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2-Octanone(111-13-7)

2-Octanone(111-13-7)
Product IdentificationBack to Contents
【Product Name】

2-Octanone
【Synonyms】

Benzenamine, 4-[(4-aminophenyl)(4-imino-2,5-cyclohexadien-1-ylidene)methyl]-, monoacetate
bis(p-Aminophenyl)-4-methylenecyclohexa-2,5-dienylideneammonium acetate
C.I. 42500
Hexyl nethyl ketone
Methyl hexyl ketone
Octan-2-one
【CAS】

6035-94-5
【CAS】

111-13-7
【Formula】

C21H21N3O2
【Formula】

C8H16O
【Molecular Weight】

128.22
【Molecular Weight】

347.41
【EINECS】

203-837-1
【EINECS】

227-918-6
【RTECS】

RH1484000
【RTECS Class】

Drug; Reproductive Effector; Primary Irritant
【Merck】

13,4731
【Beilstein/Gmelin】

3641123
【Beilstein/Gmelin】

635843
【Beilstein Reference】

4-01-00-03339
Physical and Chemical PropertiesBack to Contents
【Appearance】

Colorless liquid. Fatty, green, cheese aroma.
【Appearance】

Green powder.
【Solubility in water】

Slightly soluble
【Melting Point】

-16
【Melting Point】

205
【Boiling Point】

173
【Vapor Pressure】

1.7 (25 C)
【Density】

0.8171 g/cm3 (20 C)
【Partition Coefficient】

2.37
【Heat Of Vaporization】

39.3 kJ/mol
【Heat Of Combustion】

-5073 kJ/mol
【Usage】

Biological stain.
【Usage】

In perfumes, high-boiling solvent, esp for epoxy resin coatings, in leather finishes, flavoring, odorant, antiblushing agent for nitrocellulose lacquers.
【Vapor Density】

4.4
【Odor threshold】

248 ppm
【Refractive Index】

1.4153 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid if irritation or symptoms occur.
【Ingestion】

May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Methemoglobinemia is characterized by dizziness, drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown colored blood.
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
【Inhalation】

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Methemoglobinemia is characterized by dizziness, drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown blood. Inhalation of aniline causes anoxia due to the formation of methemoglobinemia.
【Skin】

May cause skin irritation. The toxicological properties of this material have not been fully investigated.
【Skin】

Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

May cause eye irritation. The toxicological properties of this material have not been fully investigated.
【Eyes】

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
【Eyes】

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. If irritation develops, get medical aid.
Handling and StorageBack to Contents
【Storage】

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Storage】

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Use with adequate ventilation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Hazards IdentificationBack to Contents
【Inhalation】

May cause respiratory tract irritation.
【Skin】

Causes skin irritation. May be harmful if absorbed through the skin.
【Eyes】

May cause eye irritation.
【Ingestion】

May cause digestive tract disturbances.
【Hazards】

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.
【EC Risk Phrase】

R 21
【EC Safety Phrase】

S 36/37
【UN (DOT)】

1224
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

May cause methemoglobinemia, which is characterized by chocolate-brown colored blood, headache, weakness, dizziness, breath shortness, cyanosis, rapid heart rate, unconsciousness and possible death. May cause cancer according to animal studies.
【Exposure Effects】

Reproductive effects have been reported in animals.
【Poison Class】

4
Fire Fighting MeasuresBack to Contents
【Flash Point】

56
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. Combustible Liquid. Extinguishing media: Water may be ineffective. In case of fire use water spray, dry chemical, carbon dioxide, or chemical foam. Cool containers with flooding quantities of water until well after fire is out.
【Upper exp. limit】

6.1
【Lower exp. limit】

1
【Fire Potential】

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Provide ventilation.
【Small spills/leaks】

Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.
Stability and ReactivityBack to Contents
【Disposal Code】

1
【Incompatibilities】

Oxidizing agents
【Incompatibilities】

Oxidizing agents.
【Stability】

Stable under normal temperatures and pressures.
【Decomposition】

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
【Decomposition】

Carbon monoxide, oxides of nitrogen, irritating and toxic fumes and gases, carbon dioxide.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1224
【Hazard Class】

3
【Packing Group】

I; II; III
【HS Code】

2914 19 90
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