| Identification | Back Directory | [Name]
Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride | [CAS]
1033772-47-2 | [Synonyms]
Nickamine
]amine nickeL
Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride
Bis[(2-diMethylaMino)phenyl]aMine nickel(II) chloride,98%
Bis[(2-dimethylamino)phenyl]aminenickel(II)chloride>=98.0%(AT)
Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride >=97% (AT)
(SP-4-3)-Chloro[N2-[2-(diMethylaMino-κN)phenyl]-N1,N1-diMethyl-1,2-benzenediaMinato-κN1,κN2]nickel | [Molecular Formula]
C16H20ClN3Ni | [MDL Number]
MFCD17015253 | [MOL File]
1033772-47-2.mol | [Molecular Weight]
348.5 |
| Chemical Properties | Back Directory | [storage temp. ]
2-8°C, protect from light, stored under nitrogen | [form ]
Solid | [Appearance]
Brown to black Solid | [InChI]
1S/C16H20N3.ClH.Ni/c1-18(2)15-11-7-5-9-13(15)17-14-10-6-8-12-16(14)19(3)4;;/h5-12H,1-4H3;1H;/q-1;;+2/p-1 | [InChIKey]
IRLHVNUEEKJBEL-UHFFFAOYSA-M | [SMILES]
CN(C)c1ccccc1N([Ni]Cl)c2ccccc2N(C)C |
| Hazard Information | Back Directory | [Uses]
Bis[(2-dimethylamino)phenyl]amine Nickel(II) Chloride is a new pincer-type bis(amido)amine (NN2) ligand. The Ni(II) alkyl complexes react cleanly with alkyl halides including chlorides to form C-C cou
pled products and Ni(II) halides. | [Uses]
Catalyst for:
- Alkyl-alkyl Kumada coupling of secondary alkyl halides
- Direct alkylation of heterocyclic C-H bonds
- Sonogashira coupling of nonactivated alkyl halides
- Kumada-Corriu-Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles
Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation | [reaction suitability]
core: nickel
reagent type: catalyst |
|
| Company Name: |
Sigma-Aldrich
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021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
Energy Chemical
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021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
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