ChemicalBook--->CAS DataBase List--->1060735-14-9

1060735-14-9

1060735-14-9 Structure

1060735-14-9 Structure
IdentificationBack Directory
[Name]

9-Phenyl-9H,9'H-[3,3']bicarbazolyl
[CAS]

1060735-14-9
[Synonyms]

H-[3,3'
]bicarbazolyl
-3,3'-bicarbazoL
9-Phenyl-9H,9'
9-phenyl-3,3'-bicarbazole
N-Phenyl-3,3'-bicarbazolyl
9-Phenyl-3,3'-bicarbazolyl
Phenyl-3,3'-Bi-9H-carbazole
3,3'-Bi-9H-carbazole, 9-phenyl-
9'-phenyl-9H,9H'-3,3'-carbazole
9-phenyl-9H,9'H-3,3'-bicarbazole
9-Phenyl-9H,9'H-[3,3']bicarbazolyl
3-(9-phenyl-carbazol-3-yl)-9H-carbazole
9-Phenyl-9H,9'H-[3,3']bicarbazolyl
3-(9-Phenyl-9H-carbazol-3-yl)-9H-carbazole
9-Phenyl-9H,9'H-[3,3']bicarbazolyl ISO 9001:2015 REACH
9-Phenyl-9H,9'H-3,3'-bicarbazole (This product is only available in Japan.)
[EINECS(EC#)]

1312995-182-4
[Molecular Formula]

C30H20N2
[MDL Number]

MFCD22581311
[MOL File]

1060735-14-9.mol
[Molecular Weight]

408.493
Chemical PropertiesBack Directory
[Boiling point ]

685.6±37.0 °C(Predicted)
[density ]

1.23±0.1 g/cm3(Predicted)
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[pka]

17.10±0.30(Predicted)
[Appearance]

White to off-white Powder
[InChI]

InChI=1S/C30H20N2/c1-2-8-22(9-3-1)32-29-13-7-5-11-24(29)26-19-21(15-17-30(26)32)20-14-16-28-25(18-20)23-10-4-6-12-27(23)31-28/h1-19,31H
[InChIKey]

GKTLHQFSIDFAJH-UHFFFAOYSA-N
[SMILES]

N1(C2=CC=CC=C2)C2=C(C=CC=C2)C2=C1C=CC(C1=CC3C4=C(NC=3C=C1)C=CC=C4)=C2
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H412
[Precautionary statements ]

P261-P301+P312-P302+P352-P304+P340-P305+P351+P338
[HS Code ]

2933998090
Questions And AnswerBack Directory
[Application]

9-phenyl-3,3’-bicarbazolyl is the intermediate to synthesis electronic materials, such as OLED.9-phenyl-3,3’-bicarbazolyl is a kind of organic electroluminescent materials to make OLED display screen, and this intermediate can be used in OLED series, such as Thiophene series, Fluorene series, Boronic Acid series and so on.

Spectrum DetailBack Directory
[Spectrum Detail]

9-Phenyl-9H,9'H-[3,3']bicarbazolyl(1060735-14-9)1HNMR
Hazard InformationBack Directory
[Synthesis]

A mixture of (9-phenyl-9H-carbazol-3-yl)boronic acid (14.2 g,49.5 mmol), 3-bromo-9H-carbazole (11.1 g, 45.0 mmol), Pd(PPh3)4(1.05 g, 0.9 mmol), K2CO3 (2.0 M aqueous solution, 80 mL), toluene(160 mL) and ethanol (80 mL) were stirred under nitrogen at 100 °Cfor 12 h. Until the reaction cooled to room temperature, the grey powder was filtered from the solution and was recrystallized by ethanol to afford 9-Phenyl-3,3'-bicarbazolyl (15.1 g, yield: 82 percent).
[References]

[1] Patent: CN106631984, 2017, A. Location in patent: Paragraph 0020; 0021
[2] Patent: EP2662368, 2013, A1. Location in patent: Paragraph 0155; 0156
[3] Dyes and Pigments, 2017, vol. 136, p. 54 - 62
[4] Patent: EP1972619, 2008, A1. Location in patent: Page/Page column 262-263
[5] Patent: US2009/247795, 2009, A1. Location in patent: Page/Page column 10
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