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Lithium tetrafluoroborate(14283-07-9)

Lithium tetrafluoroborate(14283-07-9)
Product IdentificationBack to Contents
【Product Name】

Lithium tetrafluoroborate
【Synonyms】

Borate(1-), tetrafluoro-, lithium
Lithium boridefluoride
Lithium fluoborate
【CAS】

14283-07-9
【Formula】

BF4Li
【Molecular Weight】

93.74
【EINECS】

238-178-9
【Beilstein/Gmelin】

47154 (G)
【EC Class】

harmful, corrosive
Physical and Chemical PropertiesBack to Contents
【Appearance】

White/grey crystalline solid.
【Solubility in water】

Very soluble
【Density】

0.852 g/cm3
【Usage】

Used as an electrolyte in lithium batteries.
【Refractive Index】

1.3332
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Skin】

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and StorageBack to Contents
【Storage】

Store in a cool, dry place. Store in a tightly closed container. Corrosives area.
【Handling】

Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use and store under nitrogen. Use only in a chemical fume hood.
Hazards IdentificationBack to Contents
【Inhalation】

May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. May cause abdominal pain, nausea, vomiting, and inflammation of the gums and mouth.
【Skin】

May cause severe irritation and possible burns.
【Eyes】

Contact with eyes may cause severe irritation, and possible eye burns.
【Ingestion】

Harmful if swallowed. Causes gastrointestinal tract burns.
【Hazards】

Contact with metals may evolve flammable hydrogen gas.
【EC Risk Phrase】

R 22 34
【EC Safety Phrase】

S 26 36/37/39 45
【UN (DOT)】

3290
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear chemical goggles and face shield. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear a chemical apron.
【Respirators】

A NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149.
【Exposure Effects】

Overexposure may cause delayed kidney injury. Chronic ingestion may cause liver damage. May cause anemia and other blood cell abnormalities. May cause digestive tract and cardiac disturbances.
Fire Fighting MeasuresBack to Contents
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.
【Fire Potential】

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Vacuum or sweep up material and place into a suitable disposal container.
Stability and ReactivityBack to Contents
【Disposal Code】

23
【Stability】

Stable under normal shipping and handling conditions.
【Incompatibilities】

Strong acids
【Decomposition】

Carbon monoxide, carbon dioxide, hydrogen fluoride.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

3290
【Hazard Class】

6.1
【Packing Group】

I; II
【HS Code】

2826 90 90
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