| Identification | Back Directory | [Name]
(Z)-5-Chloro-3-trimethylstannyl-2-pentene | [CAS]
101849-67-6 | [Synonyms]
(Z)-5-Chloro-3-trimethylstannyl-2-pentene
Stannane, [(1Z)-1-(2-chloroethyl)-1-propen-1-yl]trimethyl- | [Molecular Formula]
C8H17ClSn | [MDL Number]
MFCD17015096 | [MOL File]
101849-67-6.mol | [Molecular Weight]
267.38 |
| Hazard Information | Back Directory | [Preparation]
By the addition of Lithium Phenylthio(trimethylstannyl)cuprate to ethyl 2-pentynoate,followed by stereospecific deconjugation (eq 1) to afford ethyl (Z)-3-trimethylstannyl-3-pentynoate as a single isomer. Reduction and conversion to the chloride provides the title reagent (Z)-5-Chloro-3-trimethylstannyl-2-pentene (eq 2).
 | [storage]
Organostannanes should be considered as toxic compounds. This reagent should be handled in a well-ventilated fume hood and gloves should be worn to prevent contact with the skin. |
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