Chemical Safety Data Sheet MSDS / SDS

Butyl glycidyl ether

Revision Date:2024-04-27Revision Number:1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

Product identifier

Product name: Butyl glycidyl ether
CBnumber: CB2728089
CAS: 2426-08-6
EINECS Number: 219-376-4
Synonyms: BGE,Butyl glycidyl ether

Relevant identified uses of the substance or mixture and uses advised against

Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
Uses advised against: none

Company Identification

Company: Chemicalbook
Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
Telephone: 400-158-6606

SECTION 2: Hazards identification

GHS Label elements, including precautionary statements

Symbol(GHS)

Signal wordDanger

Precautionary statements

P405 Store locked up.

P310 Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P273 Avoid release to the environment.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P201 Obtain special instructions before use.

Hazard statements

H412 Harmful to aquatic life with long lasting effects

H402 Harmful to aquatic life

H351 Suspected of causing cancer

H350 May cause cancer

H341 Suspected of causing genetic defects

H335 May cause respiratory irritation

H332 Harmful if inhaled

H331 Toxic if inhaled

H317 May cause an allergic skin reaction

H314 Causes severe skin burns and eye damage

H302 Harmful if swallowed

H226 Flammable liquid and vapour

SECTION 3: Composition/information on ingredients

Substance

Product name: Butyl glycidyl ether
Synonyms: BGE,Butyl glycidyl ether
CAS: 2426-08-6
EC number: 219-376-4
MF: C7H14O2
MW: 130.18

SECTION 4: First aid measures

Description of first aid measures

General advice

First aiders need to protect themselves. Show this material safety data sheet to the doctor

If inhaled

After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.

In case of skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.

In case of eye contact

After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.

If swallowed

After swallowing: make victim drink water (two glasses at most), avoid vomiting (risk of perforation). Call a physician immediately. Do not attempt to neutralise.

Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5: Firefighting measures

Extinguishing media

Suitable extinguishing media

Foam Carbon dioxide (CO2) Dry powder

Unsuitable extinguishing media

For this substance/mixture no limitations of extinguishing agents are given.

Special hazards arising from the substance or mixture

Carbon oxides Hydrogen chloride gas Combustible.

Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air at elevated temperatures.

Development of hazardous combustion gases or vapours possible in the event of fire.

Advice for firefighters

Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.

Further information

Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.

NFPA 704

HEALTH	2	Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury (e.g. diethyl ether, ammonium phosphate, iodine)
FIRE	2	Must be moderately heated or exposed to relatively high ambient temperature before ignition can occur and multiple finely divided suspended solids that do not require heating before ignition can occur. Flash point between 37.8 and 93.3 °C (100 and 200 °F). (e.g. diesel fuel, sulfur)
REACT	0	Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2)
SPEC. HAZ.

SECTION 6: Accidental release measures

Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition.

Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8.

Environmental precautions

Do not let product enter drains. Risk of explosion.

Methods and materials for containment and cleaning up

Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g.

Chemizorb?). Dispose of properly. Clean up affected area.

Reference to other sections

For disposal see section 13.

SECTION 7: Handling and storage

Precautions for safe handling

Advice on safe handling

Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.

Advice on protection against fire and explosion

Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge.

Hygiene measures

Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.

For precautions see section 2.2.

Conditions for safe storage, including any incompatibilities

Storage conditions

Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and

sources of ignition. Keep locked up or in an area accessible only to qualified or authorized persons.

Air, light, and moisture sensitive.

Storage class

Storage class (TRGS 510): 3: Flammable liquids

Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection

control parameter

Hazard composition and occupational exposure limits

Does not contain substances with occupational exposure limits.

Exposure controls

Personal protective equipment

Eye/face protection

Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.

Splash contact Material: butyl-rubber

Minimum layer thickness: 0,3 mm Break through time: 60 min

Material tested:Butoject? (KCL 897 / Aldrich Z677647, Size M)

data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374

If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the EC approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

Body Protection

Flame retardant antistatic protective clothing.

Respiratory protection

required when vapours/aerosols are generated.

Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system.

Recommended Filter type: Filter type ABEK

The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer.

These measures have to be properly documented.

Control of environmental exposure

Do not let product enter drains. Risk of explosion.

SECTION 9: Physical and chemical properties

Information on basic physicochemical properties

Appearancecolorless clear, liquid
OdourNo data available
Odour ThresholdNo data available
pHNo data available
Melting point/freezing point59 °C
Initial boiling point and boiling range 164 - 166 °C - lit.
Flash point54 °C - closed cup
Evaporation rateNo data available
Flammability (solid, gas)No data available
Upper/lower flammability or explosive limitsNo data available
Vapour pressure 3,99 hPa at 20 °C
Vapour density No data available
Relative density0,91 g/mL at 25 °C - lit. No data available
Water solubility20g/l
Partition coefficient: n-octanol/waterNo data available
Autoignition temperatureNo data available
Decomposition temperatureNo data available
ViscosityViscosity, kinematic: No data available Viscosity, dynamic: No data available
Explosive propertiesNo data available
Oxidizing propertiesnone

Other safety information

No data available

SECTION 10: Stability and reactivity

Reactivity

Vapor/air-mixtures are explosive at intense warming.

Chemical stability

The product is chemically stable under standard ambient conditions (room temperature) .

Possibility of hazardous reactions

No data available

Conditions to avoid

Heating.

Incompatible materials

Strong oxidizing agents

Hazardous decomposition products

In the event of fire: see section 5

SECTION 11: Toxicological information

Information on toxicological effects

Acute toxicity

Acute toxicity estimate Oral - 1.103 mg/kg
(Calculation method)
LD50 Oral - Mouse - male - 1.530 mg/kg (butyl 2,3-epoxypropyl ether) Remarks: (ECHA)
Acute toxicity estimate Inhalation - 4 h - 6,19 mg/l (Calculation method)
LC50 Inhalation - Rat - male - 4 h - 6,93 mg/l (butyl 2,3-epoxypropyl ether) Remarks: (ECHA)
Acute toxicity estimate Dermal - > 2.000 mg/kg (Calculation method)
LD50 Dermal - Rat - > 2.150 mg/kg (butyl 2,3-epoxypropyl ether) Remarks: (RTECS)

Skin corrosion/irritation

Skin - Rabbit (butyl 2,3-epoxypropyl ether) Result: Skin irritation - 24 h
Remarks: (RTECS)

Serious eye damage/eye irritation

Eyes - Rabbit (butyl 2,3-epoxypropyl ether) Result: Severe eye irritation - 24 h Remarks: (RTECS)

Respiratory or skin sensitization

May cause allergic skin reaction. Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) (butyl 2,3-epoxypropyl ether)

Germ cell mutagenicity

Suspected of causing genetic defects. (butyl 2,3-epoxypropyl ether Test Type: unscheduled DNA synthesis assay
(butyl 2,3-epoxypropyl ether) Test system: mammalian cells
Metabolic activation: without metabolic activation Result: negative
Remarks: (ECHA)
Test Type: Ames test
(butyl 2,3-epoxypropyl ether) Test system: S. typhimurium
Metabolic activation: with and without metabolic activation Result: negative
Remarks: (ECHA)
(butyl 2,3-epoxypropyl ether)
Test Type: Chromosome aberration test in vitro Species: Rat
Cell type: Bone marrow Application Route: Intraperitoneal
Result: positive Remarks: (ECHA)

Carcinogenicity

No data available

Reproductive toxicity

Suspected of damaging the unborn child. (butyl 2,3-epoxypropyl ether) No data available
Suspected of damaging fertility. (butyl 2,3-epoxypropyl ether)

Specific target organ toxicity - single exposure

Inhalation - May cause respiratory irritation. - Nasal inner lining (butyl 2,3-epoxypropyl ether)
Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)

Specific target organ toxicity - repeated exposure

No data available

Aspiration hazard

No data available

Toxicity

LD50 orally in Rabbit: 1660 mg/kg LD50 dermal Rabbit 2520 mg/kg

SECTION 12: Ecological information

Toxicity

Toxicity to fish

semi-static test LC50 - Oncorhynchus mykiss (rainbow trout) - 65 mg/l - 96 h (butyl 2,3-epoxypropyl ether)

Remarks: (ECHA)

Toxicity to daphnia and other aquatic invertebrates

static test EC50 - Daphnia magna (Water flea) - 9,2 mg/l - 48 h (butyl 2,3-epoxypropyl ether)

Remarks: (ECHA)

Toxicity to algae

static test ErC50 - Pseudokirchneriella subcapitata - 35 mg/l - 96 h (butyl 2,3-epoxypropyl ether)

Remarks: (ECHA)

Persistence and degradability

Biodegradability aerobic - Exposure time 28 d (butyl 2,3-epoxypropyl ether) Result: 25 % - Not readily biodegradable.

(OECD Test Guideline 301B)

Bioaccumulative potential

No data available

Mobility in soil

No data available

Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Other adverse effects

Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

SECTION 13: Disposal considerations

Waste treatment methods

Product

See www.retrologistik.com for processes regarding the return of chemicals and

containers, or contact us there if you have further questions.

Incompatibilities

May form explosive mixture with air. Air and light form unstable and explosive peroxides. Contact with strong oxidizers may cause fire and explosions. Contact with strong caustics may cause polymerization. Attacks some plastics and rubber

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

SECTION 14: Transport information

UN number

ADR/RID: 3271 IMDG: 3271 IATA: 3271

UN proper shipping name

14.3	ADR/RID: ETHERS, N.O.S. (butyl 2,3-epoxypropyl ether) IMDG: ETHERS, N.O.S. (butyl 2,3-epoxypropyl ether) IATA: Ethers, n.o.s. (butyl 2,3-epoxypropyl ether) Transport hazard class(es)
	ADR/RID: 3 IMDG: 3	IATA: 3
14.4	Packaging group ADR/RID: III IMDG: III	IATA: III
14.5	Environmental hazards ADR/RID: no IMDG Marine pollutant: no	IATA: no
14.6	Special precautions for user No data available

SECTION 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture

Regulations on the Safety Management of Hazardous Chemicals

China Catalog of Hazardous chemicals 2015:Not Listed. website: https://www.mem.gov.cn/

Measures for Environmental Management of New Chemical Substances

Vietnam National Chemical Inventory:Listed. website: https://chemicaldata.gov.vn/

United States Toxic Substances Control Act (TSCA) Inventory:Listed. website: https://www.epa.gov/

Philippines Inventory of Chemicals and Chemical Substances (PICCS):Listed. website: https://emb.gov.ph/

New Zealand Inventory of Chemicals (NZIoC):Listed. website: https://www.epa.govt.nz/

Korea Existing Chemicals List (KECL):Listed. website: http://ncis.nier.go.kr

European Inventory of Existing Commercial Chemical Substances (EINECS):Listed. website: https://echa.europa.eu/

EC Inventory:Listed.

Chinese Chemical Inventory of Existing Chemical Substances (China IECSC):Listed. website: https://www.mee.gov.cn/

SECTION 16: Other information

Abbreviations and acronyms

ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
CAS: Chemical Abstracts Service
EC50: Effective Concentration 50%
IATA: International Air Transportation Association
IMDG: International Maritime Dangerous Goods
LC50: Lethal Concentration 50%
LD50: Lethal Dose 50%
RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
STEL: Short term exposure limit
TWA: Time Weighted Average

References

【1】CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple

【2】ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp

【3】ECHA - European Chemicals Agency, website: https://echa.europa.eu/

【4】eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en

【5】ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg

【6】Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp

【7】HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm

【8】IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/

【9】IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home

【10】Sigma-Aldrich, website: https://www.sigmaaldrich.com/

Other Information

Explosive limits are unknown in literature, although the substance is combustible and has a flash point < 61°C.Check for peroxides prior to distillation; eliminate if found.

Disclaimer:

The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.