ChemicalBook--->CAS DataBase List--->104371-20-2

104371-20-2

104371-20-2 Structure

104371-20-2 Structure
IdentificationBack Directory
[Name]

S(-)-1-(PENTAFLUOROPHENYL)ETHANOL
[CAS]

104371-20-2
[Synonyms]

S(-)-1-(PENTAFLUOROPHENYL)ETHANOL
(1S)-1-(Pentafluorophenyl)ethanol
(1S)-1-(2,3,4,5,6-Pentafluorophenyl)ethanol
(αS)-α-Methyl-2,3,4,5,6-pentafluorobenzenemethanol
(s)-(-)-α-methyl-2,3,4,5,6-pentafluorobenzyl alcohol
S(-)-ALPHA-METHYL-2,3,4,5,6-PENTAFLUOROBENZYL ALCOHOL
Benzenemethanol, 2,3,4,5,6-pentafluoro-α-methyl-, (αS)-
(S)-(-)-1-(PENTAFLUOROPHENYL)ETHANOL, FL UKABRAND CHIRASELECT REAGENT, 99+%
[Molecular Formula]

C8H5F5O
[MDL Number]

MFCD00077840
[MOL File]

104371-20-2.mol
[Molecular Weight]

212.12
Chemical PropertiesBack Directory
[Melting point ]

41-42 °C(lit.)
[Fp ]

189 °F
[Optical Rotation]

[α]20/D 7.0±0.5°, c = 1% in pentane
[BRN ]

4314037
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36
[WGK Germany ]

3
[F ]

10
Spectrum DetailBack Directory
[Spectrum Detail]

S(-)-1-(PENTAFLUOROPHENYL)ETHANOL(104371-20-2)1HNMR
S(-)-1-(PENTAFLUOROPHENYL)ETHANOL(104371-20-2)19FNMR
Hazard InformationBack Directory
[Purification Methods]

Recrystallise the ethanol from n-pentane at -40o and sublime it at 25o/0.3mm (use ice-cooled cold finger). It has also been purified by column chromatography through Kieselgel 60 (0.063-0.2mm mesh, Merck) and eluted with EtOAc/n-hexane (1:5), then recrystallised from n-pentane and sublimed in a vacuum. It has RF on Kieselgel 60 F254 TLC foil and eluting with EtOAc/n-hexane (1:5). [Meese Justus Liebigs Ann Chem 2004 1986.]
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