| Product Identification | Back to Contents | 【Product Name】
o-phenylaniline | 【Synonyms】
(1,1'-Biphenyl)-2-amine
2-Aminobiphenyl
2-Aminodiphenyl
o-Aminobiphenyl
o-Aminodiphenyl
o-Biphenylamine | 【CAS】
90-41-5 | 【Formula】
C12H11N | 【Molecular Weight】
169.23 | 【EINECS】
201-990-9 | 【RTECS】
DU8850000 | 【RTECS Class】
Mutagen | 【Beilstein/Gmelin】
471874 | 【Beilstein Reference】
4-12-00-03223 | 【EC Index Number】
612-142-00-6 | 【EC Class】
Carcinogenic Category 3; Harmful; Dangerous for the Environment |
| Physical and Chemical Properties | Back to Contents | 【Appearance】
Colorless or purplish crystals. | 【Solubility in water】
Insoluble | 【Melting Point】
42 - 44 | 【Boiling Point】
299 | 【Vapor Pressure】
0.001 (25 C) | 【pKa/pKb】
3.82(at 22℃) (pKa) | 【Partition Coefficient】
2.68 | 【Heat Of Vaporization】
53.9 kJ/mol | 【Heat Of Combustion】
-6388 kJ/mol | 【Usage】
Chemical intermediate for carbazole, resins, & synthetic rubbers. | 【Vapor Density】
5.8 |
| First Aid Measures | Back to Contents | 【Ingestion】
DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. | 【Inhalation】
IMMEDIATELY leave the contaminated area; take deep breaths of fresh air. IMMEDIATELY call a physician and be prepared to transport the victim to a hospital even if no symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be used. | 【Skin】
IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. IMMEDIATELY call a hospital or poison control center even if no symptoms (such as redness or irritation) develop. IMMEDIATELY transport the victim to a hospital for treatment after washing the affected areas. | 【Eyes】
First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. |
| Handling and Storage | Back to Contents | 【Storage】
Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage. | 【Handling】
All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood. |
| Hazards Identification | Back to Contents | 【Inhalation】
Dyspnea and tachypnea may occur. | 【Skin】
Central cyanosis unresponsive to oxygen therapy is classic. | 【Eyes】
See Inhalation. | 【Ingestion】
Nausea and vomiting may occur. | 【Hazards】
Contact with metals may evolve flammable hydrogen gas. | 【EC Risk Phrase】
R 22 40 52/53 | 【EC Safety Phrase】
S 36/37 61 | 【UN (DOT)】
3259 |
| Exposure Controls/Personal Protection | Back to Contents | 【Personal Protection】
If Tyvek-type disposable protective clothing is not worn during handling of this chemical, wear disposable Tyvek-type sleeves taped to your gloves. | 【Respirators】
Wear a NIOSH-approved half face respirator equipped with a combination filter cartridge, i.e. organic vapor/acid gas/HEPA (specific for organic vapors, HCl, acid gas, SO2 and a high efficiency particulate filter). | 【Exposure Effects】
CNS effects include headache, dizziness, altered mental status, confusion (lethargy progressing coma), seizures, syncope; occur secondary to CNS hypoxia, usually with levels > 20%. | 【Poison Class】
4 |
| Fire Fighting Measures | Back to Contents | 【Flash Point】
150 | 【Autoignition】
461 | 【Fire Fighting】
Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. | 【Fire Potential】
This chemical is probably combustible. |
| Accidental Release Measures | Back to Contents | 【Small spills/leaks】
Should a spill occur while you are handling this chemical, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with 60-70% ethanol and transfer the dampened material to a suitable container. Use absorbent paper dampened with 60-70% ethanol to pick up any remaining material. Seal the absorbent paper, and any of your clothes, which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. |
| Stability and Reactivity | Back to Contents | 【Disposal Code】
3 | 【Incompatibilities】
Incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides Flammable gaseous hydrogen is generated in combination with strong reducing agents, such as hydrides.. | 【Stability】
No data. | 【Combustion Products】
Fire may produce irritating, corrosive and/or toxic gases. |
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| Company Name: |
Alfa Aesar |
| Tel: |
400-6106006 |
| Fax: |
021-67582001/03/05 |
| WebSite: |
http://chemicals.thermofisher.cn |
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