ChemicalBook CAS DataBase List METHYL (2R)-2-[(TERT-BUTOXYCARBONYL)AMINO]-3-(2,4,5-TRIFLUOROPHENYL)PROPANOATE

METHYL (2R)-2-[(TERT-BUTOXYCARBONYL)AMINO]-3-(2,4,5-TRIFLUOROPHENYL)PROPANOATE synthesis

8synthesis methods

Product Name:METHYL (2R)-2-[(TERT-BUTOXYCARBONYL)AMINO]-3-(2,4,5-TRIFLUOROPHENYL)PROPANOATE
CAS Number:486460-08-6
Molecular formula:C15H18F3NO4
Molecular Weight:333.3

2-Propenoic acid, 2-[[(1,1-dimethylethoxy)carbonyl]amino]-3-(2,4,5-trifluorophenyl)-, methyl ester, (2Z)-

1500076-05-0
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METHYL (2R)-2-[(TERT-BUTOXYCARBONYL)AMINO]-3-(2,4,5-TRIFLUOROPHENYL)PROPANOATE

486460-08-6
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Yield:486460-08-6 85%

Reaction Conditions:

with 1,2-bis[(2R,5R)-2,5-diethylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate;hydrogen in methanol; under 3750.38 Torr; for 18 h;Inert atmosphere;

References:

Zhu, Linrong;Li, Yuanyuan;Qiu, Ling;Su, Mingbo;Wang, Xin;Xia, Chunmei;Qu, Yi;Li, Jingya;Li, Jia;Xiong, Bing;Shen, Jingkang [ChemMedChem,2013,vol. 8,# 7,p. 1104 - 1116]

24424-99-5 Synthesis