| Identification | Back Directory | [Name]
Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride | [CAS]
1033772-47-2 | [Synonyms]
Nickamine
]amine nickeL
Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride
Bis[(2-diMethylaMino)phenyl]aMine nickel(II) chloride,98%
Bis[(2-dimethylamino)phenyl]aminenickel(II)chloride>=98.0%(AT)
Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride >=97% (AT)
(SP-4-3)-Chloro[N2-[2-(diMethylaMino-κN)phenyl]-N1,N1-diMethyl-1,2-benzenediaMinato-κN1,κN2]nickel | [Molecular Formula]
C16H20ClN3Ni | [MDL Number]
MFCD17015253 | [MOL File]
1033772-47-2.mol | [Molecular Weight]
348.5 |
| Hazard Information | Back Directory | [Uses]
Bis[(2-dimethylamino)phenyl]amine Nickel(II) Chloride is a new pincer-type bis(amido)amine (NN2) ligand. The Ni(II) alkyl complexes react cleanly with alkyl halides including chlorides to form C-C cou
pled products and Ni(II) halides. | [Uses]
Catalyst for:
- Alkyl-alkyl Kumada coupling of secondary alkyl halides
- Direct alkylation of heterocyclic C-H bonds
- Sonogashira coupling of nonactivated alkyl halides
- Kumada-Corriu-Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles
Reactant of pincer NN2 ligand leading to selective carbon-carbon bond formation | [reaction suitability]
core: nickel
reagent type: catalyst |
|
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Sigma-Aldrich
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Energy Chemical
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http://www.energy-chemical.com |
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