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Trichloroacetyl chloride(76-02-8)

Trichloroacetyl chloride(76-02-8)
Product IdentificationBack to Contents
【Product Name】

Trichloroacetyl chloride
【Synonyms】

Acetyl chloride, trichloro-
Superpalite
Trichloroacetic acid chloride
Trichloroacetochloride
【CAS】

76-02-8
【Formula】

C2Cl4O
【Molecular Weight】

181.83
【EINECS】

200-926-7
【RTECS】

AO7140000
【RTECS Class】

Other
【Beilstein/Gmelin】

774120
【Beilstein Reference】

4-02-00-00519
【EC Class】

very toxic, corrosive
Physical and Chemical PropertiesBack to Contents
【Appearance】

A colorless volatile liquid with a strong odor.
【Solubility in water】

Decomposes
【Melting Point】

-57
【Boiling Point】

118
【Vapor Pressure】

1
【Density】

1.6564 g/cm3 (0 C)
【Partition Coefficient】

2.16
【Usage】

Trichloroacetyl chloride can be used for the manufacture of the esters and the anhydrides of trichloroacetic acid.
【Vapor Density】

6.3
【Refractive Index】

1.4667 (20 C)
First Aid MeasuresBack to Contents
【Ingestion】

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. DO NOT use mouth-to-mouth respiration.
【Skin】

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
【Eyes】

Get medical aid immediately. Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required (at least 30 minutes).
Handling and StorageBack to Contents
【Storage】

Store in a cool, dry place. Keep container closed when not in use. Corrosives area. Do not store in metal containers.
【Handling】

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Keep container tightly closed. Do not get on skin or in eyes. Avoid ingestion and inhalation. Do not ingest or inhale. Use with adequate ventilation. Discard contaminated shoes.
Hazards IdentificationBack to Contents
【Ingestion】

May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May be harmful if swallowed.
【Inhalation】

May be fatal if inhaled. Causes chemical burns to the respiratory tract.
【Skin】

Causes skin burns.
【Eyes】

Causes eye burns.
【Hazards】

Poisonous if inhaled or swallowed; skin contact poisonous. Contact may cause burns to skin and eyes.
【EC Risk Phrase】

R 22 26 35
【EC Safety Phrase】

S 26 28.1 36/37/39 45
【UN (DOT)】

2442
Exposure Controls/Personal ProtectionBack to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear a chemical apron. Wear appropriate protective clothing to minimize contact with skin.
【Respirators】

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.
【Poison Class】

1
Fire Fighting MeasuresBack to Contents
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Contact with metals may evolve flammable hydrogen gas. Containers may explode if exposed to fire. Extinguishing media: Do NOT use water directly on fire. Use dry chemical, carbon dioxide, or alcohol-resistant foam. If water is the only media available, use in flooding amounts. Do NOT get water inside containers. Cool containers with flooding quantities of water until well after fire is out.
【Fire Potential】

Material may burn but does not ignite readily.
Accidental Release MeasuresBack to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation. Do not get water inside containers.
Stability and ReactivityBack to Contents
【Disposal Code】

11
【Stability】

Stable under normal temperatures and pressures.
【Incompatibilities】

Strong oxidizing agents.
【Decomposition】

Hydrogen chloride, phosgene, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
【Combustion Products】

During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Transport InformationBack to Contents
【UN Number】

2442
【Hazard Class】

8
【Packing Group】

II
【HS Code】

2915 90 80
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