ChemicalBook >>DBU>>1,8-Diazabicyclo[5.4.0]undec-7-ene(6674-22-2)

1,8-Diazabicyclo[5.4.0]undec-7-ene(6674-22-2)

1,8-Diazabicyclo[5.4.0]undec-7-ene(6674-22-2)
Product IdentificationBack to Contents
【Product Name】

1,8-Diazabicyclo[5.4.0]undec-7-ene
【Synonyms】

1,8-Diazabicyclo[5.4.0]undec-7-ene
1,8-Diazabicyclo[5.4.0]undecene-7
2,3,4,6,7,8,9,10-Octahydropyrimido[1,2-a]azepine
Polycat DBU
U-CAT SA 851
【CAS】

6674-22-2
【Formula】

C9H16N2
【Molecular Weight】

152.24
【EINECS】

229-713-7
【Beilstein/Gmelin】

508906
【Beilstein Reference】

5-23-05-00271
【EC Class】

harmful, corrosive, dangerous for the environment
Physical and Chemical PropertiesBack to Contents
【Appearance】

Clear very light yellow liquid.
【Solubility in water】

Very soluble
【Melting Point】

-70
【Boiling Point】

275
【Vapor Pressure】

0.15 (25 C)
【Density】

1.01 g/cm3
【pKa/pKb】

12.84 (pKa)
【Partition Coefficient】

2.06
【Heat Of Vaporization】

51.3 kJ/mol
【Refractive Index】

1.52 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Skin】

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Discard contaminated clothing in a manner which limits further exposure.
【Eyes】

Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
Handling and StorageBack to Contents
【Storage】

Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Corrosives area. Do not get water inside containers.
【Handling】

Wash thoroughly after handling. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Discard contaminated shoes.
Hazards IdentificationBack to Contents
【Ingestion】

May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns. May be harmful if swallowed.
【Inhalation】

Mist or vapor is extremely irritating.
【Skin】

Causes skin burns. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
【Eyes】

Causes eye burns. Lachrymator. Mist or vapor is extremely irritating.
【Hazards】

Contact with metals may evolve flammable hydrogen gas.
【EC Risk Phrase】

R 21/22 34 52/53
【EC Safety Phrase】

S 26 36/37/39 45 61
【UN (DOT)】

1760
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Fire Fighting MeasuresBack to Contents
【Flash Point】

116
【Autoignition】

260
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Containers may explode in the heat of a fire. Extinguishing media: For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. Cool containers with flooding quantities of water until well after fire is out.
【Upper exp. limit】

6.5
【Lower exp. limit】

1.1
【Fire Potential】

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation. Do not get water inside containers.
Stability and ReactivityBack to Contents
【Disposal Code】

1
【Stability】

Stable under normal temperatures and pressures.
【Incompatibilities】

Strong oxidizing agents, acids, acid chlorides, acid anhydrides, chloroformates.
【Decomposition】

Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport InformationBack to Contents
【UN Number】

1760
【Hazard Class】

8
【Packing Group】

I; II; III
【HS Code】

2933 99 30
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