| Product Identification | Back to Contents | 【Product Name】
4-Amino-3-hydroxynitrobenzene | 【Synonyms】
2-Hydroxy-4-nitroaniline
3-Hydroxy-4-aminonitrobenzene
5-Nitro-2-amino-1-hydroxybenzene
5-Nitro-2-aminophenol
C.I. 76535
Ursol Yellow Brown A | 【CAS】
121-88-0 | 【Formula】
C6H6N2O3 | 【Molecular Weight】
154.13999999999999 | 【EINECS】
204-503-8 | 【RTECS】
SJ6302500 | 【RTECS Class】
Tumorigen; Mutagen | 【Beilstein/Gmelin】
972974 | 【Beilstein Reference】
4-13-00-00903 |
| Physical and Chemical Properties | Back to Contents | 【Appearance】
Off-white solid. | 【Solubility in water】
Slightly soluble | 【Melting Point】
207 - 208 | 【Density】
1.54 g/cm3 | 【pKa/pKb】
8.08 (pKa) | 【Partition Coefficient】
.62 | 【Usage】
2-Amino-5-nitrophenol is used as an intermediate in the manufacture of several azo dyes, including ci solvent red 8, which is used for colouring synthetic resins, lacquers, inks and wood stains. It is also used as a dye in semi-permanent hair colouring products to produce red and gold-blond shades. It is used to a limited extent in permanent hair colouring products. |
| First Aid Measures | Back to Contents | 【Ingestion】
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. | 【Inhalation】
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. | 【Skin】
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. | 【Eyes】
Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. |
| Handling and Storage | Back to Contents | 【Storage】
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. | 【Handling】
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. |
| Hazards Identification | Back to Contents | 【Inhalation】
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. Methemoglobinemia is characterized by dizziness, drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown blood. Inhalation of aniline causes anoxia due to the formation of methemoglobinemia. | 【Skin】
May cause skin irritation. | 【Eyes】
May cause eye irritation. | 【Ingestion】
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. Methemoglobinemia is characterized by dizziness, drowsiness, headache, breath shortness, cyanosis with bluish skin, rapid heart rate and chocolate-brown colored blood. Overexposure may cause methemoglobinemia. |
| Exposure Controls/Personal Protection | Back to Contents | 【Personal Protection】
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. | 【Respirators】
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. | 【Exposure Effects】
May cause methemoglobinemia, which is characterized by chocolate-brown colored blood, headache, weakness, dizziness, breath shortness, cyanosis, rapid heart rate, unconsciousness and possible death. |
| Fire Fighting Measures | Back to Contents | 【Fire Fighting】
Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam. | 【Fire Potential】
This material is probably combustible. |
| Accidental Release Measures | Back to Contents | 【Small spills/leaks】
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation. |
| Stability and Reactivity | Back to Contents | 【Incompatibilities】
Oxidizing agents. | 【Stability】
Stable under normal temperatures and pressures. | 【Decomposition】
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide. |
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