakness, stumbling, slurred speech, and shaking. May cause central and peripheral nervous system damage. Severe intoxications may cause permanent nerve damage. Causes irritation to the respiratory tract. May affect reproductive system and act as a teratogen.
【Skin】

May be absorbed through the skin in harmful amounts. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. If absorbed, causes symptoms similar to those of ingestion.
【Eyes】

May cause eye irritation and possible burns.
【Ingestion】

Harmful if swallowed. Can cause nervous system damage. May cause central, peripheral, and autonomic nervous system effects. Central nervous system effects, which appear to predominate in acute cases, are characterized by abnormal fatigue, memory difficulties, and dizziness. Peripheral neuropathy symptoms, which are more common with repeated low-dose exposure or following a latency period of up to several weeks after acute exposure can include: muscular weakness, paresthesia, numbness in hands, feet, lower legs, and lower arms, unsteadiness, and difficulties in walking and standing. Autonomic nervous system involvement is indicated by excessive sweating, peripheral vasodilation and difficulties in micturation and defecation.
【Hazards】

Emits toxic fumes under fire conditions.
【Hazards】

Pure acrylamide will decompose at 347-572F giving ammonia, hydrogen and carbon monoxide. Avoid strong oxidizers. Avoid heat, ultraviolet light. Hazardous polymerization may occur. It readily polymerizes when heated to the melting point or when exposed to ultraviolet light. It is known to polymerize with violence when heated.
【EC Risk Phrase】

R 45 46 20/21 36/38 43 48/23/24/25 62
【EC Safety Phrase】

S 53 45
【UN (DOT)】

2074
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Compatible chemical-resistant gloves. Chemical safety goggles. Protective clothing.
【Personal Protection】

Skin: Rubber or neoprene gloves and additional protection including impervious boots, apron, or coveralls, as needed in areas of unusual exposure. Eyes: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
【Respirators】

Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Respiratory protection is not required. Where protection from nuisance levels of dusts are desired, use type N95 (US) or type P1 (EN 143) dust masks.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

rolonged or repeated exposure through any route may cause muscular weakness, incoordination, skin rashes, excessive sweating of hands and feet, cold hands, peeling of the skin, numbness, abnormal skin or muscle sensations, fatigue, and cause central and peripheral nervous system damage. Suspect cancer hazard. May cause cancer. May affect the reproductive system and act as a teratogen.
【Exposure limit(s)】

OSHA PEL: TWA 0.3 mg/m3 skin NIOSH REL: Ca TWA 0.03 mg/m3 skin See Appendix A NIOSH IDLH: Potential occupational carcinogen 60 mg/m3
【Poison Class】

2
Fire Fighting MeasuresBack to Contents
【Flash Point】

122
【Flash Point】

56
【Autoignition】

240
【Fire Fighting】

Extinguish with water spray, carbon dioxide, dry chemical powder or appropriate foam. Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
【Fire Fighting】

Fight fire from maximum distance. Dike fire control water for later disposal; do not scatter the material.For small fires, use dry chemical, carbon dioxide, water spray or foam. For large fires use water spray, fog or foam. Move container from fire area if you can do so without risk.
【Upper exp. limit】

20.6
【Lower exp. limit】

2.7
【Fire Potential】

May polymerize on melting.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Sweep up, place in a bag and hold for waste disposal. Avoid raising dust. Ventilate area and wash spill site after material pickup is complete.
【Small spills/leaks】

Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation.
Stability and ReactivityBack to Contents
【Stability】

May polymerize explosively. Thermally unstable. Polymerization may be caused by exposure to heat, U.V. light, oxidizers, or peroxides. May be stabilized with hydroquinone, t-butylpyrocatechol, N-phenyl-2-naphthylamine, or other antioxidants.
【Stability】

Stable if stored as directed.
【Incompatibilities】

Strong oxidizing agents.
【Incompatibilities】

Acids, oxidizing agents, and bases. Spontaneously reacts with hydroxyl-, amino-, and sulfhydryl- containing compounds.
【Decomposition】

Carbon monoxide, oxides of nitrogen, carbon dioxide, hydrogen gas, ammonia.
【Decomposition】

hermal decomposition may produce toxic fumes of phosphorus oxides and/or phosphine Carbon monoxide, Carbon dioxide.
【Combustion Products】

Toxic oxides of nitrogen are produced during combustion.
Transport InformationBack to Contents
【UN Number】

2074
【Hazard Class】

6.1
【Packing Group】

III
【HS Code】

2924 19 00
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