| Identification | Back Directory | [Name]
(+)-CHLOROMETHYL MENTHYL ETHER | [CAS]
103128-76-3 | [Synonyms]
(+)-CHLOROMETHYL MENTHYL ETHER
(+)-Chloromethyl menthyl ether, 97% ee
(1R,2S,4S)-2-(CHLOROMETHYLOXY)-1-ISOPROPYL-4-METHYLCYCLOHEXANE | [Molecular Formula]
C11H21ClO | [MDL Number]
MFCD00216950 | [MOL File]
103128-76-3.mol | [Molecular Weight]
204.74 |
| Chemical Properties | Back Directory | [Appearance]
clear colorless liquid | [Boiling point ]
72 °C0.4 mm Hg(lit.)
| [density ]
0.994 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.467(lit.)
| [Fp ]
225 °F
| [storage temp. ]
-20°C | [form ]
liquid | [optical activity]
[α]24/D +181.0°, c = 2 in methylene chloride | [CAS DataBase Reference]
103128-76-3 |
| Hazard Information | Back Directory | [Chemical Properties]
clear colorless liquid | [Uses]
(+)-Chloromethyl menthyl ether can be used:
- As a starting material for the synthesis of 1-methyl-3-(+)-methylmenthoxide imidazolium chloride, a key intermediate for the preparation of Ag(I) N-heterocyclic carbene, applicable as a catalyst in the diboration of alkenes.
- As a substrate in the synthesis of commercially important O-substituted α-methoxymethylketones.
- To determine enantiomeric excess (ee) of an iron chiral auxiliary named [Fe(CO)(η;5- C2H5)(PPh3)COCH3].
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